CAS: 15233-65-5; 2,6-Dimethoxybenzene-1,4-Diol

该化合物是一种有机化合物,其特征是附于一种氢丙酮结构的两种甲氧基组;一种是氢丙酮的衍生物,在苯环的2和6个位置上以甲基氧替代物为主;该化合物一般是白色的脱白晶状固体,在乙醇和丙酮等有机溶剂中可溶解,但在水中溶解性有限;它具有抗氧化特性,因此对包括化妆品和药品在内的各种应用感兴趣;甲氧基组的存在增强了其稳定性,并改变了其相对于非替代的氢丙酮的再活性;此外,2,6-二甲基氧基氢丙酮可以作为消毒剂参与再氧化反应;安全考虑因素包括潜在的皮肤和眼刺激,应在实验室环境中以适当的防范措施加以处理;其化学行为和应用受其结构特征的影响,使其在有机合成和材料科学中成为有价值的化合物.

结构式图片

相似化合物

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合成工艺路线路线简述

    📜1,2,3-三甲氧基苯置于sodium Dithionite,硝酸,溶剂黄146体系中,用 水,乙酸乙酯 用作溶剂,化学反应 1.67H,反应生成2,6-二甲氧基对苯二酚
    参考文献:Total Synthesis Of Evelynin B And Taccabulin D
    标题:Total Synthesis Of Evelynin B And Taccabulin D
    摘要:通过六个步骤和三个步骤,分别从焦醛三甲醚和 1,3,5-三甲氧基苯中简便地全合成了从 Tacca Chantrieri 和 T. Integrifolia 的根和根茎中分离出来的生物合成后二氢查尔酮 Evelynin B 和 Taccabulin D.醛和苯乙酮的缩合是形成查尔酮的关键步骤.
    Doi:10.3184/174751915X14380132772976

    海关参考信息

    专利信息


    专利号:CN-101508689-A
    优先权日:2009-03-26
    标题 :Synthesis of oroxylin

    专利号:CN-101508689-B
    优先权日:2009-03-26
    标题 :Synthesis of oroxylin

    专利号:EP-2332898-A1
    优先权日:2009-12-10
    标题:Benzoquinone-based antioxidants
    发明人:GULABOSKI RUBIN; BOGESKI IVAN; KAPPL REINHARD; HOTH MARKUS PROF
    权利人:UNIV SAARLAND
    摘要:The invention relates to a new type of highly polar, at least double-negatively charged redox-active benzoquinones, notably derived from Coenzyme Q0, Q1 and dimethoxy benzoquinones, its production and use. The production of these benzoquinones comprises the reaction of dimethoxy benzoquinones with highly alkaline aqueous solutions. The benzoquinones of the invention have various potential applications in pharmaceutical and cosmetic industry (namely as antioxidants, anti-ageing agents and the like), in organic synthesis, metal complexations, metal separations, potentiometric titrations, interfacial catalysis, and ion-transfer reactions across biological membranes.

    专利号:CN-115612114-A
    优先权日:2021-07-14
    标 题:Method and application of copolymer film and its enzymatic self-assembly synthesis

    专利号:CN-116768839-A
    优先权日:2023-05-23
    标 题 :A kind of synthesis method of paper pulp

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Microwave-Assisted Efficient Synthesis Of Polymethoxyacetophenones And Natural Polymethoxyflavones, And Their Inhibitory Effects On Melanogenesis
    作者:Masao Tsukayama,Eiji Kusunoki,Mohammad M. Hossain,Yasuhiko Kawamura,Shinji Hayashi
    摘要:Microwave-Assisted Friedel-Crafts Acetylation Of Polymethoxybenzenes With Acetic Anhydride In The Presence Of In(Cf 3 So 3 ) 3 Under Solvent-Free Conditions Was Achieved Rapidly To Give Polymethoxyacetophenones In High Yields. Microwave-Assisted Benzoylation Of 2'-Hydroxypolymethoxyacetophenones With Polymethoxybenzoyl Chlorides, Followed By The Rearrangement Of The Resulting Benzoates And The Final

    合成参考文献


    摘要:Cheng, B.; Wang, T., Science of Synthesis Knowledge Updates, (2020) 3, 185.
    参考文献:10.1038/srep42121
    摘要:Singh R, Hu J, Regner MR, Round JW, Ralph J, Saddler JN, Eltis LD. Enhanced delignification of steam-pretreated poplar by a bacterial laccase. Scientific Reports. 2017 Feb 07;7(1):42121. doi: 10.1038/srep42121.
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