CAS: 129188-99-4; 4,4'-(3,3,5-Trimethylcyclohexane-1,1-Diyl)Diphenol

该化合物是一种高纯度的双酚衍生物,其特点是其环伽马体结构,可增强热稳定性和化学抗药性,其硬分子框架有助于改进聚合物基体的机械特性,使之适合先进的工程塑料,环氧树脂和涂层,该化合物具有低挥发性,与无卤阻燃剂非常相容,符合严格的监管要求.双酚TMC在要求高耐热性的应用方面特别受重视,例如电子聚氨酯和复合材料,其在紫外接触和水解下的稳定性在恶劣环境中进一步扩展了其实用性.

结构式图片

相似化合物

2362-14-3 843-55-0 41768-83-6

欧盟法规

C&L通报REACH预注册

上下游产品

dihydroisophorone phenol °Ctanethiol 1-dodecylthiol 1,1-bis(3-nitro-4-hydroxyphenyl)-3,3,5-trimethylcyclohexane

合成工艺路线路线简述

    碳酸二苯酯置于甲醇,硫酸,十二硫醇体系中,用 甲苯 用作溶剂,化学反应 4.0H,反应生成双酚tmc
    参考文献:Bisphenol Composition Containing Aromatic Alcohol Sulfonate And Method For Producing Same,Polycarbonate Resin And Method For Producing Same,And Bisphenol Production Method
    标题:Bisphenol Composition Containing Aromatic Alcohol Sulfonate And Method For Producing Same,Polycarbonate Resin And Method For Producing Same,And Bisphenol Production Method
    摘要:提供了一种包括特定量芳香醇磺酸盐的双酚类组合物,以及生产该组合物的简单方法.还提供了一种生产聚碳酸酯树脂的方法,通过使用包括特定量芳香醇磺酸盐的双酚类组合物,可以有效地进行熔融聚合反应,生产具有优异色调的聚碳酸酯树脂.一种包括不少于双酚类的质量的0.1 Ppb芳香醇磺酸盐的双酚类组合物.一种生产双酚类组合物的方法,包括在硫酸存在下将酮或醛与芳香醇反应以生产双酚类组合物.一种生产聚碳酸酯树脂的方法,包括使用双酚类组合物生产聚碳酸酯树脂.一种包括特定量芳香醇磺酸盐的聚碳酸酯树脂.

    海关参考信息

    专利信息


    专利号:US-2003130433-A1
    优先权日:2001-10-30
    标题 :Process for the production of graft polymers
    发明人:WENZ ECKHARD; BUCHHOLZ VERA; EICHENAUER HERBERT; WOLF UDO; BORN RALF-JURGEN; JANSEN ULRICH; DIETZ WOLFGANG
    摘要:A process of preparing a graft polymer (e.g., an ABS graft copolymer), which involves determining the concentration of at least one reaction component during the course of the reaction by means of Raman spectroscopy, is disclosed. The process, more particularly, comprises: (a) synthesizing the graft polymer from a reaction mixture comprising reactive components (e.g., monomers such as styrene and acrylonitrile, and a graft base); (b) analyzing the reaction mixture, at intervals, during the synthesis of the graft polymer, by means of Raman spectra; (c) recording the results of the Raman spectra analysis; (d) determining the concentration of at least one of said reactive components (e.g., styrene) by means of spectral evaluation of the recorded Raman spectra; and (e) terminating the synthesis reaction of the graft polymer when the concentration of at least one of the reactive components has reached a predetermined concentration value.

    专利号:US-5698600-A
    优先权日:1995-10-24
    标题:Process for the production of bisphenols with the use of new cocatalysts
    发明人:WULFF CLAUS; FENNHOFF GERHARD; EITEL ALFRED
    权利人:BAYER AG
    摘要:The invention relates to the synthesis of bisphenols from monophenols and carbonyl compounds such as aldehydes and ketones with concentrated mineral acids such as hydrochloric acid and/or hydrogen chloride gas as acid catalysts and a mercaptan as cocatalyst, which is fixed by an ion-pair bond to a matrix insoluble in the reaction medium.

    专利号:US-6545187-B1
    优先权日:2001-09-19
    标 题 :Production of low-particulate bisphenol and use thereof in the manufacturing of polycarbonate
    发明人:KISSINGER GAYLORD MICHAEL; CHEN FANG CHRISTINE; BLUBAUGH JAMES CRISTOPHER; NANCE DARLENE HOPE; STOKES EDWARD BRITTAIN; ORDONEZ JUAN RODRIGUEZ; QUINTANA JOSE M
    权利人:GEN ELECTRIC
    摘要:Low-particulate dihydric aromatic compounds such as bisphenol-A that can be used in the synthesis of low-particulate polycarbonates are prepared by introducing into a desorber column containing a non-aggregate packing material an adduct of bisphenol and phenol and optionally a stripping gas. The column is maintained at an operating temperature that is sufficiently high and an operating pressure that is sufficiently low such that the adduct is distilled. The stream of phenol and the stripping gas is recovered from the top of the column. A second stream containing bisphenol that is substantially free of added particulate matter is recovered from the bottom of the column. This purified stream of bisphenol-A can further be used in a method of producing optical-grade polycarbonate.

    专利号:US-6307005-B1
    优先权日:1999-10-29
    标 题:Robust process for the synthesis of polyestercarbonates
    发明人:DAVIS GARY CHARLES; MOBLEY DAVID PAUL
    权利人:GEN ELECTRIC
    摘要:The present invention related to a method for preparing a polyestercarbonate, the method comprising: n a) reacting a dihydric phenol and a diacid having from 12 to about 30 carbon atoms in the presence of an effective amount of carbonate precursor, thereby forming a reaction mixture, wherein the pH of the reaction mixture is maintained in an initial pH range of from about 8.5 to about 9.5 for about 50% to about 95% of the total carbonate precursor addition, and a second pH range of from about 10 to about 12 for the remainder of the carbonate precursor addition.

    专利号:US-8394912-B2
    优先权日:2009-12-22
    标 题 :Process and apparatus for the preparation of polycarbonate
    发明人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH
    权利人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH; BAYER MATERIALSCIENCE AG
    摘要:The invention relates to a process for the pretreatment of material surfaces in order to minimize the interaction between polycarbonate and metal and, in the processing and synthesis of polycarbonate, to obtain a high-quality polymer which in particular does not become discolored and is free of insoluble constituents.

    专利号:US-6596840-B1
    优先权日:1999-07-19
    标题 :Method for producing modified polycarbonates
    发明人:KRATSCHMER SILKE; HUCKS UWE; BUNZEL LOTHAR
    权利人:BAYER AG
    摘要:A process for the synthesis of polycarbonate is disclosed. The process entails reacting in the presence of at least one phosphonium salt as catalyst, at least one diphenol, at least one carbonic acid diester, and at least one alkyl group-substituted phenol chain terminator. The chain terminator is introduced in free form or as a transesterifiable compound under the conditions of the synthesis. The polycarbonate thus produced is suitable for preparing a variety of molded articles.
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    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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