专利号:WO-2006067109-A1 优先权日:2004-12-22 标 题 :Process for the mechanochemical synthesis of metal carboxylate 发明人:ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE 权利人:SOLVAY; ROBIN JEAN-JACQUES; TIFFES DOMINIQUE; HANNECART ETIENNE 摘要:Process for the mechanochemical synthesis of metal carboxylate Process for the mechanochemical synthesis of metal carboxylate, according to which, in a first stage, a mixture (M) comprising at least one acidic substance (A) selected from carboxylic acids and carboxylic acid anhydrides, at least one basic inorganic metal compound (B), water (C) and at least one third solid body (D) which is chemically inert with regard to the components (A), (B) and (C) and the metal carboxylate is formed and, in a second stage, the abovesaid mixture (M) is subjected to a mechanical stress sufficient to bring about a mechanochemical reaction between the acidic substance (A) and the basic inorganic metal compound (B).
专利号:US-7919069-B2 优先权日:2007-06-13 标题 :Rapid synthesis of titanate nanomaterials 发明人:KUNDU ANIMESH 权利人:UNIV LEHIGH 摘要:Provided herein is a hydrothermal process for the rapid synthesis of inorganic nanomaterials (e.g., nanofibers) containing sodium, bismuth, titanium, and oxygen, as well as new compositions made thereby. The process involves heating an aqueous solution or suspension of suitable salts of aforementioned elements at elevated temperature and pressure under constant stirring in a hermetically sealed vessel for a predetermined amount of time (e.g., less than two hours). The powder thus obtained contains nanofibers of rectangular cross-section, with the smallest fibers typically have a cross section of 16 nm×40 nm. Example fibers made by such processes have an aspect ratio exceeding 200.
专利号:US-2006229475-A1 优先权日:2005-04-11 标题:Synthesis of hydroxylated hydrocarbons 发明人:WEISS MICHAEL J; SUN SHOULI 权利人:WEISS MICHAEL J; SUN SHOULI 摘要:Ethylene glycol, other diols, triols, and polyols are made in an efficient manner by reacting dibromides with water in the presence of a metal oxide. An integrated process of dibromide formation, alcohol synthesis, metal oxide regeneration, and bromine recycling is also provided.
专利号:US-2006153728-A1 优先权日:2005-01-10 标题 :Synthesis of bulk, fully dense nanostructured metals and metal matrix composites 发明人:SCHOENUNG JULIE M; YE JICHUN 权利人:SCHOENUNG JULIE M; YE JICHUN 摘要:Bulk nanostructured alloys, such as aluminum 5083 alloys reinforced with 10 wt. % particulate B 4 C, was synthesized by cryomilling and spark plasma sintering. Material for the alloy are selected and the selected raw materials are cryomilled, mechanical milling at cryogenic temperatures, to fabricate nanostructured alloys at low temperatures. The cryomilled powders are then degassed, and consolidated using spark plasma sintering into dense bulk materials. The material thus obtained achieved near full density bulk materials, while retaining the nanocrystalline nature. The densities of the compacts were measured using Archimedes method. XRD, SEM, TEM, and hardness testing were used to characterize the cryomilled powders and consolidated compacts.
专利号:US-7485596-B2 优先权日:2005-12-28 标 题:Process for synthesizing a heteropoly acid catalyst for oxidation of unsaturated aldehydes to unsaturated carboxylic acid 发明人:KAUFFMAN JAMES W; CAI LIXIA; LIANG WUGENG 权利人:SAUDI BASIC IND CORP 摘要:The present invention is for a process for making a heteropoly acid compound catalyst for oxidation of unsaturated aldehydes, such as methacrolein, to unsaturated carboxylic acids, such as methacrylic acid, said catalyst containing oxides of molybdenum, phosphorus, and M′, wherein M′ is cesium, potassium, rubidium, or sodium, and bismuth. The process is a synthesis of the catalyst with specific process conditions for addition of the bismuth compound as an aqueous slurry without nitric acid. A catalyst precursor is formed by removing the water and drying the solid particles. The heteropoly acid compound catalyst is formed by calcination of the catalyst precursor.
专利号:US-8377406-B1 优先权日:2012-08-29 标 题 :Synthesis of bis(fluorosulfonyl)imide 发明人:SINGH RAJENDRA P; MARTIN JERRY LYNN; POSHUSTA JOSEPH CARL 权利人:BOULDER IONICS CORP; SINGH RAJENDRA P; MARTIN JERRY LYNN; POSHUSTA JOSEPH CARL 摘要:The present invention provides methods for producing bis(fluorosulfonyl) compounds of the formula:n nF—S(O) 2 —Z—S(O) 2 —F  In nby contacting a nonfluorohalide compound of the formula:n nX—S(O) 2 —Z—S(O) 2 —Xn nwith bismuth trifluoride under conditions sufficient to produce the bis(fluorosulfonyl) compound of Formula I, where Z and X are those defined herein.