CAS: 117857-95-1; Cis-α-(Carboxycyclopropyl)Glycine
该化合物是一种氨酸衍生物,它包含氨基酸组(-NH2)和碳本基组(-COOH),使它成为生理pH的Zwitter物种.2S,1'R,2'的注解表明其原子的具体空间安排,能够对其生物活动和与受体的相互作用产生重大影响.该化合物对生物化学研究,特别是...
- 英文名称Cis-α-(Carboxycyclopropyl)Glycine
- 中文名称cis-α-(羧基环丙基)甘氨酸
- IUPAC名称(1R,2S)-2-((S)-amino(carboxy)methyl)cyclopropane-1-carboxylic acid
- 其它别名(2S,3S,4R)-Ccg; (2S,3R,4S)-Alpha-(Carboxycyclopropyl)Glycine; (2S,3R,4S)-Ccg; (2S,1'R,2'S)-2-(Carboxycyclopropyl)Glycine; (2S,1'S,2'R)-2-(Carboxycyclopropyl)Glycine; L-Ccg-Iii; L-Ccg-Iv; (2S,1'R,2')-2-(2-Carboxycyclopropyl)*glycine
- CAS编号117857-95-1
- MFCD编号:MFCD00672637
- 分子式:C6H9NO4分子量:159.14
- 产品CID: 228444
- 产品分类有机原料→生命科学→氨基酸及其衍生物→甘氨酸及其衍生物
相似化合物
49606-99-7 49607-01-4 15785-26-9物理性质
上下游产品
2-((R)-Benzyloxycarbonylamino-methoxycarbonyl-methyl)-cyclopropanecarboxylic acid ethyl ester (1R,2S)-2-((S)-1-tert-Butoxycarbonylamino-2-hydroxy-ethyl)-cyclopropanecarboxylic acid ethyl ester (1R,2S)-2-((S)-tert-Butoxycarbonylamino-carboxy-methyl)-cyclopropanecarboxylic acid N-Cbz-(O-Me)-trans-2-(carboxycyclopropyl)glycine OBO ester (R)-4-(2-Carboxy-cyclopropyl)-5-oxo-oxazolidine-3-carboxylic acid benzyl ester (2R,3R,4R) α-(Carboxycyclopropyl)glycine (2R,3S,4S) α-(Carboxycyclopropyl)glycine (R)-4-[(R)-2-((R)-2-Hydroxy-1-phenyl-ethylcarbamoyl)-cyclopropyl]-5-oxo-oxazolidine-3-carboxylic acid benzyl ester合成工艺路线路线简述
海关参考信息
- 2905121000-正丙醇
2912110000-甲醛
2912120000-乙醛
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专利信息
专利号:JP-H02237984-A
优先权日:1989-03-10
标 题:Synthesis method of (5S)-5-N-(t-butoxycarbonyl)amino-5,6-dihydro-2-pyrone
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主要参考文献
[参考文献]: Charbel El-Hajj Moussa, Et Al. Effects Of L-Glutamate Transport Inhibition By A Conformationally Restricted Glutamate Analogue (2S,1'S,2'R)-2-(Carboxycyclopropyl)Glycine (L-Ccg Iii) On Metabolism In Brain Tissue In Vitro Analysed By Nmr Spectroscopy. Neurochem Res. 2002 Feb;27(1-2):27-35.[参考文献]: Y Nakamura, Et Al. (2S,3S,4R)-2-(Carboxycyclopropyl)Glycine, A Potent And Competitive Inhibitor Of Both Glial And Neuronal Uptake Of Glutamate. Neuropharmacology. 1993 Sep;32(9):833-7.
[参考文献]: Karina Apricò, Et Al. Binding And Transport Of [参考文献]: M Llansola, Et Al. Chronic Exposure To Ammonia Alters The Modulation Of Phosphorylation Of Microtubule-Associated Protein 2 By Metabotropic Glutamate Receptors 1 And 5 In Cerebellar Neurons In Culture. Neuroscience. 2005;133(1):185-91.
[参考文献]: Maria Wostrack, Et Al. Involvement Of Group Ii Mglurs In Mossy Fiber Ltd. Synapse. 2009 Dec;63(12):1060-8.
合成参考文献
参考文献:10.1016/s0031-9422(00)85446-1
摘要:Fowden L, Smith A, Millington DS, Sheppard RC. Cyclopropane amino acids from Aesculus and Blighia. Phytochemistry. 1969 Feb;8(2):437–43. doi: 10.1016/s0031-9422(00)85446-1.
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