CAS: 7789-66-4; Silicon(Iv) Bromide

该化合物是一种无机化合物,具有四面体分子几何特征,在室内温度下无色至黄色液体,呈现出阴极的气味.硅(IV) 溴具有高度反应性,特别是在水中,导致二氧化硅和氢溴酸的形成.该化合物主要用于有机合成和作为溴化剂.它有一个相对较低的沸点,可以在水性条件下处理,以防止水解.硅(IV) 也因其作为刘易斯酸,便利各种化学反应的能力而著称.由于它具有反应性,应当谨慎处理它,使用适当的安全措施避免接触,因为它可能会对皮肤,眼睛和呼吸系统造成刺激.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

tetrachlorosilane hexabromobenzene silicon hydrogen bromidetetrakis(dimethylamino)silane silica gel tribromosilane dimethyltin dibromide

合成工艺路线路线简述

    📜氢溴酸 反应生成 溴化硅(Iv)
    参考文献:Ixara,Josinao;Kogava,Tehnko
    标题:Ixara,Josinao;Kogava,Tehnko

    专利信息


    专利号:US-5359016-A
    优先权日:1993-03-29
    标 题 :Process for the synthesis of styrene-isoprene rubber
    发明人:HSU WEN-LIANG; HALASA ADEL F; MATRANA BARRY A
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The subject invention relates to a technique for synthesizing rubbery copolymers of styrene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire tread rubber compounds. By utilizing these styrene-isoprene rubbers in tire treads, tires having improved wet skid resistance can be built without sacrificing rolling resistance or tread wear characteristics. This invention more specifically discloses a process for the synthesis of styrene-isoprene rubbers which comprises copolymerizing isoprene monomer and styrene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) an alkyl tetrahydrofurfuryl ether modifier, wherein the molar ratio of the modifier to the lithitium initiator is within the range of 2:1 to 40:1. The subject invention further discloses a process for the synthesis of styrene-isoprene rubbers which comprises copolymerizing isoprene monomer and styrene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) 2,2-ditetrahydrofurylpropane as a modifier, wherein the molar ratio of the modifier to the lithium initiator is within the range of 1:1 to 40:1.

    专利号:US-2025197431-A1
    优先权日:2023-12-15
    标 题:Methods and systems for forming a layer comprising silicon and composition and synthesis of silicon precursor
    发明人:ROMERO PATRICIO EDUARDO; VERVUURT RENÉ HENRICUS JOZEF; DEZELAH CHARLES; PORE VILJAMI J
    权利人:ASM IP HOLDING BV
    摘要:Disclosed are methods and systems for forming a silicon-containing layer on a substrate. Further disclosed are composition and synthesis of silicon-containing precursor. The methods for forming a silicon-containing layer comprise executing a plurality of deposition cycles. A deposition cycle comprises a first precursor pulse that comprises exposing the substrate to a first precursor. The first precursor comprises a molecule comprising a P—Si bond. A deposition cycle further comprises a plasma pulse that comprises exposing the substrate to a plasma treatment. The plasma treatment comprises generating a plasma.

    专利号:US-5336739-A
    优先权日:1992-04-06
    标题:Alkyl tetrahydrofurfuryl ethers as anionic polymerization modifier in the synthesis of rubbery polymer
    发明人:HSU WEN-LIANG; HALASA ADEL F; MATRANA BARRY A
    权利人:GOODYEAR TIRE & RUBBER
    摘要:It has been unexpectedly discovered that various compounds, such as alkyl tetrahydrofurfuryl ethers, can be used to modify anionic polymerizations of conjugated diene monomers. These modifiers can be used to polymerize isoprene monomer into high 3,4-polyisoprene at excellent polymerization rates. This is in contrast to the modifiers such as tetramethylethylene diamine which are typically used to modify such polymerizations. This invention more specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) a modifier which is an alkyltetrahydrofurfuryl ether selected from the group consisting of ethyltetrahydrofurfuryl ether, propyltetrahydrofurfuryl ether, and butyltetrahydrofurfuryl ether. In the practice of this invention, the utilization of ethyltetrahydrofurfuryl ether is highly preferred since its use results in faster polymerization rates and higher vinyl contents in the resultant polymer.

    专利号:US-5448003-A
    优先权日:1992-04-06
    标题:Synthesis of rubbery polymer using anionic polymerization modifier
    发明人:HSU WEN-LIANG; HALASA ADEL F; MATRANA BARRY A
    权利人:GOODYEAR TIRE & RUBBER
    摘要:It has been unexpectedly discovered that various compounds, such as alkyl tetrahydrofurfuryl ethers, can be used to modify anionic polymerizations of conjugated diene monomers. These modifiers can be used to polymerize isoprene monomer into high 3,4-polyisoprene at excellent polymerization rates. This is in contrast to the modifiers such as tetramethylethylene diamine which are typically used to modify such polymerizations. This invention more specifically discloses a process for the synthesis of 3,4-polyisoprene which comprises polymerizing isoprene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) an alkyltetrahydrofurfuryl ether modifier, wherein the alkyl group in the alkyltetrahydrofurfuryl ether modifier contains from 6 to about 10 carbon atoms. In the practice of this invention, the utilization of alkyltetrahydrofurfuryl ethers having alkyl groups which contain from 6 to 10 carbon atoms, such as hexyltetrahydrofurfuryl ether, is highly preferred since their use does not results in the creation of odor problems.

    专利号:US-8933181-B2
    优先权日:2006-10-06
    标题:Branched polymers and methods for their synthesis and use
    发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
    权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
    摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

    专利号:US-9610572-B2
    优先权日:2012-11-15
    标 题 :Ruthenium complexes, method of their production and their usage
    发明人:GRELA KAROL; CZARNOCKI STEFAN
    权利人:APEIRON SYNTHESIS SPÓLKA AKCYJNA; APEIRON SYNTHESIS SPOLKA AKCYJNA
    摘要:The invention concerns the ruthenium complexes of the formula 1: n nacting as pre(catalysts) in the reaction of metathesis of olefins, as well as a method for their production, and their usage.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 183.
    摘要:Inoue, S.; Driess, M., Science of Synthesis Knowledge Updates, (2012) 4, 215.
    摘要:Kawachi, A., Science of Synthesis Knowledge Updates, (2013) 2, 154.
    摘要:Inoue, S.; Driess, M., Science of Synthesis Knowledge Updates, (2012) 4, 234.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知