专利号:US-2009043069-A1 优先权日:2007-08-06 标 题 :Activated esters for synthesis of sulfonated telechelic polycarbonates 发明人:BRUNELLE DANIEL J; COLONNA MARTINO; FIORINI MAURIZIO; BERTI CORRADO; BINASSI ENRICO 权利人:GEN ELECTRIC 摘要:A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
专利号:US-9174904-B1 优先权日:2014-07-15 标 题 :Synthesis of 2,2-bis(3-phenyl-4-hydroxyphenyl) propane (PHP) 发明人:CHANDRA GIRISH; SAIT MEERAKANI MOHAMED ALI; TANWAR AKHILESH; SHETTY SHARANKUMAR 权利人:SABIC GLOBAL TECHNOLOGIES BV 摘要:Disclosed herein are ortho aryl substituted bisphenol monomers that exhibit a lower binding energy to estradiol related receptors. The monomers are provided by the condensation of a ketone and phenol in the presence of an acid catalyst.
专利号:US-8309655-B2 优先权日:2009-12-22 标题 :Methods for the preparation of a poly(arylene ether) polysiloxane multiblock copolymer, multiblock copolymers produced thereby, and associated compositions and articles 发明人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT 权利人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT; SABIC INNOVATIVE PLASTICS IP 摘要:A poly(arylene ether)-polysiloxane multiblock copolymer is prepared by the reaction of a hydroxy-diterminated poly(arylene ether), a hydroxyaryl-diterminated polysiloxane, and an aromatic diacid chloride. This synthesis overcomes disadvantages of known syntheses of poly(arylene ether)-polysiloxane block copolymers. The poly(arylene ether)-polysiloxane multiblock copolymer is useful for improving the melt processability of poly(arylene ether) compositions.
专利号:US-12410280-B2 优先权日:2020-04-15 标 题:Synthesis, purification, and properties of ring-opened benzoxazine thermoplastic 发明人:ZHOU TIANLEI; YAO HAIQING; MIYAUCHI MASAHIKO 权利人:KANEKA CORP 摘要:A crosslinkable thermoplastic resin composition may include a polymer formed from the reaction between a bis-benzoxazine monomer and a bifunctional comonomer having phenol, amine, and/or thiol functional groups, wherein the polymer contains at least one crosslinkable group. A method of forming a crosslinkable thermoplastic resin composition may include reacting a bis-benzoxazine monomer and a bifunctional comonomer to form a polymer containing at least one crosslinkable group. A method of forming a cured thermoplastic resin may include curing the crosslinkable thermoplastic resin composition by applying an external stimulus.
专利号:US-6812320-B2 优先权日:2002-03-25 标题:Method for copolyestercarbonate synthesis 发明人:SILVA JAMES MANIO; DARDARIS DAVID MICHEL; O'NEIL GREGORY ALLEN; SYBERT PAUL DEAN; SU ZHAOHUI 权利人:GEN ELECTRIC 摘要:Thermally stable block copolyestercarbonates comprising chain members derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polyester chain segments, are prepared by a method comprising the steps of: (a) preparing a hydroxy-terminated polyester intermediate comprising structural units derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety; and (b) conducting a reaction of the polyester intermediate with phosgene in a reaction mixture comprising water, a substantially water-immiscible organic solvent, and a base, wherein base and phosgene are added simultaneously to the reaction mixture at a substantially constant molar ratio of base to phosgene for a time period of at least about 60% of the total amount of phosgene added.
专利号:JP-2005521765-A 优先权日:2002-03-25 标题 :Synthesis of copolyestercarbonate
[参考文献]: Chen D, Et Al. Bisphenol Analogues Other Than Bpa: Environmental Occurrence, Human Exposure, And Toxicity-A Review. Environ Sci Technol. 2016 Jun 7;50(11):5438-53.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198