CAS: 24038-68-4; 5,5''-(Propane-2,2-Diyl)Bis(([1,1'-Biphenyl]-2-Ol))

该化合物是一种属于双酚类别的化学化合物,其特点是两种酚组,该物质主要用于生产环氧树脂和聚碳酸酯塑料,有助于其强度和热稳定性;双酚OPPA具有良好的化学抗药性和耐久性等特性,使之适合各种工业应用,包括涂层和粘合剂;必须指出,双酚可以产生干扰内分泌的影响,引起人们对其安全和环境影响的关切;因此,监管检查已经加强,导致对更安全的替代品不断进行研究;就物理特性而言,双酚OPPA一般在室温上是固体的,可能具有与加工和应用相关的特定的熔点和沸点.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号68-11-1 硫代乙醇酸(TGA) | CAS号90-43-7 2-苯基苯酚 | CAS号67-64-1 丙酮

合成工艺路线路线简述

  • 合成目标产物 2,2-Bis(2-Hydroxy-5-Biphenylyl)Propane 主要起始原料 2-Phenylphenol And Acetone
  • (文献来源)合成步骤主要原料 2-Phenylphenol 和 Acetone
邻苯基苯酚置于盐酸,Sodium Hydroxide体系中,用 氘代丙酮,二氯甲烷 用作溶剂,化学反应生成2,2-双(2-羟基-5-联苯基)丙烷
参考文献:Synthesis Of 2,2-Bis(3-Phenyl-4-Hydroxyphenyl) Propane (Php)
标题:Synthesis Of 2,2-Bis(3-Phenyl-4-Hydroxyphenyl) Propane (Php)
摘要:本文披露了一种具有较低与雌二醇相关受体结合能的邻位芳基取代双酚单体.这些单体是在酸催化剂存在下,通过酮和酚的缩合反应提供的.

海关参考信息

专利信息


专利号:US-2009043069-A1
优先权日:2007-08-06
标 题 :Activated esters for synthesis of sulfonated telechelic polycarbonates
发明人:BRUNELLE DANIEL J; COLONNA MARTINO; FIORINI MAURIZIO; BERTI CORRADO; BINASSI ENRICO
权利人:GEN ELECTRIC
摘要:A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.

专利号:US-9174904-B1
优先权日:2014-07-15
标 题 :Synthesis of 2,2-bis(3-phenyl-4-hydroxyphenyl) propane (PHP)
发明人:CHANDRA GIRISH; SAIT MEERAKANI MOHAMED ALI; TANWAR AKHILESH; SHETTY SHARANKUMAR
权利人:SABIC GLOBAL TECHNOLOGIES BV
摘要:Disclosed herein are ortho aryl substituted bisphenol monomers that exhibit a lower binding energy to estradiol related receptors. The monomers are provided by the condensation of a ketone and phenol in the presence of an acid catalyst.

专利号:US-8309655-B2
优先权日:2009-12-22
标题 :Methods for the preparation of a poly(arylene ether) polysiloxane multiblock copolymer, multiblock copolymers produced thereby, and associated compositions and articles
发明人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT
权利人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT; SABIC INNOVATIVE PLASTICS IP
摘要:A poly(arylene ether)-polysiloxane multiblock copolymer is prepared by the reaction of a hydroxy-diterminated poly(arylene ether), a hydroxyaryl-diterminated polysiloxane, and an aromatic diacid chloride. This synthesis overcomes disadvantages of known syntheses of poly(arylene ether)-polysiloxane block copolymers. The poly(arylene ether)-polysiloxane multiblock copolymer is useful for improving the melt processability of poly(arylene ether) compositions.

专利号:US-12410280-B2
优先权日:2020-04-15
标 题:Synthesis, purification, and properties of ring-opened benzoxazine thermoplastic
发明人:ZHOU TIANLEI; YAO HAIQING; MIYAUCHI MASAHIKO
权利人:KANEKA CORP
摘要:A crosslinkable thermoplastic resin composition may include a polymer formed from the reaction between a bis-benzoxazine monomer and a bifunctional comonomer having phenol, amine, and/or thiol functional groups, wherein the polymer contains at least one crosslinkable group. A method of forming a crosslinkable thermoplastic resin composition may include reacting a bis-benzoxazine monomer and a bifunctional comonomer to form a polymer containing at least one crosslinkable group. A method of forming a cured thermoplastic resin may include curing the crosslinkable thermoplastic resin composition by applying an external stimulus.

专利号:US-6812320-B2
优先权日:2002-03-25
标题:Method for copolyestercarbonate synthesis
发明人:SILVA JAMES MANIO; DARDARIS DAVID MICHEL; O'NEIL GREGORY ALLEN; SYBERT PAUL DEAN; SU ZHAOHUI
权利人:GEN ELECTRIC
摘要:Thermally stable block copolyestercarbonates comprising chain members derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polyester chain segments, are prepared by a method comprising the steps of: (a) preparing a hydroxy-terminated polyester intermediate comprising structural units derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety; and (b) conducting a reaction of the polyester intermediate with phosgene in a reaction mixture comprising water, a substantially water-immiscible organic solvent, and a base, wherein base and phosgene are added simultaneously to the reaction mixture at a substantially constant molar ratio of base to phosgene for a time period of at least about 60% of the total amount of phosgene added.

专利号:JP-2005521765-A
优先权日:2002-03-25
标题 :Synthesis of copolyestercarbonate
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✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Chen D, Et Al. Bisphenol Analogues Other Than Bpa: Environmental Occurrence, Human Exposure, And Toxicity-A Review. Environ Sci Technol. 2016 Jun 7;50(11):5438-53.

合成参考文献


摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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