专利号:US-2024424490-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles 发明人:WNUK PAWEL; LEWERA ADAM; JURCZAKOWSKI RAFAL; POWALA FILIP; KOLODZIEJCZYK JAN 权利人:UNIV WARSZAWSKI 摘要:The presented invention relates to a method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles, which comprises the following steps:n adsorbing on carbon support complexes of a platinum group metal with a urea complexing agent selected from a group comprising urea, urea derivative, a mixture of urea with at least one urea derivative, and a mixture of at least two urea derivatives; and reducing the complexes adsorbed on the carbon support to metal nanoparticles, forming a product of carbon-supported metal nanoparticles. nn The invention also provides the use of the carbon-supported platinum group metal or metal alloy nanoparticles obtained by the method of the invention as catalyst. n The present invention further relates to a method of adsorption of precursors of platinum group metals on the surface of a carbon support and use of complexes of platinum group metals with urea complexing agent for adsorption of platinum group metal precursors on carbon support.
专利号:US-11565248-B2 优先权日:2017-10-31 标 题:Process for a mild aqueous synthesis of titanium phosphates—ion—exchangers having solely—H2PO4 active groups 发明人:ANTZUTKIN OLEG N; TRUBLET MYLÈNE CLAIRE; RUSANOVA-NAYDENOVA DANIELA PENCHEVA 权利人:ANTZUTKIN OLEG N; TRUBLET MYLENE CLAIRE; RUSANOVA NAYDENOVA DANIELA PENCHEVA 摘要:The invention relates to a process for performing a aqueous synthesis of titanium phosphates (TiP) having solely —H2PO4 groups, which process is characterised by the following steps: providing titanium (IV) oxysulphate, TiOSO4, in an aqueous solution or in a powder and H2SO4, substantially without transition divalent metal ions, including cobalt (II) and copper (II), heating of the thus formed aqueous solution to above 50° C., but below 85° C. for at least 30 minutes, providing a controlled amount of H3PO4 to said aqueous solution, to form an aqueous solution containing a molar ratio between TIO2 and P2Os being controlled to about 1:1, not above 1:1.5 and not below 1:0.7, stirring the thus formed aqueous solution for at least 3 hours to form precipitates of titanium phosphate, and allowing ageing of said solution, without stirring, acidic washing of the formed precipitate using HCI or other acids to obtain TiO(OH)(H2PO4)-H2O having solely —H2PO4 ion-exchange chemical groups and allowing said precipitates to dry to a powder product, substituting protons in the powder product TiO(OH)(H2PO4)-H2O to sodium cations by treatment of the latter with solutions of sodium carbonate and allowing the thus formed powder of Na—TiP1 to dry.
专利号:WO-2024200681-A1 优先权日:2023-03-31 标题:A catalytic material comprising supported co3mo3n for the synthesis of nh3 发明人:JEVTOVIKJ IVANA; SCHUNK STEPHAN A; FREI ELIAS CHRISTOPHER; TITLBACH SVEN; HEDRICK SCOTT; DISANTIS DAVID D; GESKE MICHAEL; MUELLER MATTHIAS 权利人:BASF SE; UNIV BERLIN TECH 摘要:The present invention relates to a catalytic material for the synthesis of NH3, the catalytic material comprising Co3Mo3N, one or more first promoter metals M1 selected from the group consisting of alkali metals, and mixtures of two or more thereof, and one or more second promoter metals M2 selected from the group consisting of V, Nb, Ta, Mo, W, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Ga, In, Sc, Y, La, and mixtures of two or more thereof, wherein the one or more first promoter metals M1 and the one or more second promoter metals M2 are supported on the Co3Mo3N. Further, the present invention relates to a process for preparing said catalytic material and a catalytic material obtained or obtainable by said process. Yet further, the present invention relates to use of the catalytic material according to the present invention and a process for synthesizing NH3.
专利号:US-11964260-B2 优先权日:2016-08-08 标题:Method for manufacturing ammonia synthesis catalyst, and method for manufacturing ammonia 发明人:HOSONO HIDEO; KITANO MASAAKI; YOKOYAMA TOSHIHARU; LI JIANG; KAWAMURA SHIGEKI; KISHIDA Kazuhisa 权利人:TOKYO INST TECH; TSUBAME BHB CO LTD 摘要:Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO·7Al 2 O 3 having a specific surface area of 5 m 2 /g or above; a second step for supporting a ruthenium compound on the 12CaO·7Al 2 O 3 ; and a third step for performing a reduction process on the 12CaO·7Al 2 O 3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.
专利号:US-11865521-B2 优先权日:2019-01-23 标题:Bifunctional catalyst for hydrogenation of carbon dioxide, and method for preparing hydrocarbon by using same 发明人:HWANG SUN MI; JUN KI WON; KIM SEOK KI; PARK HAE GU; HAN SEUNG JU 权利人:KOREA RES INST CHEMICAL TECH 摘要:The present disclosure relates to a bifunctional catalyst for manufacturing a hydrocarbon from carbon dioxide and hydrogen. The bifunctional catalyst includes a carbon composite including cobalt (Co) and nitrogen (N) atoms forming a coordinate bond with the cobalt, and metal particles which exhibit a catalytic activity for a Fischer-Tropsch synthesis reaction and which are dispersed on the inner pore surface and/or the outer surface of the carbon composite support, thus simultaneously promoting a reverse water gas shift reaction and the Fischer-Tropsch synthesis reaction.
专利号:US-2024226299-A1 优先权日:2018-10-02 标题 :Cellular production of pure iron oxide nanoparticles 发明人:ALPHANDERY EDOUARD 权利人:NANOBACTERIE 摘要:High purity magnetosomes produced by magnetotactic bacteria, wherein the metallic composition of the magnetosome is characterized by a high level of iron purity, preferentially not achieved through a chemical synthesis. The high purity magnetosomes are further characterized by having a content of Cd, Pb, Ni, Co, Al, Mn, Zn, Li, and/or Cu.
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