参考标题:The α-Effect In The Stereochemistry Of Kinetic Ketonization Of Enols1,2 作者:Howard E. Zimmerman,Pengfei Wang |发布日期:2003.11.1 摘要:Organic Reactions. Protonation Occurring From The Less Hindered Side Of The, E.G., Enolic System Affords The Less Stable Of Two Diastereomers. However, One Apparent Discrepancy Has Been In The Synthesis Of Prostaglandins. The Present Research Deals With The Source Of This Behavior. A Curious Effect Of The Substituent At The Enolic Alpha Carbon Was Uncovered. In Certain Instances An Alpha Substituent Is
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摘要:Maier, M. E., Science of Synthesis, (2007) 20, 1502. 摘要:Leung, M.-k.; Luh, T.-Y., Science of Synthesis, (2007) 30, 290.