CAS: 2348-82-5; 2-Methoxynaphthalene-1,4-Dione

上下游产品

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📜2-萘甲醚置于叔丁基过氧化氢,碳酸氢钠,[双(三氟乙酰氧基)碘]苯体系中,用 二氯甲烷 用作溶剂,化学反应 3.0H,以40%的收率获得2-甲氧基-1,4-萘醌
参考文献:Bis(Trifluoroacetoxyiodo)Benzene-Inducedactivation Oftert-Butyl Hydroperoxide For The Direct Oxyfunctionalization Of Arenes To Quinones
标题:Bis(Trifluoroacetoxyiodo)Benzene-Inducedactivation Oftert-Butyl Hydroperoxide For The Direct Oxyfunctionalization Of Arenes To Quinones
摘要:多种芳香烃与双(三氟乙酸氧)碘苯(pifa)/叔丁基过氧化氢体系氧化反应,生成相应的醌.反应条件和适用范围已详细讨论.
Doi:10.1055/s-2004-832843

专利信息

专利号:US-5708168-A
优先权日:1994-11-16
标 题 :Azepine compounds
发明人：KEANA JOHN F W; GUZIKOWSKI ANTHONY P; NOGALES DANIEL F; CAI SUI XIONG
权利人:OREGON STATE; ACEA PHARM INC
摘要:Disclosed are methods of preparing azepines by a multistep synthesis including a Diels-Alder reaction. Also disclosed are methods of treating or preventing neuronal loss associated with stroke, ischemia, CNS trauma, hypoglycemia and surgery, as well as treating neurodegenerative diseases including Alzheimer's disease, amyotrophic lateral sclerosis, Huntington's disease and Down's syndrome, treating or preventing the adverse consequences of the hyperactivity of the excitatory amino acids, as well as treating anxiety, chronic pain, convulsions, inducing anesthesia and treating or preventing opiate tolerance are disclosed by administering to an animal in need of such treatment an azepine which has high binding to the NMDA glycine site.