📜5-Chloro-8-Hydrazinopyrido<2,3-D>Pyridazine置于ammonium Cerium (Iv) Nitrate体系中,用 甲醇 用作溶剂,以70%的收率获得吡啶-2,3-二甲腈 参考文献:Can-Mediated Oxidation Of Electron-Deficient Aryl And Heteroaryl Hydrazines And Hydrazides 标题:Can-Mediated Oxidation Of Electron-Deficient Aryl And Heteroaryl Hydrazines And Hydrazides 摘要:芳基和杂芳基肼及肼酰胺成功地通过can被氧化,生成去肼化产物.反应途径强烈依赖于底物的性质,导致烃或烷氧衍生物的形成.当使用氘化溶剂,如氘代甲醇(methanol-D₄)或氘代乙腈(acetonitrile-D₃)时,实现了氘的区域特异性结合. Doi:10.1055/s-2007-1072749
专利号:US-2006183758-A1 优先权日:2005-02-17 标 题:Method for synthesis of AZA-annelated pyrroles, thiophenes, and furans 发明人:BEARD CHARLES D; LEE VING J; WHITTLE C E 权利人:CB RES AND DEV INC 摘要:Methods of synthesis of intermediates that are useful as bioisosteres of the indole, benzofuran and benzothiophene scaffold are disclosed.
专利号:US-2020398222-A1 优先权日:2019-06-14 标题 :Control of composite covalent organic framework by varying functional groups inside the pore 发明人:LI-OAKEY KATIE DONGMEI; HOBERG JOHN; PARKINSON BRUCE ALAN 权利人:UNIV WYOMING 摘要:An ordered functional nanoporous material (OFMN) composition includes a pore defined by a sidewall, the sidewall comprising N—C—N linkages therein. A process for synthesis of a reagent includes the reaction of a 6,7-diaminoquinoxaline having R groups with hexaketocyclohexane (HKH) octahydrate, where R is independently in each occurrence H, Cl, Br, I, C4H4S (thiophenyl), SO3−, CO2−, C≡CH, CHâ•?CH2, NH2, OH, C≡N, C1-C4 alkyl, (CH2)xCHâ•?CH2, or (CH2)yCHâ•?CH(CH2)z where x or (y+z) is an integer of 0 to 4 inclusive, (CH2)jCH≡CH, or (CH2)kCH≡C(CH2)r where j or (k+r) 0 to 4 inclusive. A process of degasification that includes extracting a gas from a mixture by exposing the mixture to an OFNM to selectively pass the gas therethrough. A process of dehydrogenation includes exposing an aliphatically unsaturated feedstock to platinum modified OFNM under conditions to form hydrogen and selectively passing the hydrogen through the platinum modified OFNM.
专利号:CN-102775346-A 优先权日:2012-08-24 标题:A Bifunctional Basic Ionic Liquid and Its Aqueous Phase Catalytic Synthesis of Substituted Pyridines
摘要:Lou, S.; Zhang, J., Science of Synthesis Knowledge Updates, (2012) 2, 255. 摘要:Rodríguez-Morgade, M. S.; Torres, T., Science of Synthesis Knowledge Updates, (2017) 2, 103. 参考文献:10.1155/2008/392090 摘要:Sakamoto K, Ohno-Okumura E, Kato T, Watanabe M, Cook MJ. Investigation of Zinc bis(1,4-didecylbenzo)-bis(2,3-pyrido) Porphyrazine for Application as Photosensitizer in Photodynamic Therapy of Cancer. Met Based Drugs. 2008;2008():392090. 参考文献:10.2478/v10007-008-0005-4 摘要:Hosni HM, Abdulla MM. Anti-inflammatory and analgesic activities of some newly synthesized pyridinedicarbonitrile and benzopyranopyridine derivatives. Acta Pharm. 2008 Jun;58(2):175–86. doi: 10.2478/v10007-008-0005-4.