📜3-叔丁基甲苯置于吡啶,氢氧化钾,Potassium Permanganate,氢氟酸体系中,化学反应生成3,5-二叔丁基苯甲酸 参考文献:Polyalkylbenzene Carboxylic Acid And Process Of Preparing It 标题:Polyalkylbenzene Carboxylic Acid And Process Of Preparing It
专利号:US-6479685-B2 优先权日:1998-01-09 标题 :Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers 发明人:WAYMOUTH ROBERT M; KRAVCHENKO RAISA L; MACIEJEWSKI PETOFF JENNIFER; HUNG JOYCE 权利人:TRUSTEES OF THE LELAND STANDAR 摘要:Metallocene catalysts having plural coordination geometries for synthesis of high melting polyolefin copolymers suitable as thermoplastic elastomers. The inventive catalysts comprise unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalysts that are capable of inter-converting between states with different polymerization or copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where r i >r f the polymer can be characterized as multiblock; where r i 专利号:US-9006347-B2 优先权日:2011-09-08 标 题 :Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent 发明人:WILLIAMS CHARLOTTE K; KEMBER MICHAEL; BUCHARD ANTOINE; JUTZ FABIAN 权利人:IMP INNOVATIONS LTD 摘要:The invention provides a process for the synthesis of a polycarbonate, the process comprising the step of reacting carbon dioxide with at least one epoxide in the presence of a catalyst of formula (I) and a chain transfer agent. The invention also provides a polymerization system for the copolymerization of carbon dioxide and at least one epoxide comprising a catalyst of formula (I) and a chain transfer agent, polycarbonates produced by the inventive process, a block copolymer comprising a polycarbonate produced by the inventive process, and a method of producing the block copolymer. The invention also relates to novel catalysts of formula (III).
专利号:US-6518378-B2 优先权日:1998-01-09 标题:High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis 发明人:WAYMOUTH ROBERT M; KRAVCHENKO RAISA L; PETOFF JENNIFER MACIEJEWSKI; HUNG JOYCE 权利人:UNIV LELAND STANFORD JUNIOR 摘要:This invention relates to high melting polyolefin copolymers suitable as thermoplastic elastomers and catalysts and methods for their synthesis. These elastomeric olefin copolymers are characterized by a mole fraction of crystallizable component X c from about 30 to about 99%; low glass transition temperatures, below −20° C., and typically below −50° C.; melting points above about 90° C.; high molecular weights; a molecular weight distribution M W /M n =10; and a narrow composition distribution between chains of =15%. The novel copolymers of the invention range from reactor blends to multiblock copolymers that can be sequentially fractionated into fractions of differing crystallinities, which fractions nevertheless show compositions of comonomers which differ by less than 15% from the parent polymer (reactor product). The invention also relates to a process for producing such copolymers by utilizing an unbridged, substituted or unsubstituted cyclopentadienyl metallocene catalyst that is capable of interconverting between states with different copolymerization characteristics, which interconversion is controlled by selecting the substituents of the cyclopentadienyl ligands so that the rate of interconversion of the two states is within several orders of magnitude of the rate of formation of a single polymer chain. Where r i >r f the polymer can be characterized as multiblock; where r i 专利号:BR-112014005182-B1 优先权日:2011-09-08 标 题:PROCESS FOR THE SYNTHESIS OF A POLYCARBONATE, POLYMERIZATION SYSTEM, AND METHOD TO PRODUCE THE COPOLYMER OF FORMULA B (A) N
专利号:US-10022454-B2 优先权日:2008-09-23 标 题 :Functionalized phosphorodiamites for therapeutic oligonucleotide synthesis 发明人:PETERSEN SCOTT G 权利人:PETERSEN SCOTT G; LIPOSCIENCES LLC 摘要:Disclosed herein are compositions and methods for generating ribo-nucleic neutral (RNN) or deoxyribo-nucleic-neutral (DNN) polynucleotides with reduced anionic charge, for improved intracellular delivery. Also disclosed herein are methods of using RNN and DNN compositions.
专利号:US-9217012-B2 优先权日:2009-04-08 标题 :Inhibitors of protein tyrosine phosphatases 发明人:ZHANG ZHONG-YIN; ZHANG SHENG 权利人:ZHANG ZHONG-YIN; ZHANG SHENG; UNIV INDIANA RES & TECH CORP 摘要:Disclosed herein are compounds that selectively inhibit members of the PTP family of enzymes. Synthesized compounds demonstrated selective inhibition of TC-PTP. Also provided are methods of using the compounds and formulations containing the compounds. Also described is a fluorescence-tagged combinatorial library synthesis and screening method. And methods of using these compounds to effect enzyme activity both in cells and in vitro as well as method of using these compounds to treat diseases in human and animals.