CAS: 13537-32-1; Fluorophosphoric Acid

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CAS号7664-38-2 磷酸 | CAS号7664-39-3 氟化氢 | CAS号21324-40-3 六氟磷酸锂 | CAS号14456-60-1 Pyrophosphoryl ... | CAS号403-65-6 (fluoro-phenoxy... | CAS号1333-74-0 氢 | CAS号13779-41-4 二氟磷酸 | CAS号13478-20-1 Phosphoryl fluoride | CAS号96-49-1 碳酸乙烯酯 | CAS号13779-41-4 二氟磷酸 | CAS号7664-38-2 磷酸

📜六氟磷酸锂置于碳酸乙烯酯,碳酸二甲酯体系中,用 氘代二甲亚砜 用作溶剂,化学反应 0.5H,反应生成单氟磷酸
参考文献:详细的拉曼光谱和NMR光谱分析 Lipf 6基锂离子电池电解质 的热分解初始阶段
标题:详细的拉曼光谱和NMR光谱分析 Lipf 6基锂离子电池电解质 的热分解初始阶段
摘要:与特定的电极化学性质无关,基于lipf 6的最先进的锂离子电池电解质在有机溶剂中的耐热性低,并且在高温下的循环寿命差.在此,我们使用拉曼光谱和NMR光谱对在85oc下存储的ec / Dmc中lipf 6热分解的初始阶段进行详细研究.如在拉曼光谱中检测到的那样,在储存过程中(长达160小时),放出了大量的co 2.时间分辨的1 H,31 P和19 F NMR光谱显示pof 3,Pof(oh)2,Pof 2(och 2 Ch2) N F和pof 2 Ome作为反应性分解产物.我们独特的19 F NMR方法(在加热的同时以高能量和高时间分辨率进行测量)可以对进化出的物种进行首次定量分析,并揭示了在最初的30分钟至72小时内的几种分解反应,其中hf和pof的速率2 Ome的形成令人惊讶地是线性的.发现ec与dmc相比反应性低得多.所有信息都用于制定基于lipf 6的电解质的更新分解路径图.
Doi:10.1039/c3Ra42611D

专利信息

专利号:US-2025250302-A1
优先权日:2024-02-05
标题:Synthesis of self-assembling artificial proteins utilizing a host-guest system and uses thereof
发明人：SANDANARAJ BRITTO S; KHYADE ASHWINI RAJENDRA; HATI KSHITISH CHANDRA
权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES PUNE IISER PUNE
摘要:The invention relates to an efficient method for synthesizing self-assembling artificial proteins (SAPs) utilizing a catalytic host-guest system. The process involves encapsulating hydrophobic probes with cyclodextrin, performing site-specific protein bioconjugation, and employing a second catalysis cycle for enhanced labeling. SAPs produced through this method are versatile and find applications in therapeutic delivery and diagnostics. The process is simplified, scalable, cost-effective, and environmentally sustainable, addressing the challenges of traditional SAP synthesis. By offering improved yield, functionality, and structural integrity, this invention advances the potential of SAPs in medical and industrial fields.

专利号:US-12304922-B1
优先权日:2021-12-09
标题:Low pressure process for synthesis of Pt(PF3)4 involving a soluble intermediate and storage of obtained Pt(PF3)4
发明人：NIKIFOROV GRIGORY; BLASCO NICOLAS
权利人:AIR LIQUIDE
摘要:A method for synthesis of Pt(PF3)4 (CAS #19529-53-4), the method comprising the steps of forming a suspension of a platinum precursor Pt(Hal)2, wherein Hal=F, Cl, Br or I, and a metal powder in a solvent, introducing excess amount of PF3 into the suspension of Pt(Hal)2 and the metal powder, forming a soluble reaction intermediate Pt(Hal)2(PF3)x in the solvent through a reaction between PF3 and Pt(Hal)2, wherein Hal=F, Cl, Br or I, x=1, 2, under a reaction condition, and forming Pt(PF3)4 from a reaction between Pt(Hal)2(PF3)x, the metal powder and the excess of PF3 in the solvent.

专利号:US-11807884-B2
优先权日:2017-12-09
标题:Generation-dependent supramolecular assemblies of protein-dendron conjugates
发明人：BRITTO Sandanaraj Selvaraj; BHANDARI PAVANKUMAR JANARDHAN; REDDY Mullapudi Mohan
权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES
摘要:The present invention discloses monodisperse protein-dendron conjugates that self-assemble to generation-dependent supramolecular protein assemblies of different size and surface charges. The invention further provides a process for synthesis of protein-dendron conjugates containing hydrophobic dendron of different generations.

专利号:US-2024150177-A1
优先权日:2022-11-07
标题 :Synthesis of cathode material for lithium battery
发明人：SHAKOOR ABDUL; NISAR UMAIR; QURESHI ZAWAR; ABRAHAM JEFFIN; ABDUL QUDDUS KHADIJA MUHAMMAD; ALQARADAWI SIHAM; KAHRAMAN RAMAZAN
权利人:QATAR FOUND EDUCATION SCIENCE & COMMUNITY DEV; UNIV QATAR
摘要:A synthesis method of cathode material for lithium battery is provided. The method includes dissolving lithium, nickel and cobalt acetate in a solution, adding ammonium dihydrogen phosphate to the solution, adding acid to the solution, heating the solution to a first temperature for a first period of time to form a solid mixer material, and sintering the solid mixer material at a second temperature for a second period of time.

专利号:US-8652431-B2
优先权日:2009-11-10
标 题 :Metal fluorophosphate synthesis and use as an active material for a battery electrode
发明人：PATOUX SEBASTIEN; BOURBON CAROLE; DUMONT-BOTTO ERWAN; DOLLE MICKAEL; ROZIER PATRICK
权利人:PATOUX SEBASTIEN; BOURBON CAROLE; DUMONT-BOTTO ERWAN; DOLLE MICKAEL; ROZIER PATRICK; COMMISSARIAT ENERGIE ATOMIQUE; CT NATIONALE DE RECH SCIENT
摘要:A method of synthesis of a metal fluorophosphate having the following general formula (1): X a M b (PO 4 ) c F d (1), in which: X is an alkaline metal selected among sodium (Na) and lithium (Li) or a mixture of said metals; M is a transition metal selected among the following elements: Co, Ni, Fe, Mn, V, Cu, Ti, Al, Cr, Mo, Nb or a combination of at least two of said metals, 0≦a≦5; 0.5≦b≦3; 0.5≦c≦3; and d is an integer equal to 1, 2 or 3. The method contains an electric-field-activated sintering process for a mixture (1) formed by at least one first phosphate-containing solid precursor and at least one second fluorine-containing solid precursor.

专利号:US-6316595-B1
优先权日:1994-03-14
标题 :PNA synthesis using a base-labile amino protecting group
发明人：BREIPOHL GERHARD; UHLMANN EUGEN; KNOLLE JOCHEN
权利人:AVENTIS PHARMA GMBH
摘要:The invention provides compounds and processes for synthesis of peptide nucleic acids (PNA). The compounds include temporary amino protecting groups that are base-labile, and protection groups for the exocyclic amino function of the nucleotide base that is compatible with the base-labile amino protecting group. Cleavage of an oligomer comprising these compounds from a solid support can be achieved using weak or medium strength acids.