CAS: 13067-79-3; 2-(2-Chloroethyl)Oxirane

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CAS号855241-51-9 1-bromo-3-chlor...

📜4-氯-1-丁烯置于叔丁基过氧化氢,[moo2(N'-(2-Hydroxy-4-Diethylaminobenzylidene)-4-Hydroxybenzohydrazide(-2H))(Meoh)]体系中,化学反应 1.0H,反应生成1,2-环氧氯丁烷
参考文献:钼(vi)配合物[moo 2(ch 3 Oh)l]的合成,结构和催化氧化
标题:钼(vi)配合物[moo 2(ch 3 Oh)l]的合成,结构和催化氧化
摘要:制备了一种新的钼(vi)络合物[moo 2(ch 3 Oh)(l)](l = N '-(4-二乙基氨基-2-羟基苄叉)-4-羟基苯并肼晶体x射线衍射(cif文件ccdc号1038153).配合物c 19 H 23 Mon 3 O 6的晶体在三斜晶空间群\(p \ Bar 1 \)中结晶,晶胞尺寸为a = 6.9824(9),B = 10.206(1),C = 15.302 (2)埃,α= 94.399(2)°,β= 101.877(2)°,γ= 104.062(2)°,V = 1025.9(2)埃3,ž= 2,R 1 = 0.0317,Wr 2 = 0.0796,S = 1.060.络合物中的mo原子与配体l的酚盐o,亚氨基n,烯醇式o原子和赤道平面中的一个oxo处于八面体配位,并且在轴向位点与一个甲醇o和另一个oxo O处于八面体配位.配合物的晶体通过氢键稳定.以叔丁基过氧化氢为氧化剂,
Doi:10.1134/s1070328415070052

专利信息

专利号:US-7301041-B2
优先权日:2002-02-14
标 题:Bi-functional metallocenes, preparation process and use in the labeling or biological molecules
发明人：CHAIX-BAUVAIS CAROLE; MOUSTROU CORINNE; NAVARRO AUDE-EMMANUELLE; BRISSET HUGUES; GARNIER FRANCIS; MANDRAND BERNARD; SPINELLI NICOLAS
权利人:BIO MERIEUX
摘要:The invention relates to bi-functionalised metallocenes of general formula (I) where Me=a transition metal, preferably chosen from Fe, Ru and Os, Y and Z, when identical are selected from —(CH 2 ) n —O—, (CH 2 )—O—[(CH 2 ) 2 —O] P — and —(CH 2 ) q —CONH—(CH 2 ) r —O—, or Y=—(CH 2 ) S —NH— and Z=—(CH 2 ) t —COO—, n =a whole number from 3 to 6 inclusive, p=a whole number from 1 to 4 inclusive, q=a whole number from 0 to 2 inclusive, r=a whole number from 0 to 2 inclusive, s=a whole number from 2 to 5 inclusive, t=a whole number from 3 to 6 inclusive, R and R′=H atoms or are protective groups used in oligonucleotide and peptide synthesis, where at least one of R or R′ is protective group used in oligonucleotide and peptide synthesis and R and R′ are as defined below: (i) when Z and Y are selected from (CH 2 ) n —O—, —(CH 2 )—O—[(CH 2 ) 2 —O] p — and —(CH 2 ) q —CONH—(CH 2 ) r —O—, then R and R′ are protective groups used in oligonucleotide synthesis and R is a group which can leave a free OH group after deprotection, preferably a photolabile group such as monomethroxythoxytrityl, dimethoxytrityl, t-butyldimethylsilyl, acetyl or trifluroacetyl, and R′ is a phosphorylated group which can react with a free OH, preferably a phosphodiester, phosphoramidite or H-phosphonate and (ii) when Y=—(CH 2 ) s —NH— and Z=—(CH 2 ) t —COO—, then R is a protective group used in the synthesis of peptides and is an amino-protecting group, preferably 9-fluorenyloxycarbonyl, t-butoxycarbonyl or benzyloxycarbonyl and R′=H. The above is applied in marking.

专利号:CN-104109097-A
优先权日:2014-05-20
标 题 :Synthesis method of 1,4-bis-dicyclohexylamido-2-butanol