CAS: 1676-81-9; Methyl ((Benzyloxy)Carbonyl)-L-Serinate

相似化合物

93204-36-5 14464-15-4 1145-80-8

上下游产品

CAS号5680-80-8 L-丝氨酸甲酯盐酸盐 | CAS号501-53-1 氯甲酸苄酯 | CAS号1145-80-8 |N|-苄氧羰基-L-丝氨酸 | CAS号74-88-4 碘甲烷 | CAS号67-56-1 甲醇 | CAS号2788-84-3 L-丝氨酸甲酯 | CAS号186581-53-3 重氮甲烷 | CAS号77-78-1 硫酸二甲酯 | CAS号108655-52-3 benzyl triazolo... | CAS号35761-26-3 |N|{α}-苄氧羰基-L-2... | CAS号35761-27-4 (S)-3-氨基-2-(((苄... | CAS号19647-68-8 (S)-(3-羟基-1-(甲基... | CAS号838-85-7 磷酸二苯酯 | CAS号25644-83-1 L-Serine,N-[(ph... | CAS号1872-59-9 O-叔丁基-N-苄氧羰基-L-丝氨酸甲酯 | CAS号1145-80-8 |N|-苄氧羰基-L-丝氨酸 | CAS号17331-87-2 N-Benzyloxycarb... | CAS号30735-20-7 N-苄氧羰基-L-丝氨酰基甘氨酸

Methyl (2S)-3-Acetyloxy-2-(Phenylmethoxycarbonylamino)Propanoate置于甲醇,Potassium Permanganate,三甲基碘化锍体系中,25.0 °C,101.33 Kpa 条件下,以96%的收率获得n-苄氧羰酰基-L-丝氨酸甲酯
参考文献:Me3Si 促进的化学选择性脱乙酰化:一般和温和的方案.
标题:Me3Si 促进的化学选择性脱乙酰化:一般和温和的方案.
摘要:通过使用 Kmno4 作为添加剂,开发了一种 Me3Si 介导的简单而有效的乙酰基化学选择性脱保护方案.这种化学选择性脱乙酰化适用于多种底物,可耐受碳水化合物,氨基酸,天然产物,杂环化合物和一般支架中的多种敏感官能团.该协议很有吸引力,因为它使用环境友好的试剂系统在环境条件下进行定量和清洁转化.
Doi:10.1039/d1Ra03209G

专利信息

专利号:FR-2881741-A1
优先权日:2005-02-07
标题:PROCESS FOR THE SYNTHESIS OF CYSTEINE DERIVATIVES, IN PARTICULAR THIOCARBAESTER, USEFUL AS INTERMEDIATE PRODUCTS IN THE SYNTHESIS OF DRUGS

专利号:CN-1837189-A
优先权日:2005-03-21
标 题 :Process for liquid phase synthesis of N-fluorenyl-methoxy-carbonyl-N-methyl-O-tertiary butyl serine

专利号:US-5618808-A
优先权日:1992-07-01
标 题 :Benzothiazepine and benzoxazepine derivatives as cholecystokinin receptor antagonists
发明人：NAGEL ARTHUR A
权利人:PFIZER
摘要:The present invention relates to novel substituted benzothiazepines and benzoxazepines of the formula ##STR1## wherein R 1 , R 2 , R 7 , R 8 , R 9 and X are as defined below, and to novel intermediates used in the synthesis of such compounds. n Such compounds are useful in the treatment and prevention of gastrointestinal disorders, pain and anxiety disorders.

专利号:CN-100491345-C
优先权日:2005-03-21
标 题:Process for liquid phase synthesis of N-fluorenyl-methoxy-carbonyl-N-methyl-O-tertiary butyl serine

专利号:DE-19802748-A1
优先权日:1998-01-26
标题:Process for the enzymatic synthesis of glycoamino acid derivatives

专利号:US-5767254-A
优先权日:1992-12-15
标题 :Method for making amino acid glycosides and glycopeptides
发明人：POLT ROBIN L
权利人:UNIV ARIZONA
摘要:A compound of the formula ##STR1## is disclosed. X is selected from the group consisting of aryl, alkyl, imte ester, imino ester, amidine, azide, isocyanate, and dithiocarbonate. R' is a group selected from the group consisting of groups containing a hydroxyl moiety, groups containing a protected hydroxyl moiety, and groups containing an O-linked sugar. G is a carbon chain of 0-10 carbons and R is not a methyl group and is a group capable of removal under conditions compatible with glycopeptide synthesis. In a preferred form the compound, R is selected from the group consisting of benzylic or allyl groups and X is CPh 2 . A method of forming a glycocide from the compound is also disclosed.