CAS: 1529-48-2; Dimethylgermanium Dichloride

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CAS号7440-56-4 锗粉 | CAS号74-87-3 氯甲烷 | CAS号75-76-3 四甲基硅烷 | CAS号10038-98-9 氯化锗 | CAS号22702-77-8 chloro(dimethyl... | CAS号100-44-7 氯化苄 | CAS号32284-96-1 Digermane, pent... | CAS号37899-63-1 dimethyl(phenyl... | CAS号56-23-5 四氯化碳 | CAS号150054-52-7 chloro-[5-[chlo... | CAS号993-52-2 六甲基二锗 | CAS号1066-63-3 dimethylgermani... | CAS号14938-41-1 dimethylgermani... | CAS号13189-68-9 dimethylgermani... | CAS号21961-74-0 1,1-Dimethyl-1-... | CAS号22702-77-8 chloro(dimethyl...

📜锗烷置于铜 Methyl Chloride体系中,化学反应生成二氯二甲基锗
参考文献:镧系元素的有机金属化合物.64.二甲基锗双(四甲基环戊二烯基)卤化物和镧系元素的烷基衍生物的合成和x射线晶体结构
标题:镧系元素的有机金属化合物.64.二甲基锗双(四甲基环戊二烯基)卤化物和镧系元素的烷基衍生物的合成和x射线晶体结构
摘要:Metathesis Of Me2Gecl2 Or Me2Sncl2 With 2 Equiv Of Lic5Me4H Affords Me2Ge(C5Me4H)2 (1) And Me2Sn(C5Me4H)2 (2),Respectively. The Subsequent Deprotonation Of 1 With Meli Yields Only The Desired Dilithium Salt Me2Ge(C5Me4Li)2 (3) Whereas 2 Forms Me4Sn And Two Lic5Me4H. The Trichlorides Of Neodymium,Samarium,Holmium,And Lutetium React With The Dilithium Salt 3 With The Formation Of Me2Ge(C5Me4)2Lncl2Li(Thf)2 (Ln = Nd (4),Sm (5),Ho (6),Lu (7)). The Reaction Of 4 And 6 With Lich(Sime3)2 Produces Me2Ge(C5Me4)2Lnch(Sime3)2 (Ln = Nd (8),Ho (9)). The New Compounds Have Been Characterized By Elemental Analysis,Mass And NMR Spectra,As Well As X-Ray Structural Analysis Of 5,7,And 9. The Halides 5 And 7 Crystallize In The Monoclinic Space Group P2(1)/c (No. 14) With A = 9.7284 (9),B = 19.397 (1),C = 16.610 (2) Angstrom,Beta = 98.963 (9)-Degrees; Z = 4 Or A = 9.578 (3),B = 19.218 (4),C = 16.525 (4) Angstrom,Beta = 99.73 (2)-Degrees; Z = 4,Respectively. Least-Squares Refinement Led To A Final R Value Of 0.020 (F(O) > 4-Sigma-(F(O))) For 5554 Independent Reflections For 5 Or Of 0.028 (F(O) > 3-Sigma-(F(O))) For 5822 Independent Reflections For 7. Compound 9 Crystallizes In The Monoclinic Space Group P2(1)/m (No. 11) With A = 9.2621 (8),B = 14.216 (2),C = 11.839 (2) Angstrom,Beta = 107.79 (1)-Degrees,Z = 2,And R = 0.023 (F(O) > 4-Sigma-(F(O))) For 2954 Reflections. The Structure Of 9 Shows A Short Ho-C(Methyl) Contact Of 2.774 (4) Angstrom.
Doi:10.1021/om00054A017

专利信息

专利号:US-9896776-B2
优先权日:2011-09-21
标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids
发明人：STEVENSON KEITH J; MURUGESAN SANKARAN; KEARNS PATRICK; AKKINENI ARUNKUMAR
权利人:UNIV TEXAS
摘要:Room temperature electrochemical methods to deposit thin films of chalcogenide glasses.

专利号:US-2013112110-A1
优先权日:2011-09-21
标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids

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优先权日:2015-04-17
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专利号:CN-106145144-B
优先权日:2015-04-17
标 题 :A kind of heteroatom micro-mesoporous composite material and its synthesis method

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优先权日:2015-04-17
标题 :A kind of heteroatom molecular sieve and its synthesis method

专利号:US-2016153108-A1
优先权日:2011-09-21
标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids