CAS: 104-09-6; 2-(P-Tolyl)Acetaldehyde

相似化合物

14062-19-2 622-47-9 699-02-5

上下游产品

(4-methylphenyl)acetonitrile 2-(4-methylphenyl)oxirane ethyl 3-(4-methylphenyl)oxirane-2-carboxylate 1-(4-methylphenyl)-1,2-ethanediol1-(3-methylphenyl)-2-(4-methylphenyl)ethanol 2,4'-dimethyl-deoxybenzoin 4-Methylphenethyl alcohol 6-benzo[1,2,4]thiadiazine-7-sulfonic acid amide6-chloro-3-(4-methyl-benzyl)-1,1-dioxo-1,2,3,4-tetrahydro-1λ6-benzo[1,2,4]thiadiazine-7-sulfonic acid amide

📜1-烯丙基-4-甲基苯置于臭氧体系中,用 甲醇 用作溶剂,化学反应 0.75H,以13%的收率获得4-甲基苯乙醛
参考文献:揭示了黄连ncs2的催化潜力-基于氟胺的测定方法的开发和利用
标题:揭示了黄连ncs2的催化潜力-基于氟胺的测定方法的开发和利用
摘要:研究了来自黄连ncs2的正月桂氨酸合成酶(ncs)的多功能性和潜力,以及使用近四十种胺/醛的新型荧光高通量测定方法的开发和应用.已经确定了cj Ncs2对选定的非天然底物施加的立体控制,其中天然氢去甲可可碱在> 95%ee中形成了四氢异喹啉(thias)作为(1 S)异构体.利用报告的黄藻ncs X射线晶体结构对涉及thia机制中间体的对接计算,并与cj结合ncs2筛选结果可进一步了解ncs的作用方式.这些发现表明,除了关键的活性位点残基k122和e110,D141对于酶促转化在机械上也是必不可少的.我们提出的机理进一步支持了ncs对醛底物的超强耐受性,其中醛从酶口袋中伸出.
Doi:10.1002/adsc.201200641

专利信息

专利号:DE-102011006459-B4
优先权日:2011-03-30
标题:Process for the enzymatic synthesis of aromatic aldehydes or ketones

专利号:CN-103922876-A
优先权日:2014-05-07
标题:A new method for the synthesis of functionalized ketones via the deoximation reaction of hexachlorodisilane

专利号:US-4267359-A
优先权日:1978-05-04
标 题:Novel carboxylic acid esters
发明人：ANDERSON RICHARD J; HENRICK CLIVE A
权利人:ZOECON CORP
摘要:Esters and thiolesters of α-substituted unsaturated acids, intermediates therefor, synthesis thereof, and the use of said esters and thiolesters and compositions thereof for the control of pests.

专利号:US-2008139805-A1
优先权日:2005-03-22
标题 :Process for producing carbapenem derivative having a 1-alkylpyrrolidine structure
发明人：MICHIDA MAKOTO; HAYASHI MASAKI; KOBAYASHI SATOSHI
权利人:DAIICHI SANKYO CO LTD
摘要:A process for the preparation of carbapenem-type antibacterial agents involving the following reaction: n n n n n n n n n n wherein R 1 is a C 1 -C 3 alkyl group, n is 0, 1 or 2, A is a C 1 -C 3 alkylene group, L is a leaving group, R 3 is a hydrogen atom, a C 1 -C 3 alkyl group or an amino protecting group, and the hydroxyl or carboxyl groups are optionally independently protected. In such process, amine compound (1) or a salt thereof acts as a synthetic intermediate. Such process is a less expensive and highly safe synthetic route for carbapenem-type antibacterial agents suitable for large-scale synthesis.

专利号:US-4204071-A
优先权日:1978-05-04
标题:4-Aryl-3-butenoic acids and lower alkyl esters
发明人：ANDERSON RICHARD J; HENRICK CLIVE A
权利人:ZOECON CORP
摘要:Benzyl esters and thiolesters of 4-aryl-3-butenoic acids, intermediates therefor, synthesis thereof, and the use of said esters and thiolesters for the control of pests.

专利号:CN-106588788-B
优先权日:2016-11-11
标 题 :The method of one pot of two-step method synthesis 1,2,3- triazole compound