合成目标产物 Propoxyethylene 主要起始原料 1-Propanol And Acetylene
(文献来源)合成步骤主要原料 1-Propanol 和 Acetylene
1-(1-乙氧基乙氧基)丙烷 反应生成 正丙基乙烯基醚 参考文献:Deschamps Et Al.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1954,Vol. 238,P. 2006 标题:Deschamps Et Al.,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1954,Vol. 238,P. 2006
专利号:US-2012184653-A1 优先权日:2011-01-18 标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer 发明人:WANG LIANG; WANG VIKTORIA 权利人:WANG LIANG; WANG VIKTORIA 摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.
专利号:US-5788950-A 优先权日:1994-08-03 标 题 :Method for the synthesis of mixed metal oxide powders 发明人:IMAMURA KUNIO; DIGREGORIO JOHN F; SMITH DOUGLAS M; IZAWA HIROZUMI; YAMAGUCHI TETSUHIKO 权利人:SHOWA DENKO KK 摘要:A technique to synthesize complex oxide ceramic powders which offers advantages of both the coprecipitation and sol-gel routes while doing away with the disadvantages is disclosed. Namely, the ability to achieve chemical homogeneity and crystallite size on the namometer length scale at a nonprohibitive cost is provided by the disclosed method. In one embodiment of the invention, a method for the synthesis of a mixed metal oxide powder is provided including (a) combining a liquid absorbent resin with at least one solution selected from the group consisting of solutions containing at least one organo-metallic compound and solutions containing at least one metallic salt compound, such that at least two metals are present in the liquid absorbent resin after the combining is completed; (b) after the combining, allowing the liquid absorbent resin to swell and gel and thereby form a swollen gel; (c) preparing a precursor material by changing at least one of the pH and temperature of the swollen gel; (d) pyrolyzing the precursor material to form a pyrolyzed precursor material; and (e) calcining the pyrolyzed precursor material to form a mixed metal oxide powder.
专利号:US-5420237-A 优先权日:1991-08-29 标 题:Enzymatic synthesis of polyaniline 发明人:ZEMEL HAYA; QUINN JOHN F 权利人:ALLIED SIGNAL INC 摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.
专利号:US-4331688-A 优先权日:1978-02-23 标题 :Therapeutic method for inhibiting gastric secretion by administration of 15-deoxy-16-hydroxy prostaglandins 发明人:KLUENDER HAROLD C; WOESSNER WARREN D; BIDDLECOM WILLIAM G 权利人:MILES LAB 摘要:Analogues of PGE 1 having the structural formula, ##STR1## in which J is R-hydroxymethylene or S-hydroxymethylene; R 1 is hydrogen; R 2 is hydrogen or together with R 4 is a methylene chain of 2 to 3 carbon atoms such that a cycloalkyl of 5 to 6 carbon atoms inclusive is formed; R 3 is hydrogen or methyl, or together with R 4 is a methylene or a lower alkylated methylene chain of 2 to 5 carbon atoms such that a cycloalkyl or a lower alkylated cycloalkyl of 4 to 7 carbon atoms inclusive is formed, or together with R 4 is bicycloalkyl or bicycloalkenyl moiety having the formula: ##STR2## such that a bicycloalkyl or bicycloalkenyl compound is formed, wherein m and n are integers having a value from 0 to 3, p is an integer having a value from 0 to 4 and q is an integer having a value of from 1 to 4 and wherein the double bond of such bicycloalkenyl is in the m, n, p, or q bridge; R 4 is hydrogen or methyl or together with R 2 or R 3 forms a cycloalkyl or bicycloalkyl or bicycloalkenyl as defined above, or together with R 5 is a methylene chain of 3 to 5 carbon atoms such that a cycloalkyl of 4 to 6 carbon atoms inclusive is formed; R 5 is selected from the group consisting of hydrogen, straight-chain alkyl having from 1 to 3 carbon atoms or together with R 4 forms a cycloalkyl as defined above; and R 6 is hydrogen or straight-chain alkyl having from 1 to 3 carbon atoms are disclosed. n PGE 1 ester analogues of the above formula, limited to the structures wherein two of R 2 , R 3 R 4 and R 5 form a cycloalkyl, lower alkylated cycloalkyl, bicycloalkyl or bicycloalkenyl are also disclosed. n The prostaglandin analogues selectively produce bronchodilation and decrease gastric secretion in vivo. n Methods of preparing the analogues and starting materials required in the synthesis of the analogues are also disclosed.
专利号:US-10336912-B2 优先权日:2014-08-01 标 题 :Methods for producing and using aqueous polyurethane/polyacrylate hybrid dispersions and use of said aqueous polyurethane/polyacrylate hybrid dispersions in coating agents 发明人:JAHNS EKKEHARD; MANGEL TIMO; ROESCH CHRISTINE; ROMANATO PAOLA; BURK YENI; PAKUSCH JOACHIM 权利人:BASF SE 摘要:The present invention provides an aqueous polyurethane (PU)-polyacrylate hybrid dispersion obtainable by free radical polymerization of at least one acrylate polymer (A1) in the presence of at least one polyurethane (P1), a process for preparing these aqueous polyurethane-polyacrylate hybrid dispersions, wherein said process comprises a) preparing an aqueous polyurethane dispersion and b) using the polyurethane dispersion thus prepared as raw material for the further synthesis of a polyacrylate dispersion, and the use of the hybrid dispersion thus obtained as binder in filled coating materials, particularly as a binder for flexible roof coatings.
专利号:US-4395561-A 优先权日:1982-05-14 标 题 :Synthesis of 3-hydroxyoxetane 发明人:BAUM KURT; GRAKAUSKAS VYTAUTAS; BERKOWITZ PHILLIP T 权利人:US NAVY 摘要:A process for preparing 3-hydroxyoxetane comprising the following steps in order n (1) reacting a carboxylic acid of the formula CH 3 (CH 2 ) n COOH with epichlorohydrin in the presence of anhydrous ferric chloride to produce an ester of the formula ##STR1## wherein n is an integer of from 0 to 3; (2) protecting the secondary hydroxy group of the ester with a blocking group, Z, that is stable to bases; thus forming a blocked ester of the formula ##STR2## (3) hydrolyzing the blocked ester formed in step (2) with an aqueous base to remove the carboxylic acid and form a 3-hydroxyoxetane derivative of the formula ##STR3## in which Z represents the blocking group; (4) removing the blocking group from the 3-hydroxyoxetane derivative by heating it with an alcohol and an acid to form the product 3-hydroxyoxetane, ##STR4##
摘要:Tang, X., Science of Synthesis Knowledge Updates, (2022) 3, 482. 摘要:Tang, X., Science of Synthesis Knowledge Updates, (2022) 3, 460. 摘要:Ishihara, K.; Sakakura, A., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 117. 摘要:Du, H., Science of Synthesis: Metal-Catalyzed Cyclization Reactions, (2016) 2, 252. 参考文献:10.1021/jp061431s 摘要:Zhou S, Barnes I, Zhu T, Bejan I, Benter T. Kinetic Study of the Gas-Phase Reactions of OH and NO3Radicals and O3with Selected Vinyl Ethers. J. Phys. Chem. A. 2006 May 20;110(23):7386–92. doi: 10.1021/jp061431s.