CAS: 630-17-1; 1-Bromo-2,2-Dimethylpropane

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新戊烷置于溴体系中,化学反应生成 1-溴-2,2-二甲基丙烷
参考文献:Poni,Chemisches Zentralblatt,1906,Vol. 77,# I,P. 442
标题:Poni,Chemisches Zentralblatt,1906,Vol. 77,# I,P. 442

专利信息

专利号:US-3872168-A
优先权日:1972-10-02
标题:Synthesis of acids and amides
发明人：COLLMAN JAMES P; WINTER STANLEY R; KOMOTO ROBERT G
权利人:TRUSTEES OF THE LELAND STAMFOR
摘要:Synthesis of acids R1COOH and amides R1CONR2R3 wherein R1 is attached to the carbonyl group by an aliphatic carbon atom and R2 and R3 are hydrogen or organic groups of a primary or secondary amine, by forming an alkyl or acyl intermediate (R1Fe(CO) 4 or R1COFe(CO) 4) and treating the intermediate with a suitable cleaving agent and, in the case of amides, also with ammonia or an amine.

专利号:US-3647837-A
优先权日:1970-02-09
标 题 :Synthesis of organolead compounds
发明人：WILLIAMS KENNETH C
权利人:ETHYL CORP
摘要:A METHOD OF MAKING ORGANOLEAD COMPOUNDS AND PARTICULARLY THE SYNTHESIS OF TETRANEOPENTYLLEAD AND HEXANEOPENTYLDILEAD FROM AN INORGANIC LEAD (II) SALT, AND THE USE OF SAID LEAD COMPOUNDS FOR DECREASING KNOCK IN INTERNAL COMBUSTION ENGINES.

专利号:US-9982005-B2
优先权日:2013-04-04
标 题 :Macrolides and methods of their preparation and use
发明人：MYERS ANDREW G; SEIPLE IAN BASS; ZHANG ZIYANG
权利人:HARVARD COLLEGE
摘要:Provided herein are methods of preparing macrolides by the coupling of an eastern and western half, followed by macrocyclization, to provide macrolides, including both known and novel macrolides. Intermediates in the synthesis of macrolides including the eastern and western halves are also provided. Pharmaceutical compositions and methods of treating infectious diseases and inflammatory conditions using the inventive macrolides are also provided. A general diastereoselective aldol methodology used in the synthesis of the western half is further provided.

专利号:US-6407299-B1
优先权日:1999-06-02
标 题:Alkyl magnesium catalyzed synthesis of ethylene and α-olefin polymers
发明人：SEN AYUSMAN; KIM JANG SUB
权利人:EXXONMOBIL RES & ENG CO; PENNSYLVANIA STATE RES FOUNDAT
摘要:The present invention is a two-component catalyst system comprising (a) an alkyl magnesium (MgR 2 ) component and (b) a Lewis acid component. The catalyst system is used for catalyzing the oligomerization and polymerization of ethylene and/or α-olefins to form homopolymers and copolymers. The products range from highly linear, high molecular weight, solid polymers to highly branched, lower molecular weight oils.

专利号:WO-0073359-A1
优先权日:1999-06-02
标题 :Alkyl magnesium catalyzed synthesis of ethylene and alpha-olefin polymers
发明人：SEN AYUSMAN; KIM JANG SUB
权利人:EXXONMOBIL RES & ENG CO
摘要:The present invention is a two-component catalyst system comprising (a) an alkyl magnesium (MgR2) component and (b) a Lewis acid component. The catalyst system is used for catalyzing the oligomerization and polymerization of ethylene and/or α-olefins to form homopolymers and copolymers. The products range from highly linear, high molecular weight, solid polymers to highly branched, lower molecular weight oils.

专利号:US-5936132-A
优先权日:1994-03-11
标题 :Alkene intermediates and synthesis thereof
发明人：MATSUMOTO MASAKATSU
摘要:A chemiluminescent 1,2-dioxetane derivative having a formula (I): ##STR1## wherein R 1 and R 4 each represent, individually, hydrogen, an alkyl group, an alkoxyl group, a hydroxyl group, or --OS;(R 9 R 10 R 11 ) in which R 9 , R 10 and R 11 each represent an alkyl group; R 2 , R 3 , R 5 and R 6 each represent, individually, hydrogen or an alkyl group, provided that R 2 , R 3 , R 5 and R 6 each cannot be hydrogen at the same time, and that R 2 and R 3 , and R 5 and R 6 , each taken together, can form a cycloalkyl group; R 7 represents an alkyl group; R 8 represents hydrogen, an alkoxyl group, a phosphate salt group, or --OSi(R 9 R 10 R 11 ); intermediates for synthesizing the above 1,2-dioxetane derivative; and methods of producing the intermediates are provided.