CAS: 944392-68-1; Dimethyl 5-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)Isophthalate

该化合物是一种正甲酸酯衍生物,通常用作有机合成的中间体,特别是在铃木-宫浦交叉相交反应中,二氧甲醇组的存在增强了稳定性和反应性,使其成为构建复杂的芳香框架的宝贵试剂.其酯功能为进一步衍生提供了额外的多功能.该化合物通常用于制药和材料科学研究,因为它具有高效的理晶特性,并且与各种反应条件相容.高纯度能确保敏感应用的性能一致.建议在惰性条件下进行适当处理,以保持其稳定性.

结构式图片

相似化合物

177735-55-6 1041434-13-2 945865-80-5

物理性质

MSDS等安全信息

合成工艺路线路线简述

  • 合成目标产物 3,5-Bis(Methoxycarbonyl)Phenylboronic Acid Pinacol Ester 主要起始原料 Dimethyl Isophthalate And Bis(Pinacolato)Diboron
  • 1459-93-4 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Catalysts: Di-μ-Chlorobis[(1,2,5,6-η)-1,5-Cyclooctadiene]Diiridium,N1-[4,4′-Bis(1,1-Dimethylethyl)[2,2′-Bipyridin]-6-Yl]-1,2-Benzenediamine Solvents: Cyclopentyl Methyl Ether; 12 H,140 °C
    标题:Nnb-Type Tridentate Boryl Ligands Enabling A Highly Active Iridium Catalyst For C-H Borylation
    作者:Ding,Siyi; Wang,Linghua; Miao,Zongcheng; Li,Pengfei
    参考文献:Molecules 日期:2019 卷标:24(7)]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Stereoisomer Of Bis[2-[[bis[2,4-Bis(1,1-Dimethylethyl)Phenoxy]Phosphino-Kp]Oxy]-...,4-(9-Anthracenyl)-3-(1,1-Dimethylethyl)-2,3-Dihydro-1,3-Benzoxaphosphole Solvents: Dimethylacetamide; 12 H,100 °C
    标题:Efficient Monophosphorus Ligands For Palladium-Catalyzed Miyaura Borylation
    作者:Tang,Wenjun; Keshipeddy,Santosh; Zhang,Yongda; Wei,Xudong; Savoie,Jolaine; Et Al
    参考文献:Organic Letters 日期:2011 卷标:13(6) 页码:1366-1369]

    1459-93-4 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Oxygen Catalysts: Isopropanol,Chloro[(1,2,5,6-η)-1,5-Cyclooctadiene](1,10-Phenanthroline-Kn1,Kn10)Iridium Solvents: Heptane; 1 H,75 °C1.2 18 H
    标题:Understanding The Activation Of Air-Stable Ir(Cod)(Phen)Cl Precatalyst For C-H Borylation Of Aromatics And Heteroaromatics
    作者:Slack,Eric D.; Colacot,Thomas J.
    参考文献:Organic Letters 日期:2021 卷标:23(5) 页码:1561-1565]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Diacetate Solvents: Dimethylformamide; 24 H,Rt -> 90 °C
    标题:A Novel Electrochromic Polymer Synthesized Through Electropolymerization Of A New Donor-Acceptor Bipolar System
    作者:Natera,Jose; Otero,Luis; Sereno,Leonides; Fungo,Fernando; Wang,Nung-Sen; Et Al
    参考文献:Macromolecules (Washington 日期:2007 卷标:40(13) 页码:4456-4463]

    51839-15-7 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Diacetate Solvents: Dimethylformamide; 12 H,Rt -> 90 °C; 90 °C -> Rt
    标题:Functionalized Mesopores To Metal Organic Frameworks Via Metal Ligand Fragment Coassembly
    作者:Park,Jinhee; Wang,Zhiyong U.; Sun,Lin-Bing; Chen,Ying-Pin; Zhou,Hong-Cai
    参考文献:Journal Of The American Chemical Society 日期:2012 卷标:134(49) 页码:20110-20116]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; Overnight,100 °C
    标题:Two Isostructural Metal-Organic Frameworks With Unique Nickel Clusters For C2H2/c2H6/c2H4 Mixture Separation
    作者:Wang,Hao-Tian; Chen,Qiang; Zhang,Xin; Zhao,Yan-Long; Xu,Ming-Ming; Et Al
    参考文献:Journal Of Materials Chemistry A: Materials For Energy And Sustainability 日期:2022 卷标:10(23) 页码:12497-12502]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Dichlorobis[(Diphenylphosphino)Ferrocene]Palladium Solvents: 1,4-Dioxane; 24 H,80 °C
    标题:A New Metal-Organic Framework For Separation Of C2H2/ch4 And Co2/ch4 At Room Temperature
    作者:Duan,Xing; Zhou,You; Lv,Ran; Yu,Ben; Chen,Haodong; Et Al
    参考文献:Journal Of Solid State Chemistry 日期:2018 卷标:260 页码:31-33]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,70 °C
    标题:A Copper(Ii)-Paddlewheel Metal-Organic Framework With Exceptional Hydrolytic Stability And Selective Adsorption And Detection Ability Of Aniline In Water
    作者:Chen,Ya; Wang,Bin; Wang,Xiaoqing; Xie,Lin-Hua; Li,Jinping; Et Al
    参考文献:Acs Applied Materials & Interfaces 日期:2017 卷标:9(32) 页码:27027-27035]

    1459-93-4 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Catalysts: Bis[(1,2,5,6-η)-1,5-Cyclooctadiene]Di-μ-Methoxydiiridium,1,1′,3,3′-Tetrahydro-1,1′-Di-2-Pyridinyl-2,2′-Bi-2H-1,3,2-Benzodiazaborole Solvents: Cyclopentyl Methyl Ether; 16 H,100 °C; 100 °C -> Rt
    标题:Double N,B-Type Bidentate Boryl Ligands Enabling A Highly Active Iridium Catalyst For C-H Borylation
    作者:Wang,Guanghui; Xu,Liang; Li,Pengfei
    参考文献:Journal Of The American Chemical Society 日期:2015 卷标:137(25) 页码:8058-8061]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,80 °C
    标题:A Nbo-Type Metal-Organic Framework Exhibiting High Deliverable Capacity For Methane Storage
    作者:Song,Chengling; Ling,Yajing; Feng,Yunlong; Zhou,Wei; Yildirim,Taner; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2015 卷标:51(40) 页码:8508-8511]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,80 °C
    标题:Compositions And Methods For Selective Separation Of Hydrocarbon Isomers
    参考文献:World Intellectual Property Organization]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,128 °C
    标题:Preparation Of 5-[2-(5-Carboxy-Pyridyl)]-1,3- Benzene Dicarboxylic Acid
    参考文献:China]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,Rt -> 80 °C
    标题:Synthesis Of Metal Organic Framework (Mof) Materials With High Adsorption Capacity Of Organic Compounds And Co2 Capture
    参考文献:World Intellectual Property Organization]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: 1,1-Bis(Diphenylphosphino)Ferrocene,Dichloro[1,1′-Bis(Diphenylphosphino)Ferrocene]Palladium(Ii) Dichloromethane Addu... Solvents: 1,4-Dioxane; 18 H,90 °C
    标题:Preparation Of 3-Oxo-2,3-Dihydropyridazin-4-Ylurea Derivatives As Pde4 Inhibitors
    参考文献:World Intellectual Property Organization]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Dichloro[1,1′-Bis(Diphenylphosphino)Ferrocene]Palladium(Ii) Dichloromethane Addu... Solvents: 1,4-Dioxane; -78 °C; 15 H,Reflux
    标题:Methane Storage In Metal-Organic Frameworks: Current Records,Surprise Findings,And Challenges
    作者:Peng,Yang; Krungleviciute,Vaiva; Eryazici,Ibrahim; Hupp,Joseph T.; Farha,Omar K.; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2013 卷标:135(32) 页码:11887-11894]

    51839-15-7 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Palladium Diacetate Solvents: Dimethylformamide
    标题:Programmed Negative Allostery With Guest-Selected Rotamers Control Anion-Anion Complexes Of Stackable Macrocycles
    作者:Sheetz,Edward G.; Qiao,Bo; Pink,Maren; Flood,Amar H.
    参考文献:Journal Of The American Chemical Society 日期:2018 卷标:140(25) 页码:7773-7777]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; Rt -> 100 °C; 12 H,100 °C
    标题:Method For Preparing 5-(4-Carboxynaphthalen-1-Yl)Isophthalic Acid From 4-Bromonaphthalen-1-Carboxylic Acid
    参考文献:China]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: Dichloro[1,1′-Bis(Diphenylphosphino)Ferrocene]Palladium(Ii) Dichloromethane Addu... Solvents: 1,4-Dioxane; 0.5 H; 12 H,Rt -> 100 °C
    标题:A Synthetic Method Of New 5-[10-(9-Carboxyl Anthracene)]-Isophthalic Acid
    参考文献:China]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; Overnight,100 °C
    标题:A New Multidentate Hexacarboxylic Acid For The Construction Of Porous Metal-Organic Frameworks Of Diverse Structures And Porosities
    作者:Chen,Zhenxia; Xiang,Shengchang; Liao,Tengbiao; Yang,Yongtai; Chen,Yu-Sheng; Et Al
    参考文献:Crystal Growth & Design 日期:2010 卷标:10(6) 页码:2775-2779]

    51760-21-5 + 73183-34-3 = 944392-68-1
    反应条件:1.1 Reagents: Potassium Acetate Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: 1,4-Dioxane; 24 H,70 °C
    标题:A Novel Methoxy-Decorated Metal-Organic Framework Exhibiting High Acetylene And Carbon Dioxide Storage Capacities
    作者:Duan,Xing; Cui,Yuanjing; Yang,Yu; Qian,Guodong
    参考文献:Crystengcomm 日期:2017 卷标:19(11) 页码:1464-1469
📜5-氨基间苯二甲酸二甲酯置于盐酸,(1,1'-Bis(Diphenylphosphino)Ferrocene)Palladium(II) Dichloride,Potassium Acetate,Sodium Nitrite体系中,用 水,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 15.0H,反应生成 3,5-双(甲氧羰基)苯硼酸片呐醇酯
参考文献:Removal Of Toxic Dyes From Aqueous Medium Using Adenine Based Bicomponent Hydrogel
标题:Removal Of Toxic Dyes From Aqueous Medium Using Adenine Based Bicomponent Hydrogel
摘要:通过利用氢键和π-π堆积相互作用,我们展示了由腺苷与互补的三羧酸衍生物自组装构建的三维腺苷基凝胶网络,这些衍生物通过NMR,Hrms和ftir的帮助进行了设计并明确表征.在冷却腺苷和三羧酸的均匀水溶液时,形成了性质上热可逆的水凝胶,并由om,Fesem,Tem,Afm,Fl,Xrd,Ft-Ir,流变学等多种仪器技术表征.在水凝胶中清晰观测到带状网络,带状的尺寸取决于所用的三羧酸.通过ft-Ir研究证实了被认为是形成稳定凝胶驱动力的分子间氢键.尽管bpca或腺苷中缺乏对称性,但这两个部分却惊人地反应生成了凝胶,这是由于腺苷和三羧酸之间互补相互作用点的对称位置所致.流变学研究揭示的水凝胶网络的机械强度取决于二元系统中所用的三羧酸,也取决于固定对的组成.这类水凝胶有潜力作为处理含有广泛用于纺织和染料工业的有机染料(亚甲基蓝,罗丹明6G和结晶紫)的废水的廉价材料.
DOI:10.1039/c2Ra22988A

海关参考信息

专利信息


专利号:WO-2023118454-A1
优先权日:2021-12-22
标 题 :Synthesis of metal organic framework (mof) materials with high adsorption capacity of organic compounds and co2 capture

专利号:EP-4201940-A1
优先权日:2021-12-22
标 题 :Synthesis of metal organic framework (mof) materials with high adsorption capacity of organic compounds and co2 capture

专利号:EP-4452987-A1
优先权日:2021-12-22
标 题 :Synthesis of metal organic framework (mof) materials with high adsorption capacity of organic compounds and co2 capture

专利号:CN-105237337-A
优先权日:2015-11-11
标题:Synthesis method of novel 5-[10-(9-carboxyanthracenyl)]-isophthalic acid

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主要参考文献

参考标题:Regioselective Conversion Of Arenes ToN-Aryl-1,2,3-Triazoles Using Ch Borylation
作者:Rajavel Srinivasan,Anthony G. Coyne,Chris Abell |发布日期:2014.9.8
摘要:A One‐pot Protocol For The Synthesis Of N‐aryl 1,2,3‐triazoles From Arenes By An Iridium‐catalyzed Ch Borylation/copper Catalyzed Azidation/click Sequence Is Described. 1 Mol % Of Cu(Otf)2 Was Found To Efficiently Catalyze Both The Azidation And The Click Reaction. The Applicability Of This Method Is Demonstrated By The Late‐stage Chemoselective Installation Of 1,2,3‐triazole Moiety Into Unactivated

合成参考文献


摘要:Chowdhury, S., Science of Synthesis: Knowledge Updates, (2024) 1, 250.
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