CAS: 39067-39-5; 2-Propylbicyclo[2.2.1]Hept-5-Ene-3-Carbaldehyde

上下游产品

(E)-2-Hexenal cyclopenta-1,3-diene 2-hexenal

📜2-已烯醛,环戊二烯置于indium(III) Bromide体系中,用 二氯甲烷 用作溶剂,化学反应生成3-丙基二环[2.2.1]庚-5-烯-2-羧醛
参考文献:可回收利用的应用 离子液体-支持的 咪唑啉酮 催化剂 对映选择性狄尔斯-阿尔德反应
标题:可回收利用的应用 离子液体-支持的 咪唑啉酮 催化剂 对映选择性狄尔斯-阿尔德反应
摘要:的应用 离子液体-支持的 咪唑啉酮 催化剂 我在对映选择性diels-Alder反应中进行了研究.涉及α,β-不饱和基团的狄尔斯-阿尔德反应醛类 和 环戊二烯 在存在的情况下有效地进行了 催化剂 我将以中等至非常好的收率以及非常好至优异的对映选择性提供所需的产品.特别值得一提的是催化剂 我可以回收并重复使用多达五次,同时保持其高催化活性.
Doi:10.1039/c2Gc35966A

专利信息

专利号:US-11225655-B2
优先权日:2010-04-16
标题:Bi-functional complexes and methods for making and using such complexes
发明人：GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK
权利人:GOULIAEV ALEX HAAHR; FRANCH THOMAS; GODSKESEN MICHAEL ANDERS; JENSEN KIM BIRKEBAEK; NUEVOLUTION AS
摘要:The present invention is directed to a method for the synthesis of a bi-functional complex comprising a molecule part and an identifier oligonucleotide part identifying the molecule part. A part of the synthesis method according to the present invention is preferably conducted in one or more organic solvents when a nascent bi-functional complex comprising an optionally protected tag or oligonucleotide identifier is linked to a solid support, and another part of the synthesis method is preferably conducted under conditions suitable for enzymatic addition of an oligonucleotide tag to a nascent bi-functional complex in solution.