CAS: 10031-22-8; Lead(Ii) Bromide

该化合物是一种无机化合物,其特点是形成铅离子和溴离子,通常看起来像白色的黄色固体,以其低溶性在水中闻名,这是铅化合物的一个常见特征;铅二溴化物具有晶体结构,通常在四角系统中发现,并显示出高熔点;主要用于有机合成,并在各种化学反应中用作试剂;由于铅的存在,它构成严重的健康和环境风险,需要小心处理和处置;化合物可以使用强酸和碱进行反应,并且必须指出,铅二溴化物具有毒性,导致对其使用进行管制;

结构式图片

相似化合物

10031-22-8

欧盟法规

《欧盟PIC法规》ECHA物质ECHA物质OtherC&L通报REACH预注册

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CAS号22655-59-0 gallium monobromide | CAS号13450-88-9 溴化镓(III)

合成工艺路线路线简述

    溴化铵 反应生成溴化铅
    参考文献:Smirnov,V. A.;Kopetskij,Ch. V.;Redkin,A. N.,Vysokochist. Veshchestva,(1988) N 1,48-54
    标题:Smirnov,V. A.;Kopetskij,Ch. V.;Redkin,A. N.,Vysokochist. Veshchestva,(1988) N 1,48-54

    专利信息


    专利号:WO-2025062384-A2
    优先权日:2023-09-23
    标题 :A method for synthesis of metal halide perovskite (cspbbr3) nano/microcrystals
    发明人:M A GOKUL; RAHMAN ATIKUR
    权利人:INDIAN INSTITUTE OF SCIENCE EDUCATION AND RES PUNE IISER PUNE
    摘要:The present invention relates to metal halide perovskite (CsPbBr3) nano/microcrystals. Specifically, the present invention relates to a method for the synthesis of metal halide perovskite (CsPbBr3) nano/microcrystals. The present invention uses an easy, scalable low temperature growth of metal halide nanoparticles like CsPbBr3. The method uses a clever play on the solubility and ion exchange mechanism to precipitate nano and microcrystals of metal halide perovskites. The synthesis resulted in stable perovskite crystals with high photo- luminescence, ultralow dark current and control over their morphology. The combination of ultralow dark current, high responsivity, exceptional detectivity, and broad-band photon detection capabilities makes these crystals an excellent choice for upcoming sensors and detector technologies.

    专利号:US-7615169-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-7927516-B2
    优先权日:2004-09-20
    标题 :Method for synthesis of colloidal nanoparticles
    发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
    权利人:UNIV CALIFORNIA
    摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

    专利号:US-12202783-B2
    优先权日:2019-04-02
    标题 :Method for synthesis of organic iodides, a perovskite-forming composition comprising an organic iodide and a photovoltaic cell with a perovskite layer obtained therefrom
    发明人:MISZTAL KASJAN; WOJCIECHOWSKI KONRAD; MALINKIEWICZ OLGA; MIARA ZBIGNIEW
    权利人:SAULE S A
    摘要:A method for obtaining a salt with a general formula: RxNI, wherein: RxN is an organic cation (RxN+), R represents substituents (R—) independently selected from a group consisting of organic substituents: R1—, R2—, R3— and hydrogen (H—), x is a number of the substituents R— directly linked with the nitrogen (N) atom in the organic cation RxN+, wherein x is 3 or 4, I is an iodide anion (I−). The method comprises: preparing a reaction mixture comprising the steps of: synthesizing hydrogen iodide (HI) in situ by mixing molecular iodine (I2) with formic acid (COOH) in a molar ratio of molecular iodine (I2): formic acid (COOH) of no less than 1.01:1, in a solvent medium, introducing into the solvent medium a compound being a donor of organic cation RxN+ in an amount providing the molar ratio of the donor of organic cation RxN+: molecular iodine (I2) of no less than 1.01:1, and maintaining the reaction mixture at a temperature of not less than 20° C. for the time necessary to obtain the reaction product being the salt with the general formula RxNI. The obtained product is a substrate for synthesis of perovskites.

    专利号:US-7118627-B2
    优先权日:2003-12-04
    标 题 :Synthesis of colloidal PbS nanocrystals with size tunable NIR emission
    发明人:HINES MARGARET A; SCHOLES GREGORY D
    权利人:HINES MARGARET A; SCHOLES GREGORY D
    摘要:The present invention discloses a method for synthesis of narrowly dipsersed colloidal PbS nanocrystals that offer size-tunable near-infrared emission. The stability and processibility of these near-infrared emitting quantum dots makes them ideal materials for device applications. The use of cost-effective and non-pyrophoric precursors as well as the success of larger scale reactions means the present invention provides a method for the industrial scale production of PbS nanocrystals.

    专利号:WO-2024187064-A1
    优先权日:2023-03-09
    标题:Deterministic onsite synthesis of perovskite emitters via confined local heating
    发明人:NIROUI FARNAZ; ZHU WEIKUN; BEN-DAVID SHELLY; JASTRZEBSKA-PERFECT PATRICIA HELENA; JACK WILLIAM
    权利人:MASSACHUSETTS INST TECHNOLOGY
    摘要:A method of forming deterministic perovskite nanocrystals on a substrate is disclosed. The method includes preparing a perovskite forming precursor solution comprising a mixture of a solvent, perovskite precursors, and optionally surface passivation ligands and/or a host matrix. This perovskite forming precursor solution is deposited on a substrate by spin-coating, blade-coating or other deposition techniques to produce a layer comprising perovskite precursors, also referred to as a deposited perovskite forming precursor film. Then, a region of the film is locally heated to transform the perovskite precursors into perovskite nanocrystals and deterministically form an arbitrary pattern comprising clusters of the perovskite nanocrystals with control down to a single nanocrystal. The localized heating may be accomplished using thermal scanning probe lithography or lasers or a combination.
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    主要参考文献

    [参考文献]: A N Hamir, Et Al. Clinical Signs, Radiology And Tissue Lead Distribution Of Dogs Administered A Mixture Of Lead Chloride, Lead Bromide And Lead Sulphate. Aust Vet J. 1981 Sep;57(9):401-6.
    [参考文献]: A O Maslat, Et Al. Mutagenic Effects Of Lead (Ii) Bromide. J Trace Elem Electrolytes Health Dis. 1989 Dec;3(4):187-91.
    [参考文献]: G Ahmed, Et Al. Electronic Properties Of Pbcl2 And Pbbr2 Using Compton Scattering Technique. Appl Radiat Isot. 2009 Jun;67(6):1050-6.

    合成参考文献


    摘要:T17: Baselt RC (2000). Disposition of Toxic Drugs and Chemicals in Man, 5th ed. Foster City, CA: Chemical Toxicology Institute.
    摘要:A22: Hashemzadeh-Gargari H, Guilarte TR: Divalent cations modulate N-methyl-D-aspartate receptor function at the glycine site. J Pharmacol Exp Ther. 1999 Sep;290(3):1356-62.
    摘要:L136: ATSDR - Agency for Toxic Substances and Disease Registry (2007). Toxicological profile for lead. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    摘要:L21: Wikipedia. Lead poisoning. Last Updated 3 March 2009.
    摘要:L625: Wikipedia. Bromine. Last Updated 9 June 2009. http://en.wikipedia.org/wiki/Bromine
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