CAS: 111-70-6; 1-Heptanol

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112-06-1 24767-82-6 106-30-9

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CAS号111-71-7 正庚醛 | CAS号592-41-6 1-己烯 | CAS号124-38-9 二氧化碳 | CAS号503-30-0 三甲氧基酯 | CAS号109-72-8 正丁基锂 | CAS号115306-89-3 1-[(tert-butyld... | CAS号18132-93-9 1-(Trimethylsil... | CAS号201230-82-2 carbon monoxide | CAS号110-54-3 正己烷 | CAS号132336-04-0 2-heptoxyoxane | CAS号5063-65-0 1,2-环氧庚烷 | CAS号33758-34-8 氯甲酸庚酯 | CAS号4282-40-0 1-碘庚烷 | CAS号3152-43-0 (3R,4R)-3,4-Dih... | CAS号6743-60-8 1-heptyl 2,3,4-... | CAS号40782-54-5 4-庚氧基苯甲酰氯 | CAS号37529-27-4 4-庚基苯胺 | CAS号462-18-0 7-十三酮 | CAS号624-09-9 庚酸庚酯 | CAS号42598-96-9 乙酰乙酸庚酯

正庚烷置于亚碘酰苯,[5,10,15,20-Tetrakis(4-Hydroxy-3-Methoxyphenyl)Porphyrinato]Manganese(III) Acetate体系中,用 二氯甲烷,乙腈 用作溶剂,化学反应 1.0H,以13%的收率获得正庚醇
参考文献:Manganese Porphyrin In Solution And Heterogenized In Different Materials Mediates Oxidation Of Hydrocarbons By Iodosylbenzene
标题:Manganese Porphyrin In Solution And Heterogenized In Different Materials Mediates Oxidation Of Hydrocarbons By Iodosylbenzene
摘要:We Prepared A Free Base Porphyrin (Hp) Containing Hydroxy And Methoxy Groups In The Mesophenyl Substituents Of The Porphyrin Ring. We Then Inserted Mn(III) Ion Into The Resulting Hp,To Obtain Mnp. We Used Silica Synthesized By The Sol-Gel Process To Immobilize The Mnp In Either Acidic Or Basic Medium,Which Afforded The Solids Mnpa And Mnpb,Respectively. We Also Conducted The Solvothermal Mn(III) Ion Insertion Into Hp,Which Furnished The Self-Structured Solid Mnps. Because The Mnp Was Catalytically Active In Homogeneous Medium,We Investigated The Activity Of All The Prepared Solids As Heterogeneous Catalysts In The Oxidation Of Various Hydrocarbons. Mnpa,Mnpb,And Mnps Presented Similar Or Higher Activity Than The Homogeneous Mnp In The Oxidation Of Cyclooctene,Cyclohexene,Cyclohexane And N-Heptane. Concerning Alkane Oxidation,The Heterogeneous Catalysts Were More Selective For The Alcohol Than The Mnp In Homogeneous Solution. Moreover,The Solid Catalysts Favored The Oxidation Of Linear Alkane,With Selectivity Toward The Primary Alcohol. We Were Able To Recover All The Solids At The End Of The Reaction And Reuse Them. (C) 2013 Elsevier B.V. All Rights Reserved.
Doi:10.1016/j.Molcata.2013.06.022

专利信息

专利号:US-7247752-B2
优先权日:2004-10-01
标 题 :Methods for the synthesis of astaxanthin
发明人：LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
权利人:CARDAX PHARMACEUTICALS INC
摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

专利号:US-10696622-B2
优先权日:2016-08-29
标题 :Synthesis of N-vinyl carboxylic acid amides
发明人：DUMOLEIJN KIM; MOONEN KRISTOF; Henricot Alexis; Han Cai Xing Simon
权利人:TAMINCO BVBA; EASTMAN CHEM CO
摘要:Processes and systems for producing N-vinyl carboxylic acid amides are provided herein. According to some aspects of the present invention, a process for producing an N-vinyl carboxylic acid amide is described that eliminates interim solids handling steps during formation of the intermediate compounds, thereby increasing efficiency and reducing cost. The processes and system described herein may be used for the synthesis of N-vinylformamide and its intermediates, including 1-hydroxyethylformamide and 1-alkoxyethylformamide, or for the synthesis of N-methyl,N-vinylformamide and its intermediates, including N-methyl,1-hydroxyethylformamide and N-methyl,1alkoxyethylformamide.

专利号:WO-03031376-A1
优先权日:2001-10-12
标 题 :Solid phase synthesis of substituted 1,5-benzodiazepine-2-one and 1,5-benzothiazepine-2-one
发明人：MORTON GEORGE C; SALVINO JOSEPH M; LABAUDINIERE RICHARD F; HERPIN TIMOTHY F
权利人:AVENTIS PHARMA INC; MORTON GEORGE C; SALVINO JOSEPH M; LABAUDINIERE RICHARD F; HERPIN TIMOTHY F
摘要:A solid phase synthetic method for making substituted 1,5-benzodiazepine-2-one or 1,5-benzothiazepine-2-one. The method is useful for synthesis of large numbers of compounds through automated parallel synthesis or combinatorial library generation and is thus important to rapid discovery or new therapeutic agents containing the base structure of 1,5-benzodiazepine-2-one or 1,5-benzothiazepine-2-one.

专利号:US-7138526-B1
优先权日:1999-06-15
标 题 :Solid phase synthesis of n,n-disubstituted diazacycloalkylcarboxy derivatives
发明人：HERPIN TIMOTHY F; MORTON GEORGE C; SALVINO JOSEPH M
权利人:AVENTIS PHARMA INC
摘要:A method for the solid phase synthesis of N,N-disubstituted diazacycloalkylcarboxy derivatives of general formula (I) and (II) is claimed. Examples include piperazine-2-carboxamide. The method is applicable to the synthesis or large combinatorial libraries

专利号:US-10730904-B2
优先权日:2012-11-14
标 题:Method for liquid-phase synthesis of nucleic acid
发明人：NONOGAWA MITSURU; NAGATA TOSHIAKI; SAITO HIDEKI; YASUMA TSUNEO
权利人:TAKEDA PHARMACEUTICALS CO
摘要:In this method, an oligonucleotide represented by formula (II) [wherein Y 1 , Q, Base, r and r′ are each as defined in claim 1 ] is prepared by using, as a synthesis unit, a novel nucleoside monomer compound represented by formula (I) [wherein X, R 1 , Y, Base, Z, Ar, R 2 , R 3 and n are each as defined in claim 1 ]. The novel nucleoside monomer compound is a nucleoside, the base moiety of which is substituted with an aromatic-hydrocarbon-ring-carbonyl or -thiocarbonyl group having at least one hydrophobic group. The method can dispense with column-chromatographic purification in every reaction, and enables base elongation not only in the 3′-direction but also in the 5′-direction, thus attaining efficient liquid-phase mass synthesis of an oligonucleotide.

专利号:US-2004072282-A1
优先权日:2002-10-15
标题:Synthesis of membrane proteins
发明人：GUARNIERI FRANK; KULP JOHN; CHIANG WILLIAM
权利人:SARNOFF CORP
摘要:Methods for chemical ligation and synthesis of peptides and polypeptides including membrane polypeptides and hydrophobic peptides and polypeptides or membrane polypeptide domains in a multiphase solvent mixture comprising at least two component solvents; compositions produced using these methods and assays performed using these compositions.