CAS: 937082-81-0; 9-(4-Bromophenyl)-9-Phenyl-9H-Fluorene

该化合物是一种有机化合物,其独特的结构特征是,含有一种由4-溴苯基组和9级苯基组替代的氟烯核心,在9个位置上,该化合物通常具有与芳香化合物相关的特性,例如稳定性和参加电益替代反应的趋势,其分子结构有助于其在有机电子中的潜在应用,特别是在有机发光二极管(OLEDs)和有机光伏发电(OLEDs)和有机光伏击中的潜在应用,因为它能够促进充电运输和光源排放.溴原子的存在可增强其在各种有机溶剂中的再活性和溶性.此外,该化合物还可能显示出有趣的光物理特性,包括荧光性,这种特性可能受到周围环境和亚种成分的性质的影响.

英文名称9-(4-Bromophenyl)-9-Phenyl-9H-Fluorene
中文名称9-(4-溴苯基)-9-苯基芴
IUPAC名称9-(4-bromophenyl)-9-phenyl-9H-fluorene
其它别名9-(4-溴苯基)-9-苯基-9H-芴
CAS编号937082-81-0
MFCD编号:MFCD28975087
EINECS号:823-789-0
分子式:C25H17Br
分子量:397.32
产品CID: 1977152
产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

相似结构搜索
InChIKey: OOKRYIPMHLUQHU-UHFFFAOYSA-N
InChI=1S/C25H17Br/c26-20-16-14-19(15-17-20)25(18-8-2-1-3-9-18)23-12-6-4-10-21(23)22-11-5-7-13-24(22)25/h1-17H…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数2.0

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别皮肤腐蚀/刺激类别2
严重眼刺激类别2
警示词Warning(警告)
危险描述H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
安全声明H303+H313+H110

欧盟法规

C&L通报

上下游产品

9-苯基芴 9-Phenylfluorene 789-24-2
9-(4-Bromophenyl)-9H-Fluoren-9-Ol 79653-80-8
9-苯基-9-芴醇 9-Phenyl-Fluoren-9-Ol 25603-67-2
9-溴-9-苯基芴 9-Bromo-9-Phenyl-9H-Fluorene 55135-66-5
9-芴酮 9-Fluorenone 486-25-9

合成工艺路线路线简述

1629589-22-5 = 937082-81-0
反应条件:1.1 Catalysts: P-Toluenesulfonic Acid Solvents: Toluene; 3 H,Reflux; Reflux -> Rt1.2 Reagents: Sodium Bicarbonate Solvents: Water; Neutralized
标题:Organic Light-Emitting Elements For Lighting Apparatus,Light-Emitting Apparatus,Imaging Device,And Electronic Devices,And Biphenylfluorenylamine
参考文献:Japan]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium Solvents: Diethyl Ether; Rt; Heated; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; Heated; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate; 2 H,Rt1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid; Heated; 1.5 H,130 °C
标题:Heterocyclic Compound,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
参考文献:United States]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether; Rt; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; Acidified; 2 H1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 1.5 H,130 °C
标题:Organic Light-Emitting Components,Organometallic Complexes,Light-Emitting Devices,Electronic Appliances,And Lighting Devices
参考文献:World Intellectual Property Organization]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Heated; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Reflux; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 1.5 H,130 °C
标题:Composite Material,Light-Emitting Element,Light-Emitting Device,Lighting Device,Electronic Device,And Fluorene Derivative
参考文献:United States]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Rt; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; 1.5 H,130 °C
标题:Organometallic Complex,And Light-Emitting Element And Display Device Using The Organometallic Complex
参考文献:United States]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium Solvents: Diethyl Ether; Rt; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Acidified,Rt1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid; 1.5 H,130 °C
标题:Organometallic Complex,Light-Emitting Element,Light-Emitting Device,Electronic Device And Lighting Device
参考文献:World Intellectual Property Organization]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether,1,2-Dibromoethane1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; 1.5 H,130 °C
标题:Organometallic Complex,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
参考文献:United States]

106-37-6 + 789-24-2 = 937082-81-0
反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: Tert-Butyldiphenylphosphine,Tris(Dibenzylideneacetone)Dipalladium Solvents: Toluene; 12 H,100 °C1.2 Reagents: Water
标题:Palladium-Catalyzed Direct Arylation Of C-H Bond To Construct Quaternary Carbon Centers: The Synthesis Of Diarylfluorene
作者:Cao,Xiao; Yang,Weidong; Liu,Chao; Wei,Fuliang; Wu,Kun; Et Al
参考文献:Organic Letters 日期:2013 卷标:15(12) 页码:3102-3105]

79653-80-8 = 937082-81-0
反应条件:1.1 Reagents: Boron Trifluoride Etherate Solvents: Dichloromethane; Rt; 30 Min,Rt1.2 Reagents: Ethanol,Water
标题:Fluorene-Containing Compounds And Their Application In Oleds
参考文献:China]

79653-80-8 = 937082-81-0
反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Benzene; 50 °C; 2 H,50 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water; Neutralized
标题:Heterocyclic Compounds For Optoelectric Devices And Compositions For Optoelectric Devices And Organic Optoelectric Devices And Display Devices Using Them
参考文献:European Patent Organization]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Heated; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; 1.5 H,130 °C
标题:Benzo[b]Naphtho[1,2-D]Furan Compound As Light-Emitting Materials For Electroluminescent Devices
参考文献:United States]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Rt; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Acidified,Rt1.4 Reagents: Acetic Acid,Hydrochloric Acid Solvents: Water; 1.5 H,130 °C
标题:Carbazole Derivatives
参考文献:United States]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Heated; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; Heated; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 2 H,Acidified,Rt1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 1.5 H,130 °C
标题:Organic Light-Emitting Devices Employing Carbazole Derivatives
参考文献:World Intellectual Property Organization]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: 1,2-Dibromoethane,Magnesium Solvents: Diethyl Ether; Heated; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Reflux; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Acidified,Rt1.4 Reagents: Acetic Acid; 1.5 H,130 °C
标题:Light-Emitting Elements With Multiple Emitting Layers And Electron Relay Layers And Displays And Lighting Devices And Electronic Devices Using Them
参考文献:World Intellectual Property Organization]

90-90-4 + 2052-07-5 = 937082-81-0
反应条件:1.1 Reagents: Magnesium Catalysts: 1,2-Dibromoethane Solvents: Diethyl Ether; Rt; 2.5 H,Reflux1.2 Solvents: Diethyl Ether; Rt; 9 H,Reflux1.3 Reagents: Hydrochloric Acid Solvents: Ethyl Acetate,Water; 2 H,Rt1.4 Reagents: Hydrochloric Acid Solvents: Acetic Acid,Water; 1.5 H,130 °C
标题:Fluorene Derivative,Light-Emitting Element,Light-Emitting Device,Electronic Device,And Lighting Device
参考文献:European Patent Organization]

79653-80-8 = 937082-81-0
反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Benzene; Rt; 48 H,Reflux
标题:9,9-Diphenylfluorene Derivatives And Organic Optoelectric Devices Using Them And Display Devices Using The Optoelectric Devices
参考文献:United States]

1629589-22-5 = 937082-81-0
反应条件:1.1 Reagents: Acetic Acid,Hydrochloric Acid; 2 H,130 °C
标题:Preparation Of Fluorene Derivatives As Organic Electroluminescence Device Materials
参考文献:Korea]

1629589-22-5 = 937082-81-0
反应条件:1.1 Reagents: Sodium Phosphite Solvents: Dimethylformamide; 1 H,Rt -> 120 °C
标题:Method For Preparing Substituted Aryl Fluorene And Its Derivatives
参考文献:China

9-溴-9-苯基芴置于四(三苯基膦)钯,正丁基锂,Sodium Carbonate体系中,用四氢呋喃,乙醇,水,甲苯作为反应溶剂,化学反应 8.0H,反应生成 9-(4-溴苯基)-9-苯基芴
参考文献:一种芴类有机化合物及其在oled器件上的应用
标题:一种芴类有机化合物及其在oled器件上的应用
摘要:本发明涉及一种芴类有机化合物及其在oled器件上的应用,所述化合物的结构为芴通过碳碳键与苯并六元环并六元环结构相连,碳碳键连接既提高了材料化学稳定性又避免了支链基团活泼位置裸露,而且整个分子是一个较大的刚性结构,具有较高的三线态能级(T1);且空间位阻大,不易转动,立体空间结构更稳定,因此化合物具有较高的玻璃化温度和分子热稳定性;另外,本发明化合物的homo和lumo分布位置相互分开,使其具有了合适的homo和lumo能级;因此,本发明化合物应用于oled器件后,可有效提升器件的发光效率及使用寿命.