CAS: 591-20-8; 3-Bromophenol

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CAS号89598-96-9 3-溴苯硼酸 | CAS号2398-37-0 间溴苯甲醚 | CAS号2655-84-7 间溴苯乙醚 | CAS号53087-13-1 3-苄氧基溴苯 | CAS号591-19-5 3-溴苯胺 | CAS号591-18-4 1-溴-3-碘苯 | CAS号108-86-1 溴苯 | CAS号106-41-2 对溴苯酚 | CAS号10540-41-7 4'-Fluoro-3-bip... | CAS号107396-23-6 3-(Diphenylamin... | CAS号36971-28-5 (3-溴苯氧基)三甲基硅烷 | CAS号38191-34-3 2-氨基-5-溴苯酚 | CAS号5470-65-5 3-溴-4-硝基苯酚 | CAS号27684-84-0 2-硝基-5-溴苯酚 | CAS号35065-86-2 3-溴乙酸苯酯 | CAS号30186-18-6 4-溴-2-羟基苯乙酮 | CAS号34068-01-4 3-苄氧基苯乙酮 | CAS号43192-33-2 4-溴-2-甲氧基苯甲醛

2-Diazocyclohexane-1,3-Dione置于tris(Triphenylphosphine)Ruthenium(II) Chloride,草酰溴体系中,用 氟苯 作为反应溶剂,化学反应 10.0H,以68%的收率获得产物间溴苯酚
参考文献:钌(II)催化的重氮二羰基化合物制备各种α,β-和β,β-二卤代烯酮的方案
标题:钌(II)催化的重氮二羰基化合物制备各种α,β-和β,β-二卤代烯酮的方案
摘要:Abstractefficient One‐step Syntheses Of α,β‐ And β,β‐dihaloenones Were Achieved By Ruthenium(II)‐catalyzed Reactions Between Cyclic Or Acyclic Diazodicarbonyl Compounds And Oxalyl Chloride Or Oxalyl Bromide In Moderate To Good Yields. This Methodology Offers Several Significant Advantages,Which Include Ease Of Handling,Mild Reaction Conditions,One‐step Reaction,And The Use Of An Effective And Non‐toxic Catalyst. The Synthesized Compounds Were Further Transformed Into Highly Functionalized Novel Molecules Bearing Aromatic Rings On The Enone Moiety Using The Suzuki Reaction.Magnified Image
DOI:10.1002/adsc.201400348

专利信息

专利号:US-7164018-B2
优先权日:2001-01-29
标 题 :Polymers based on N-carbamyl-N'-dimethylsilyl methyl-piperazine traceless linkers for the solid phase synthesis of phenyl based libraries
发明人：CEREDA ENZO; PELLEGRINI CARLO MARIA; QUAI MONICA; BARBAGLIA WALTER
权利人:BOEHRINGER INGELHEIM INT
摘要:The present invention relates to polymers characterized by novel silicon linkers based on the carbamyl piperazine moiety, methods of preparing these polymers and their use in the solid phase synthesis of compounds or libraries of compounds embracing a phenyl ring in their structure.

专利号:US-10254287-B2
优先权日:2015-07-21
标题 :Protein fluorescent nanoparticles and methods of synthesis thereof
发明人：KUMAR CHALLA VIJAYA; STROMER BOBBI SHANYELLE
权利人:UNIV CONNECTICUT
摘要:Disclosed herein are stable and versatile protein nanoparticles having a range of tunable fluorescent properties. Such nanoparticles may find utility in biological imaging. Methods of synthesis of such nanoparticles are also disclosed.

专利号:US-2022356182-A1
优先权日:2009-03-27
标题 :Inhibitors of hepatitis c virus replication
发明人：COBURN CRAIG A; LUDMERER STEVEN W; LIU KUN; WU HAO; SOLL RICHARD; ZHONG BIN; ZHU JIAN
权利人:MERCK SHARP & DOHME
摘要:The present invention relates to compounds of formula (I) that are useful as hepatitis C virus (HCV) NS5A inhibitors, the synthesis of such compounds, and the use of such compounds for inhibiting HCV NS5A activity, for treating or preventing HCV infections and for inhibiting HCV viral replication and/or viral production in a cell-based system.

专利号:US-7253324-B1
优先权日:2007-01-23
标 题:Process for the synthesis of biologically active oxygenated compounds by dealkylation of the corresponding alkylethers
发明人：MAJEED MUHAMMED; THOMAS SAMUEL MANOHARAN; NAGABHUSHANAM KALYANAM; BALAKRISHNAN SIVAPRAKASH KURUM; PRAKASH SUBBALAKSHMI
权利人:SAMI LABS LTD
摘要:Alkoxy aromatic compounds are conveniently dealkylated to the corresponding phenolic compounds by treatment with aluminum chloride/N,N-dimethyl aniline complex. Aromatic poly O-demethylation is a unique feature of this invention. This process is applicable to the manufacture of polyphenols such as Resveratrol, Oxyresveratrol, Gnetol.

专利号:US-2004110228-A1
优先权日:2002-04-01
标 题:Combinatorial organic synthesis of unique biologically active compounds
发明人：MCALPINE SHELLI R; TAYLOR RACHEL E; BOLLA MEGAN L; SEGALL ANCA M
摘要:The invention provides a method for making a combinatorial library of cyclic compounds, such as Holliday junction-trapping compounds, comprising the steps of (a) obtaining a plurality of trimers according to the generic structure X 1- X 2- X 3 , wherein X 1 , X 2 and X 3 can be independently any naturally or nonnaturally occurring amino acids or peptidomimetics thereof; (b) optionally coupling a spacer S to the trimer at either end; (c) cyclizing two trimers or trimer-spacer conjugates in a head-to-tail orientation; thereby obtaining a combinatorial library of compounds, wherein the library does not include an unmodifed or naturally occurring Holliday Junction-trapping compounds. The invention additionally provides methods macrocyclic compounds that are synergimycin derivatives.

专利号:US-4157344-A
优先权日:1978-01-16
标题 :Preparation of aryl trifluoromethyl ethers
发明人：FEIRING ANDREW E
权利人:DU PONT
摘要:A one-step process for the synthesis of aryl trifluoromethyl ethers by reacting phenol or certain substituted phenols with a perhalomethane and hydrogen fluoride is provided. The compounds produced by the process of this invention are useful intermediates in the production of dyestuffs and pharmaceuticals.