CAS: 558-20-3; Tetradeuteriomethane

该化合物是甲烷的稳定异族体,所有四个氢原子都由氢的较重同位素-取代.其化学配方为CD4,分子重量约为18.03克/摩尔.甲烷-d4是室内温度和压力的无色无味气体,类似于其非脱入式对应物.它主要用于科学研究,特别是核磁共振光谱学,因其独特的光谱特性而成为溶剂和参考标准.除化子的存在改变了分子的振动频率,使其对研究反应机制和分子动态有用.甲烷-d4还被用于有机化学和环境研究的各种应用,特别是在追踪研究和同位素标签方面.它与所有甲烷衍生物一样,是易燃的,应在受控制的环境中谨慎处理.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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CAS号7553-56-2 碘 | CAS号7647-01-0 盐酸

合成工艺路线路线简述

  • 合成目标产物 Methane-D4 主要起始原料 Methane, Ion(2+)
  • (文献来源)合成步骤主要原料 Methane, Ion(2+)
📜二氧化碳置于重水体系中,化学反应 3.0H,反应生成 甲烷-D4
参考文献:不锈钢球磨机中 Co2 与 H2O 的定量机械化学甲烷化
标题:不锈钢球磨机中 Co2 与 H2O 的定量机械化学甲烷化
摘要:在此,我们实现了在 H2O 存在下,通过不锈钢球的碰撞和摩擦介导的 Co2 到 Ch4 的几乎定量和选择性的机械化学转化,无需外部加热.
DOI:10.1246/bcsj.20200105

专利信息


专利号:US-2009234121-A1
优先权日:2008-01-16
标 题 :Tridentate (nnc) catalysts for the selective oxidation of hydrocarbons
发明人:PERIANA ROY A; GODDARD III WILLIAM A; OXGAARD JONAS; YOUNG KENNETH
权利人:PERIANA ROY A; GODDARD III WILLIAM A; OXGAARD JONAS; YOUNG KENNETH
摘要:The synthesis of discrete, air, protic, and thermally stable transition metal NNC complexes that catalyze the CH activation and functionalization of alkanes and arenes is disclosed. Methods for the selective conversion of methane to methanol or methyl esters in acidic and neutral media are disclosed.

专利号:US-4388095-A
优先权日:1980-07-21
标 题 :Method of producing a glass layer on an interior surface of a hollow body
发明人:SCHNEIDER HARTMUT; LEBETZKI EGON
权利人:SIEMENS AG
摘要:Glass preforms useful for producing optical fibers therefrom are produced by forming at least one layer of glass on an inner surface of a hollow glass tube by introducing a reactive gas mixture suitable for glass synthesis (ie., SiCl 4 , GeCl 4 , etc., and O 2 ) and a combustible heating gas mixture (ie., CO, C 2 N 2 , CS 2 , C 4 N 2 , COS, C 3 O 2 , etc., and O 2 ) into a hot region within the hollow tube which is generated by exterior heating of such tube. The reactive gas undergoes a chemical reaction at such hot region whereby a material having the composition of glass is deposited on the hot inner surface of the tube as a layer and melts into a clear glass film while the heating gas combusts at the hot region and aids the rate of glass formation on the inner surface of the tube.

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📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1007/978-981-13-6967-4_6
摘要:Xu J, Wang Q, Li S, Deng F. In Situ Solid-State NMR Investigation of Catalytic Reactions on Zeolites. 2019. In: Lecture Notes in Chemistry.
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