CAS: 4525-44-4; Ethylmethyldichlorosilane

该化合物是一种氯硅烷化合物,广泛用作有机合成和硅酮生产的中间体,其反应性二氯硅烷组能够在硅氧烷聚合物中进行有效交叉联系和功能化,而乙基和甲基替代成分则有助于量身定制的疏水和消毒效应.该化合物在地表改造,粘合促进和特殊硅酮合成方面特别宝贵.其高纯度和连续的再活动使其适合于需要精确控制分子结构的应用.由于其湿度敏感度和腐蚀性,需要惰性大气储存和使用过程中的无水条件,妥善处理是必不可少的.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号115-21-9 乙基三氯硅烷 | CAS号75-78-5 二甲基二氯硅烷 | CAS号124-70-9 甲基乙烯基二氯硅烷 | CAS号75-54-7 甲基二氯硅烷 | CAS号54509-73-8 ethene | CAS号75-00-3 氯乙烷 | CAS号7440-21-3 硅 | CAS号75-79-6 甲基三氯硅烷 | CAS号925-90-6 乙基溴化镁 | CAS号75-77-4 三甲基氯硅烷 | CAS号15901-49-2 2,4,6-三乙基-2,4,6... | CAS号7623-01-0 2,4,6,8-tetraet... | CAS号17861-60-8 3-乙基七甲基三硅氧烷 | CAS号17940-62-4 3,5,7-triethyl-... | CAS号7787-84-0 1-CHLOROETHYLME... | CAS号7787-85-1 2-氯乙基甲基二氯硅烷

合成工艺路线路线简述

    📜甲基乙烯基二氯硅烷置于镍 氢气体系中,化学反应 6.0H,以91%的收率获得产物甲基乙基二氯硅烷
    参考文献:Picard,Jean-Paul; Dunogues,Jacques; Elyusufi,Abdelaziz,Synthetic Communications,1984,Vol. 14,# 2,P. 95-100
    标题:Picard,Jean-Paul; Dunogues,Jacques; Elyusufi,Abdelaziz,Synthetic Communications,1984,Vol. 14,# 2,P. 95-100

    海关参考信息

    专利信息


    专利号:US-6344578-B1
    优先权日:2000-08-10
    标题 :Process for working up residues from the direct synthesis of organochlorosilanes
    发明人:MAUTNER KONRAD; KOEHLER BERND; TAMME GUDRUN
    权利人:WACKER CHEMIE GMBH
    摘要:The invention relates to a process for preparing alkylchlorosilanes from the liquid constituents of the residues from the direct synthesis of alkylchlorosilanes which have a boiling point of above 70° C. at 1013 hPa and comprise disilanes, in which the residues are heated with hydrogen chloride and silicon at temperatures of at least 300° C., with at least 10% by weight of trichlorosilane and/or tetrachlorosilane, based on the weight of the alkylchlorosilanes formed, being formed at the same time.

    专利号:US-11033507-B2
    优先权日:2013-12-19
    标 题 :Method of synthesis of silica vesicles and use thereof
    发明人:YU CHENGZHONG; MITTER NEENA; ZHANG JUN
    权利人:UNIV QUEENSLAND
    摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

    专利号:US-4552973-A
    优先权日:1984-03-23
    标题 :Process for the preparation of dimethyldichlorosilane
    发明人:FELDNER KURT; GRAPE WOLFGANG
    权利人:BAYER AG
    摘要:A process for the preparation of dimethyldichlorosilane from the low-boiling and high-boiling by-products of the direct synthesis of methylchlorosilane, comprising reacting methyltrichlorosilane simultaneously with the low-boiling components having a high content of methyl groups and with the high-boiling non-cleavable components, in the presence of a catalyst, at a temperature between about 250° C. and 400° C. and under a pressure of up to 100 bar.

    专利号:US-5538618-A
    优先权日:1993-06-17
    标 题:Process for the electrochemical synthesis of organosilicon compounds, and an appliance for carrying out the process, and use thereof for preparing organosilicon compounds
    发明人:HENGGE EDWIN; JAMMEGG CHRISTA; KALCHAUER WILFRIED
    权利人:WACKER CHEMIE GMBH
    摘要:A process is described for the electrochemical preparation of organosilicon compounds having at least one SiC-bound organic radical, a solution which contains at least one halosilane being subjected to an electrochemical reaction, an anode which contains a noble metal or an alloy consisting essentially of one or more noble metals having a halogen scavenger flowing around said anode.

    专利号:RU-2036926-C1
    优先权日:1992-05-20
    标题 :Method of synthesis of monomers containing functional groups for synthesis of polyethylsiloxane liquids

    专利号:US-2022355262-A1
    优先权日:2019-07-22
    标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
    发明人:SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
    权利人:KROSSLINKER PTE LTD
    摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Catalytic Synthesis Of Functional Silicon-Stereogenic Silanes ThroughCandida AntarcticaLipase B Catalyzed Remote Desymmetrization Of Silicon-Centered Diols
    作者:Xing Lu,Li Li,Wei Yang,Kezhi Jiang,Ke-Fang Yang,Zhan-Jiang Zheng,Li-Wen Xu |发布日期:2013.9
    摘要:A Series Of Silicon-Containing Diols Are Synthesized And Used In Lipase-Catalyzed Remote Desymmetrization. This Synthetic Method Is Valuable In The Construction Of Optically Active Silicon-Stereogenic Organosilicon Compounds. Good Enantioselectivities Of The Remote Desymmetrization Was Achieved With Candida Antarctica Lipase B (Cal-B) (Up To 90:10Er).

    合成参考文献


    参考文献:10.1007/978-981-16-1892-5_17
    摘要:Koiry SP, Chauhan AK. Synthesis Strategies for Si-Based Advanced Materials and Their Applications. 2021. In: Indian Institute of Metals Series.
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