专利号:US-4794199-A 优先权日:1984-07-05 标题:Process for synthesis of primary amines from olefins, syngas and ammonia 发明人:LIN JIANG-JEN; KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention concerns the synthesis of primary amines from olefins, synthesis gas and ammonia via an amination process in the presence of a cobalt catalyst, an ether solvent and a tertiary group VB donor ligand.
专利号:US-10626091-B2 优先权日:2014-10-01 标 题 :Process for the preparation of enzalutamide 发明人:CHIVUKULA KAMESWAR RAO; KARUTURI VEERA VENKATESWARA RAO; BENDA SRINIVAS; ANKE RAMACHANDRA; GAJULA DHARMAPURI; MOTURU VENKATA RAMA KRISHNA MURTHY; INDUKURI VENKATA SUNIL KUMAR; GORANTLA SEETA RAMA ANJANEYULU; CHAVA SATYANARAYANA 权利人:LAURUS LABS LTD 摘要:The present invention relates to an improved process for the preparation of enzalutamide by conventional synthesis, which avoids utilization of microwave irradiation and noxious reagents. The present invention also relates to an improved process for preparation of 4-isothiocyanato-2-(trifluoromethyl) benzonitrile, which is an intermediate in the synthesis of Enzalutamide.
专利号:WO-2025004059-A1 优先权日:2023-06-30 标题:Synthesis of polyether polyols based low dosage gas hydrate inhibitors using double metal cyanide catalyst 发明人:KUMAR UMESH; KUMAR ASHEESH; VERMA AKASH; DUBEY SADHBHAWANA; KUMAR SANAT; GANGULY SUDIP KUMAR 权利人:COUNCIL SCIENT IND RES 摘要:A series of different metals (Zn/Fe/Co/Sn/Mg/La/Al/Cr) based double metal cyanide (DMC) catalyst is disclosed herein. Benzene-1,3,5-tricarboxylic acid (BTC) is incorporated as an organic complexing agent (CA) in the DMC catalyst. The DMC catalysts prepared with BTC and its derivatives as CAs are highly active towards ring opening polymerization (ROP) of propylene oxide (PO) and imparts heterogeneity as compared to the DMC prepared without any CA. The polyether polyols (PEPOs) with controlled molecular weight (Mw), polydispersity index (PDI), hydroxyl value (OH), and iodine value (I2) are produced using a DMC catalyst. PEPOs of the present invention relate to low-dosage gas hydrate inhibitors (LDHIs) utilized to mitigate/manage the formation, growth, and deposition/agglomeration of gas hydrate crystals in oil and gas production pipelines (especially applicable to deep and ultra-deep developments), and drilling or fracturing operations during natural gas hydrate exploration.
专利号:US-4433176-A 优先权日:1982-02-01 标 题:Process for preparing acetaldehyde from methanol and synthesis gas using a novel catalyst composition 发明人:LIN JIANG-JEN; KNIFTON JOHN F 权利人:TEXACO INC 摘要:Acetaldehyde is prepared in good yield from methanol and synthesis gas under mild reaction conditions by contacting a mixture of methanol, carbon monoxide and hydrogen with an iodide or iodine free catalyst composition comprising (1) ruthenium powder, (2) a cobalt-containing compound (3) a rhodium-containing compound, and (4) an onium salt or base, and heating the resulting mixture under mild temperature and pressure for sufficient time to produce the desired acetaldehyde, and then recovering the same from the reaction mixture.
专利号:US-4433178-A 优先权日:1982-02-01 标题 :Process for preparing acetaldehyde from methanol and synthesis gas using a novel catalyst composition 发明人:LIN JIANG-JEN; KNIFTON JOHN F 权利人:TEXACO INC 摘要:Acetaldehyde is prepared in good yield from methanol and synthesis gas by contacting the mixture of methanol, carbon monoxide and hydrogen with an iodide or iodine-free catalyst composition comprising ruthenium powder, a cobalt-containing compound and an onium salt or base, and heating the resulting mixture to an elevated temperature and pressure for sufficient time to produce the acetaldehyde, and then recovering the same from the reaction mixture.
专利号:US-2023340197-A1 优先权日:2022-04-22 标题 :Schiff base incorporated double metal cyanide catalyst for the production of polyether polyols 发明人:KUMAR UMESH; VERMA AKASH; SHARMA BHAWNA; KUMAR AMOD; SWATI; SENTHILKUMAR THANGARAJ; GANGULY SUDIP KUMAR; RAY ANJAN 权利人:COUNCIL SCIENT IND RES 摘要:A double metal cyanide [DMC] catalyst and a method for the synthesis thereof at room temperature is disclosed herein. Various Schiff bases are incorporated as organic complexing agents in the DMC catalysts. The catalysts of the present invention are highly active for the ring opening polymerization (ROP) of epoxides in the presence of different H-functional initiators to produce polyether polyols (PEPO) with a wide range of average molecular weight (Mw) and polydispersity index (PDI).
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