CAS: 17831-71-9; ((Oxybis(Ethane-2,1-Diyl))Bis(Oxy))Bis(Ethane-2,1-Diyl) Diacrylate

上下游产品

acrylic acid methyl ester tetraethylene glycol monoacrylate

📜丙烯酸甲酯(ma),2-[2-[2-(2-羟基乙氧基)乙氧基]乙氧基]乙基丙烯酸酯置于4-二甲氨基吡啶,Oxo[hexa(Trifluoroacetato)]Tetrazinc体系中,用 Neat (No Solvent) 用作溶剂,化学反应 48.0H,以84%的收率获得四甘醇二丙烯酸酯
参考文献:丙烯酸酯衍生物的化学选择性酯交换,用于使用硬锌醇盐生成策略合成官能化单体
标题:丙烯酸酯衍生物的化学选择性酯交换,用于使用硬锌醇盐生成策略合成官能化单体
摘要:为了制备功能性聚合物,探索了一种合成功能化丙烯酸酯衍生物的实用新方法.硬锌醇盐生成使丙烯酸酯衍生物的高度化学选择性酯交换超过不希望的共轭加成,这会导致聚合.催化锌簇 Zn4(ococf3)6O 和 4-(二甲氨基)吡啶的联合使用通过在温和条件下将市售的丙烯酸甲酯衍生物与官能化醇进行酯交换,提供了各种官能化丙烯酸酯衍生物.
Doi:10.1002/ejoc.201600737

专利信息

专利号:US-2005019747-A1
优先权日:2002-08-07
标 题 :Nanoliter-scale synthesis of arrayed biomaterials and screening thereof
发明人：ANDERSON DANIEL G; LEVENBERG SHULAMIT; LANGER ROBERT S
摘要:A method of screening cell-polymer interactions. The method includes depositing monomers as a plurality of discrete elements on a substrate, causing the deposited monomers to polymerize, thereby creating an array of discrete polymer elements on the substrate, incubating the substrate in a cell-containing culture medium, and characterizing a predetermined cell behavior on each polymer element.

专利号:US-2012267111-A1
优先权日:2009-12-30
标题 :Synthesis of Degradable Polymers Downhole for Oilfield Applications
发明人：KHLESTKIN VADIM KAMIL EVICH
权利人:KHLESTKIN VADIM KAMIL EVICH
摘要:A method is given for polymerizing monomers downhole to create well treatment polymers. The monomers each contain two polymerizable groups and a degradable group or groups which allow the polymer to degrade under downhole conditions, for example by hydrolysis. Polymerization downhole allows easier, more precise, placement of polymer. Polymer obtained from monomers pumped downhole may be used, for example, for fluid diversion plugs, isolation plugs, formation consolidation, flowback control, and fluid loss control. Synthesized polymer may form gels, films, solids or other structure in treated wellbores, fractures, and/or formations. After the desired effect is achieved, the deposited polymer degrades and the polymer degradation products dissolve, leaving the wellbore, fracture and/or formation clean, with no damage that might have decreased fluid flow.

专利号:US-9193682-B2
优先权日:2013-04-05
标题:Synthesis of trithiocarbonates and allyl sulfides and their application into advances in covalent adaptable networks
发明人：FENOLI CHRISTOPHER R; BOWMAN CHRISTOPHER N
权利人:FENOLI CHRISTOPHER R; BOWMAN CHRISTOPHER N
摘要:Monomers having a C-B-A-B-C structure are disclosed, where A is a core of either trithiocarbonate and allyl sulfide, where B are linker units, and where C are end units. The end units may comprise acrylates, methacrylates, alcohol(s), amine(s), and alkynes, among others. The linker units may include an alkane, alkene, phenyl, diphenyl, or benzylic group, among others. Methods of synthesizing such compounds are also disclosed.

专利号:US-4732945-A
优先权日:1986-10-15
标题 :Synthesis by reacting oxirane resin with carboxyl compounds
发明人：DAMMANN LAURENCE G
权利人:ASHLAND OIL INC
摘要:Disclosed is a new partial capping synthesis wherein resinous mixtures containing controlled amounts of phenolic hydroxyl and/or mercapto functionality, and aliphatic hydroxyl functionality are synthesized. Such synthesis comprises providing one or more resins which in total contain aliphatic primary and/or secondary hydroxyl functionality and oxirane functionality. A single resin or blend of resins may provide the requisite functionality. The one or more resins then are reacted with a carboxyl-functional capping agent bearing phenolic hydroxyl functionality and/or mercapto functionality. This reaction is conducted under reaction conditions and for a time such that the carboxyl functionality of the capping agent selectively reacts with the oxirane functionality of the one or more resins to produce a resinous product containing aliphatic hydroxyl functionality and containing phenolic hydroxyl functionality and/or mercapto functionality.

专利号:US-4826617-A
优先权日:1986-10-15
标题:Selective resin synthesis and dual functional resins made thereby
发明人：DAMMANN LAURENCE G
权利人:ASHLAND OIL INC
摘要:Disclosed is a new partial capping synthesis wherein resinous mixtures containing controlled amounts of phenolic hydroxyl and/or mercapto functionality, and aliphatic hydroxyl functionality are synthesized. Such synthesis comprises providing one or more resins which in total contain aliphatic primary and/or secondary hydroxyl functionality and oxirane functionality. A single resin or blend of resins may provide the requisite functionality. The one or more resins then are reacted with a carboxyl-functional capping agent bearing phenolic hydroxyl functionality and/or mercapto functionality. This reaction is conducted under reaction conditions and for a time such that the carboxyl functionality of the capping agent selectively reacts with the oxirane functionality of the one or more resins to produce a resinous product containing aliphatic hydroxyl functionality and containing phenolic hydroxyl functionality and/or mercapto functionality.

专利号:US-2003144467-A1
优先权日:2001-10-12
标题:Matrix solid-phase organic synthesis
发明人：MELDAL MORTEN; MIRANDA LESLIE P
摘要:The present invention relates to a polymer matrix comprising a backbone of linked macromonomers, wherein said macromonomers are selected from the group consisting of triethylene glycols, tetraethylene glycols, and pentaethylene glycols, including any derivative and/or combination thereof. The polymer matrix of the present invention has a high-loading capacity while still being able to swell in small volumes of organic and aqueous solvents; it forms beads effectively so as to provide a resin of homogeneous size and shape; and it is more stable both chemically and physically than state of the art resins. One preferred type of SPOCC resin according to the present invention comprises short chained ethylene glycol macromonomers, including tetraethylene glycol (TEG 194 ), or derivatives thereof.