CAS: 16529-56-9; 2-Methylbut-3-Enenitrile

相似化合物

53774-20-2 20626-49-7 59014-11-8

上下游产品

CAS号74-90-8 氢氰酸 | CAS号106-99-0 丁二烯 | CAS号75-86-5 丙酮氰醇 | CAS号188290-36-0 Thiophene(SIV) | CAS号109-75-1 3-丁烯腈 | CAS号74-88-4 碘甲烷 | CAS号563-52-0 3-氯-1-丁烯 | CAS号22037-73-6 3-溴-1-丁烯 | CAS号4894-61-5 巴豆基氯,主要为反式 | CAS号544-16-1 亚硝酸丁酯 | CAS号4403-61-6 2-甲基-2-丁烯腈 | CAS号4635-87-4 3-戊烯腈 | CAS号592-51-8 4-戊烯腈 | CAS号20068-02-4 (Z)-2-methyl-2-... | CAS号30574-97-1 (E)-2-Methyl-2-... | CAS号25899-50-7 顺-2-戊烯腈 | CAS号26294-98-4 2-Pentenenitrile | CAS号16529-66-1 3-戊烯腈 | CAS号16545-78-1 (Z)-pent-3-enen... | CAS号80-59-1 惕格酸

1,3-丁二烯 反应生成2-甲基-3-丁烯腈
参考文献:Manufacture Of Organic Nitriles
标题:Manufacture Of Organic Nitriles
摘要:通过将丁二烯与氢氰酸和铜盐与有机腈的复合催化剂反应,形成3-戊烯腈,然后进行氰化反应制备己二腈的制造过程中,用作铜的唯一腈络合剂的溶剂是3-甲基戊二腈,或者是3-甲基戊二腈与2-乙基琥珀二腈或与2-乙基琥珀二腈和己二腈的混合物.

专利信息

专利号:US-12331007-B2
优先权日:2021-10-15
标题 :Use of a multidentate phosphite ligand in the catalytic synthesis of adiponitrile
发明人：CHEN ZHIRONG; WU WENBIN; YIN HONG; ZHA ZENGSHI; WANG KEYAN; MA LI; HUANG GUODONG; ZHOU GUIYANG; XU YONG
权利人:ZHEJIANG NHU CO LTD; ZHEJIANG NHU SPECIAL MAT CO LTD; ZHEJIANG NHU NYLON MAT CO LTD
摘要:A multidentate phosphite ligand is used in the catalytic synthesis of adiponitrile. The ligand is represented by the following general formula (I). The method of catalytic synthesis of adiponitrile comprises primary hydrocyanation, isomerization, and secondary hydrocyanation reactions, wherein the catalyst adopted each comprises a phosphite ligand-nickel complex composed of a nickel precursor and a multidentate phosphite ligand. The ligand molecule has a higher electron cloud density, and the phosphorus content capable of participating in coordination in the ligand molecule per unit mass is higher, so that the catalytic activity of the catalyst is improved, and the amount of the catalyst is reduced.

专利号:US-8697902-B2
优先权日:2008-06-17
标 题:Preparation of nitriles from ethylenically unsaturated compounds
发明人：MASTROIANNI SERGIO
权利人:MASTROIANNI SERGIO; RHODIA OPERATIONS
摘要:A process for the hydrocyanation of a hydrocarbon-based compound having at least one site of ethylenic unsaturation into a nitrile compound includes reaction thereof, in a liquid medium, with hydrogen cyanide in the presence of a catalyst containing a metal element selected from among the transition metals and an organophosphorus ligand, wherein the organophosphorus ligand is a compound of formula (I): n n n n n n n n n n The subject process is particularly useful for the synthesis of adiponitrile from butadiene.

专利号:US-7470805-B2
优先权日:2002-12-23
标题:Process of synthesis of compounds having nitrile functions from ethylenically unsaturated compounds
发明人：ROSIER CECILE; MARION PHILIPPE; BOURGEOIS DAMIEN
权利人:RHODIA OPERATIONS
摘要:A process of hydrocyanation of diolefins such as butadiene is carried out in the presence of a catalytic system comprising a transition metal and mono- and pluri-dentate organophosphorus ligands. The reaction medium containing branched nitrites subsequently is isomerized in the absence of hydrogen cyanide.

专利号:US-8039660-B2
优先权日:2001-09-18
标 题:Method of producing nitrile compounds
发明人：BASSET JEAN-MARIE; CHAUVIN YVES; GALLAND JEAN-CHRISTOPHE; NICCOLAI GERALD; VALERIO CHRISTINE; VALLEE CHRISTOPHE
权利人:RHODIA POLYAMIDE INTERMEDIATES
摘要:The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.

专利号:US-3631191-A
优先权日:1970-04-08
标 题 :Synthesis of zero valent nickel-tetrakis triaryl phosphite complexes
发明人：KANE NEAL JAMES; BROCKWAY JOHN
权利人:DU PONT
摘要:THE PROCESS FOR PREPARING A ZERO VALENT NICKELPHOSPHITE COMPLEX BY REACTING A DIVALENT NICKEL COMPOUND WITH A REDUCING METAL IN THE PRESENCE OF A TRIARYL PHOSPHITE IN A SATURATED ALIPHATIC DINITRILE SOLVENT. THE REACTION MIXTURE SEPARATES INTO MULTIPLE PHASES, ONE OF WHICH CONTAINS THE DESIRED COMPLEX SUBSTANTIALLY FREE OF BY-PRODUCT AND ANOTHER PHASE CONTAINING THE BY-PRODUCT OF THE REDUCING ACTION.

专利号:US-9233917-B2
优先权日:2008-06-17
标题:Preparation of nitriles from ethylenically unsaturated compounds
发明人：MASTROIANNI SERGIO
权利人:MASTROIANNI SERGIO; INVISTA NORTH AMERICA SARL
摘要:A process for the hydrocyanation of a hydrocarbon-based compound having at least one site of ethylenic unsaturation into a nitrile compound includes reaction thereof, in a liquid medium, with hydrogen cyanide in the presence of a catalyst containing a metal element selected from among the transition metals and an organophosphorus ligand, wherein the organophosphorus ligand is a mixture of at least one monodentate organophosphite compound and at least one monodentate organophosphine compound; the subject process is especially useful for the synthesis of adiponitrile from butadiene.