CAS: 161024-80-2; (R)-3-((Tert-Butoxycarbonyl)Amino)-3-Phenylpropanoic Acid
- 英文名称(R)-3-((Tert-Butoxycarbonyl)Amino)-3-Phenylpropanoic Acid
- 中文名称(R)-3-((叔丁氧基羰基)氨基)-3-苯基丙酸
- IUPAC名称(R)-3-((tert-butoxycarbonyl)amino)-3-phenylpropanoic acid
- 其它别名Boc-D-3-氨基-3-苯基丙酸; Boc-R-3-Amino-3-Phenylpropionic Acid
- CAS编号161024-80-2
- MFCD编号:MFCD01320859
- EINECS号:973-299-7
- 分子式:C14H19NO4分子量:265.31
- 产品CID: 812240
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
相似化合物
14676-01-8 103365-47-5 209252-15-3物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS07;
注释: Exclamation mark - 危险类别特定目标器官毒性 - 单次接触 类别3
皮肤腐蚀/刺激 类别2
严重眼刺激 类别2
严重眼刺激 类别2A - 警示词Warning(警告)
- 危险描述H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激. - 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
- 危险等级IRRITANT
- UN编号NONH for all modes of transport
- 危险品标志Xi
- 安全声明24/25
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号24424-99-5 二碳酸二叔丁酯 | CAS号614-19-7 DL-β-苯丙氨酸 | CAS号271600-36-3 N-[phenyl(tolue... | CAS号3646-50-2 DL(±)-3-氨基-3-苯基-丙酸 | CAS号65451-19-6 (DL)-N-(Phenyla... | CAS号100-52-7 苯甲醛 | CAS号158807-47-7 (R)-N-叔丁氧羰基-3-氨...合成工艺路线路线简述
📜N-[phenyl(Toluene-4-Sulfonyl)Methyl]Tert-Butoxycarboxyamide置于ammonium Cerium(Iv) Nitrate,Lithium Diisopropyl Amide体系中,用 四氢呋喃,乙腈 用作溶剂,化学反应 17.25H,反应生成(R)-Boc-Beta-苯丙氨酸
参考文献:α-Oxymethyl Ketone Enolates For The Asymmetric Mannich Reaction. From Acetylene Andn-Alkoxycarbonylimines Toβ-Amino Acids
标题:α-Oxymethyl Ketone Enolates For The Asymmetric Mannich Reaction. From Acetylene Andn-Alkoxycarbonylimines Toβ-Amino Acids
摘要:
Doi:10.1002/(Sici)1521-3773(20000317)39:6<1063::Aid-Anie1063>3.0.Co;2-Y
海关参考信息
- 2902600000-乙苯
2905122000-异丙醇
2905143000-叔丁醇
2912110000-甲醛 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2019276389-A1
优先权日:2015-12-18
标题:Synthesis of aryl cyclohexane ester derivatives useful as sensates in consumer products
发明人：WOS JOHN AUGUST; YELM KENNETH EDWARD; BUNKE GREGORY MARK; FREDERICK HEATH ALAN; REILLY MICHAEL; HAUGHT JOHN CHRISTIAN; SREEKRISHNA KOTI TATACHAR; LIN YAKANG
权利人:PROCTER & GAMBLE
摘要:Personal care compositions, such as oral care and skin care compositions containing a flavor/perfume system comprising one or more coolants. The pleasant cool sensation provided by a coolant is enhanced in terms of quicker onset, greater intensity, impact or longer duration, which improves appeal and acceptability of the compositions to consumers.
专利号:EP-3390352-A1
优先权日:2015-12-18
标题:Synthesis of cyclohexane ester derivatives useful as sensates in consumer products
专利号:WO-2017106279-A1
优先权日:2015-12-18
标 题 :Synthesis of cyclohexane ester derivatives useful as sensates in consumer products
专利号:AU-2016371908-A1
优先权日:2015-12-18
标题 :Synthesis of cyclohexane ester derivatives useful as sensates in consumer products
专利号:CA-3007767-A1
优先权日:2015-12-18
标题:Synthesis of cyclohexane ester derivatives useful as sensates in consumer products
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:The Mannich Reaction Of Malonates With Simple Imines Catalyzed By Bifunctional Cinchona Alkaloids: Enantioselective Synthesis Of β-Amino Acids作者:Jun Song,Yi Wang,Li Deng |发布日期:2006.5.1
摘要:Efficient, Direct Asymmetric Mannich Reactions With Malonates And N-Boc Aryl And Alkyl Imines By Cooperative Hydrogen-Bonding Catalysis With A Cinchona Alkaloid Bearing A Thiourea Functionality. We Have Also Extended The Scope Of This Reaction To Beta-Ketoesters. The Synthetic Value Of This New Reaction Is Demonstrated In The Establishment Of A Convergent Enantioselective Route Toward The Biologically
合成参考文献
参考文献:10.1007/978-3-319-50015-7_1
摘要:Babaev EV. Peptide Synthesis of Libraries of Non-natural Amino Acids. 2016 Dec 04. In: SpringerBriefs in Molecular Science.
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