CAS: 1468-95-7; 9-Anthracenemethanol

该化合物其结构特征为该化合物其结构特征为炭疽,与9号位置上附着的氢氧化物组有共性,该化合物一般为白色至黄色,因其芳香特性而闻名,因为存在由三枚已引信的苯环组成的炭角框架,它具有芳香特性,在乙醇和丙酮等有机溶剂中表现出中等溶解性,但在水中却不易溶解. 9-Anthracenemeal乙醇可以参与各种化学反应,包括氧化和酯化,使其成为有机合成的有用中间体.此外,它有可能在材料科学中,特别是在有机半导体和荧光材料的开发中,其光物理特性,包括荧光光,对光电子设备的研究很感兴趣.许多有机化合物,处理应谨慎,考虑到潜在的健康和环境影响.

结构式图片

相似化合物

642-31-9 723-62-6 10273-85-5

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号642-31-9 9-蒽醛 | CAS号88920-56-3 Anthracene, 9-[... | CAS号64-17-5 乙醇 | CAS号120-12-7 蒽 | CAS号53774-56-4 p-nitrophenyl a... | CAS号23674-17-1 RARECHEM AQ BD AN06 | CAS号779-02-2 9-甲基蒽 | CAS号2417-77-8 9-(溴甲基)蒽 | CAS号723-62-6 9-蒽甲酸 | CAS号108-95-2 苯酚 | CAS号41034-83-7 3-(9-蒽基)丙酸 | CAS号1498-71-1 Anthracene,9-(p... | CAS号22844-33-3 2-Propenoic aci... | CAS号120-12-7 蒽 | CAS号779-02-2 9-甲基蒽 | CAS号2476-68-8 蒽-9-基甲胺 | CAS号2606-52-2 9-bromo-10-(bro... | CAS号260365-89-7 9-(碘甲基)蒽 | CAS号31645-35-9 甲基丙烯酸-9-蒽甲酯

合成工艺路线路线简述

    9-蒽甲酸置于4-二甲氨基吡啶,Sodium Tetrahydroborate,十六烷基三甲基溴化铵,N,N'-二环己基碳二亚胺体系中,用 二氯甲烷,水,乙腈 用作溶剂,化学反应生成9-蒽醇
    参考文献:Efficient And Simple Nabh4 Reduction Of Esters At Cationic Micellar Surface
    标题:Efficient And Simple Nabh4 Reduction Of Esters At Cationic Micellar Surface
    摘要:A Simple,Efficacious,And Biocompatible Methodology For Reducing Esters With Sodium Borohydride At An Aqueous Cationic Micellar Surface Under Ambient Conditions Has Been Developed. The Present Method Holds Promise For Future Use In Selective Functional Group Reduction And Stereocontrolled Alcohol Synthesis.
    Doi:10.1021/ol0481176

    海关参考信息

    专利信息


    专利号:US-2012029226-A1
    优先权日:2009-02-06
    标题:Method for the synthesis of chiral alpha-aryl propionic acid derivatives
    发明人:KAPTEIN BERNARDUS; VLIEG ELIAS; NOORDUIN WILLEM LIEUWE
    权利人:KAPTEIN BERNARDUS; VLIEG ELIAS; NOORDUIN WILLEM LIEUWE
    摘要:The present invention provides a method for the synthesis of optically pure α-aryl propionic acid derivatives comprising subjecting the corresponding racemic α-aryl propionic acid derivatives to high sheer or impact forces, such as grinding.

    专利号:US-11034664-B1
    优先权日:2020-05-11
    标题 :Synthesis of cyclic carbonate monomers
    发明人:PARK NATHANIEL H; HEDRICK JAMES L; PIUNOVA VICTORIA A; ARRECHEA PEDRO; ERDMANN TIM
    权利人:IBM
    摘要:Techniques regarding the synthesis of cyclic carbonate monomers are provided. For example, one or more embodiments described herein can comprise a method, which can include cyclizing a functionalized diol monomer with N,N′-carbonyldiimidazole, wherein the cyclizing produces a cyclic carbonate monomer and an imidazole carbamate. The method can also include activating the imidazole carbamate with an acid, wherein the activating promotes cyclization of the imidazole carbamate into the cyclic carbonate monomer.

    专利号:US-8268936-B2
    优先权日:2005-01-04
    标题:Synthesis of hybrid block copolymers and uses thereof
    发明人:BREITENKAMP KURT; SILL KEVIN N
    权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC
    摘要:The present invention relates to the field of polymer chemistry and more particularly to multiblock copolymers and methods of preparing the same.

    专利号:US-2012196989-A1
    优先权日:2005-02-11
    标题:Synthesis of homopolymers and block copolymers
    发明人:BREITENKAMP KURT; SILL KEVIN N
    权利人:BREITENKAMP KURT; SILL KEVIN N; INTEZYNE TECHNOLOGIES INC
    摘要:The present invention relates to the field of polymer chemistry and more particularly to homopolymers and block copolymers and methods of preparing the same.

    专利号:US-9676904-B2
    优先权日:2011-12-08
    标 题:Metal alkoxide complex, catalyst composition, and production method of polycaprolactone or polylactide
    发明人:CUI DONGMEI; LIU XINLI; LIU BO; LI SHIHUI; LIU DONGTAO; WU CHUNJI
    权利人:CUI DONGMEI; LIU XINLI; LIU BO; LI SHIHUI; LIU DONGTAO; WU CHUNJI; CHANGCHUN INST APPLIED CHEMISTRY CAS
    摘要:The invention provides a metal alkoxide complex of Formula (I), wherein X, M, R1, R2, R3, m, n, y and z are as defined in the Description. The invention also provides a catalyst composition comprising the metal alkoxide complex and a hydroxy-containing compound, wherein the molar ratio of the metal alkoxide complex to the hydroxy-containing compound is 1:0.1-1000. The invention also provides a production method of poly-ε-caprolactone or polyactide, wherein an ε-caprolactone monomer or a lactide monomer is reacted in the presence of the metal alkoxide complex or catalyst composition to obtain poly-ε-caprolactone or polylactide. The metal alkoxide complex and the catalyst composition thereof can be used to catalyze the synthesis of poly-ε-caprolactone or polylactide with a high efficiency. The molecular weight of polycaprolactone or polylactide can be controlled by the molar ratio of the metal alkoxide complex and the hydroxy-containing compound, and is adjustable in the range of 1000-600,000, and wherein the molecular weight distribution is from 1.03 to 1.50.n n[X n-m M(OCR 1 R 2 R 3 ) m ] y .(organic solvent) z   (I)

    专利号:US-7470783-B2
    优先权日:1995-12-15
    标 题 :Photocleavable protecting groups and methods for their use
    发明人:MCGALL GLENN H; NAM NGO Q; RAVA RICHARD P
    权利人:AFFYMETRIX INC
    摘要:Novel compounds are provided which are useful as linking groups in chemical synthesis, preferably in the solid phase synthesis of oligonucleotides and polypeptides. These compounds are generally photolabile and comprise protecting groups which can be removed by photolysis to unmask a reactive group. The protecting group has the general formula Ar—C(R 1 )(R 2 )—O—C(O)-wherein:n Ar is an optionally substituted fused polycyclic aryl or heteroaromatic group or a vinylogous derivative thereof; R 1 and R2 are independently H, optionally substituted alkyl, alkenyl or alkynyl, optionally substituted aryl or optionally substituted heteroaromatic, or a vinylogous derivative of the foregoing; and X is a leaving group, a chemical fragment linked to Ar—C(R 1 )(R 2 )—O—C(O)— via a heteroatom, or a solid support; provided that when Ar is 1 -pyrenyl and R 1 and R 2 are H, X is not linked to Ar—C(R 1 )(R 2 )—O—C(O)— via a nitrogen atom. Preferred embodiments are those in which Ar is a fused polycyclic aromatic hydrocarbon and in which the substituents on Ar, R 1 and R 2 are electron donating groups. A particularly preferred protecting group is the “PYMOCâ€? protecting group, pyrenylmethyloxycarbonyl, where Ar is pyrenyl and R 1 and R 2 are H. nn Also provided is a method of forming, from component molecules, a plurality of compounds on a support, each compound occupying a separate predefined region f the support, using the protected compounds described above.
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    ✅ COA系统入驻 | 共享模式

    主要参考文献

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    [参考文献]: C E Cerniglia, Et Al. Stereoselective Fungal Metabolism Of Methylated Anthracenes. Appl Environ Microbiol. 1990 Mar;56(3):661-8.
    [参考文献]: Chen-Yu Li, Et Al. Synthesis, Structural Characterization And Reactivity Of Aluminium Complexes Supported By Benzotriazole Phenoxide Ligands: Air-Stable Alumoxane As An Efficient Catalyst For Ring-Opening Polymerization Of L-Lactide. Dalton Trans. 2011 Mar 7;40(9):1880-7.
    [参考文献]: Dipak Samanta, Et Al. Self-Assembled Pd6 Open Cage With Triimidazole Walls And The Use Of Its Confined Nanospace For Catalytic Knoevenagel- And Diels-Alder Reactions In Aqueous Medium. Chemistry. 2012 Sep 24;18(39):12322-9.
    [参考文献]: H Glatt, Et Al. Activation Of Promutagens By Endogenous And Heterologous Sulfotransferases Expressed In Continuous Cell Cultures. Toxicol Lett. 1994 Jun;72(1-3):13-21.

    合成参考文献


    摘要:Braverman, S.; Cherkinsky, M., Science of Synthesis Knowledge Updates, (2014) 3, 201.
    摘要:Cruz, F. A.; Dong, V. M., Science of Synthesis, (2019) , 127.
    摘要:Cui, H.; An, B.; Zhang, X., Science of Synthesis: Dearomatizations, (2026) .
    参考文献:10.1038/srep42141
    摘要:Kumar A, Balbach J. Targeting the molecular chaperone SlyD to inhibit bacterial growth with a small molecule. Scientific Reports. 2017 Feb 08;7(1):42141. doi: 10.1038/srep42141.
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