CAS: 882-59-7; 2,2-Diphenyloxirane
该化合物是一种有机化合物,其特点是由三环醚组成的四氧功能组,由三者组成,该化合物具有两个联苯组,附属于该氧化物的碳原子,具有独特的化学特性,一般是一种无色的黄色液体,具有独特的芳香味. 22-二苯氧,因其反应活动性而闻名于浅色,特别是正在发生环状反应,这种反应可由核素推动.这使其在各种化学合成中有用,包括生产聚合物和其他有机化合物.该化合物还有助于研究其潜在的生物活动,因为乙氧可表现出不同程度的毒性和与生物分子的再活动性.由于其化学结构,22-二苯氧,在正常条件下相对稳定,但应当谨慎处理,因为它具有潜在的再活动性,而且有可参与进一步化学转化的氧化物组的存在.
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号530-48-3 1,1-二苯基乙烯 | CAS号119-61-9 二苯甲酮 | CAS号1774-47-6 三甲基碘化亚砜 | CAS号2181-42-2 三甲基碘代磺酸 | CAS号75-11-6 二碘甲烷 | CAS号6814-64-8 dimethylsulphon... | CAS号950-17-4 Benzenemethanol... | CAS号78485-09-3 3,3,5-triphenyl... | CAS号950-16-3 Benzenemethanol... | CAS号451-40-1 二苯乙酮 | CAS号183-84-6 Bis[cyclohexyli... | CAS号108-94-1 环己酮 | CAS号121744-30-7 2,2-diphenyl-1,... | CAS号121744-23-8 3,3-diphenyl-1,... | CAS号1883-32-5 2,2-二苯基乙醇 | CAS号86-29-3 二苯乙腈 | CAS号947-91-1 二苯基乙醛 | CAS号119-61-9 二苯甲酮 | CAS号599-67-7 1,1-二苯基乙醇合成工艺路线路线简述
- 119-61-9 + 2181-42-2 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide,Tetrahydrofuran; 30 Min,Rt1.2 Solvents: Tetrahydrofuran; 2 H,0 °C; Rt1.3 Reagents: Ammonium Chloride Solvents: Water; Rt
标题:Isomerization Of Terminal Epoxides By A [pd-H] Catalyst: A Combined Experimental And Theoretical Mechanistic Study
作者:Vyas,Devendra J.; Et Al
参考文献:Journal Of The American Chemical Society 日期:2013 卷标:135(16) 页码:6177-6183]
119-61-9 + 2181-42-2 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide,Tetrahydrofuran; 0 °C; 0 °C -> 25 °C; 16 H,25 °C
标题:"Instant Methylide" Modification Of The Corey-Chaykovsky Epoxide Synthesis
作者:Ciaccio,James A.; Et Al
参考文献:Synthetic Communications 日期:2003 卷标:33(12) 页码:2135-2143]
530-48-3 = 882-59-7
反应条件:1.1 Reagents: Dimethyldioxirane Solvents: Acetone
标题:Development Of A Polymer Bound Wittig Reaction And Use In Multi-Step Organic Synthesis For The Overall Conversion Of Alcohols To β-Hydroxyamines
作者:Bolli,Martin H.; Et Al
参考文献:Journal Of The Chemical Society 日期:1998 卷标:(15) 页码:2243-2246]
530-48-3 = 882-59-7
反应条件:1.1 Reagents: Acetic Acid,Hydrogen Peroxide Catalysts: Phosphonium,Tetraphenyl-,(Sp-5-12)-Tetrakis(Cyano-Kc)Nitridomanganate(2-) (2:1... Solvents: Acetonitrile; 0.5 H,23 °C
标题:Epoxidation Of Alkenes And Oxidation Of Alcohols With Hydrogen Peroxide Catalyzed By A Manganese(V) Nitrido Complex
作者:Kwong,Hoi-Ki; Et Al
参考文献:Chemical Communications (Cambridge 日期:2011 卷标:47(14) 页码:4273-4275]
119-61-9 + 6814-64-8 = 882-59-7 [标题:Reaction Conditions
标题:Dimethylsulfonium Methylide
作者:Okazaki,Renji; Et Al
参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
119-61-9 + 1774-47-6 = 882-59-7
反应条件:1.1 Reagents: 1884186-57-5 Solvents: 1-Butyl-3-Methylimidazolium Tetrafluoroborate; 90 Min,Rt
标题:Facile Synthesis Of Libraries Of Functionalized Cyclopropanes And Oxiranes Using Ionic Liquids - A New Approach To The Classical Corey-Chaykovsky Reaction
作者:Malunavar,Shruti S.; Et Al
参考文献:Tetrahedron Letters 日期:2021 卷标:81]
119-61-9 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide
标题:Dimethylsulfoxonium Methylide
作者:Corey,E. J.; Et Al
参考文献:Journal Of The American Chemical Society 日期:1962 卷标:84 页码:867-8]
119-61-9 = 882-59-7
反应条件:1.1 Reagents: Methyllithium,Lithium Bromide Solvents: Diethyl Ether,Tetrahydrofuran
标题:The In Situ Generation And Use Of Iodomethyllithium For The One-Carbon Homologation Of Boronic Esters And Epoxide Formation From Carbonyl Compounds
作者:Wallace,Richard H.; Et Al
参考文献:Synthetic Communications 日期:1995 卷标:25(1) 页码:127-33]
119-61-9 + 105-39-5 = 882-59-7
反应条件:1.1 Catalysts: Sodium Ethoxide Solvents: Diethyl Ether; 0 - 2 °C; 15 H,20 °C1.2 Reagents: Acetic Acid Solvents: Water; 10 Min,Cooled1.3 Reagents: Sodium Hydroxide Solvents: Water; 12 H,Rt1.4 Reagents: Hydrochloric Acid Solvents: Water; Ph 3 - 4; Rt -> 50 °C; 50 °C
标题:Synthesis Of The Internal Electron Donor In Z-N Catalyst-2,2-Diphenyl-1,3-Dimethoxypropane
作者:Liu,Min; Et Al
参考文献:Huaxue Shiji 日期:2011 卷标:33(5) 页码:420-422]
119-61-9 + 93938-04-6 = 882-59-7 [标题:Reaction Conditions
标题:Product Class 3: Oxetanes And Oxetan-3-Ones
作者:Griesbeck,A. G.; Et Al
参考文献:Science Of Synthesis 日期:2008 卷标:37 页码:433-471]
119-61-9 + 60065-96-5 = 882-59-7
反应条件:1.1 Solvents: Benzophenone
标题:Organic Sulfur Compounds. Part 51. Oxosulfonium Salts. Iv. Preparation And Reactions Of Methylphenyloxosulfonium Methylide
作者:Ryoke,Katsumi; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:1976 卷标:49(5) 页码:1455-6]
119-61-9 + 51-92-3 + 37181-39-8 = 882-59-7
反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran; 30 Min,0 °C1.2 Solvents: Tetrahydrofuran; 16 H,0 °C -> Rt
标题:A Lithiomethyl Trimethylammonium Reagent As A Methylene Donor
作者:Den Hartog,Tim; Et Al
参考文献:Chemical Communications (Cambridge 日期:2014 卷标:50(73) 页码:10604-10607]
119-61-9 + 4358-26-3 + 68944-15-0 = 882-59-7
反应条件:1.1 Reagents: 2,2,6,6-Tetramethylpiperidine Solvents: Tetrahydrofuran1.2 -
标题:Synthetic Application Of Elementorganic Compounds Of The 15Th And 16Th Groups. 84. A First Non-Stabilized Telluronium Ylide. Diphenyltelluronium Methylide As A Novel Reagent For Synthesis Of Oxiranes
作者:Shi,Lilan; Et Al
参考文献:Tetrahedron Letters 日期:1990 卷标:31(29) 页码:4173-4]
119-61-9 + 676-84-6 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dichloromethane,Water
标题:Trimethylsulfonium Methyl Sulfate,A Simple And Efficient Epoxidizing Agent
作者:Mosset,Paul; Et Al
参考文献:Synthetic Communications 日期:1985 卷标:15(8) 页码:749-57]
119-61-9 + 2181-42-2 = 882-59-7
反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Tert-Butanol; 30 °C; 30 °C -> 50 °C; 40 - 50 °C; 12 H,40 - 50 °C
标题:Practical Corey-Chaykovsky Epoxidation. Scope And Limitation
作者:Yu,Hao; Et Al
参考文献:Letters In Organic Chemistry 日期:2011 卷标:8(7) 页码:509-514]
530-48-3 = 882-59-7
反应条件:1.1 Reagents: Dimethyldioxirane Solvents: Acetone
标题:Dioxirane Epoxidation Of Alkenes
作者:Adam,Waldemar; Et Al
参考文献:Organic Reactions (Hoboken 日期:2002 卷标:61]
119-61-9 + 333-27-7 = 882-59-7
反应条件:1.1 Catalysts: Benzene,1,1′-[1,4-Butanediylbis(Oxy)]Bis[4-Ethenyl-,Polymer With 1-Ethenyl-4-(... Solvents: Dichloromethane; Rt; 24 H,Rt1.2 Reagents: Sodium Hydride Solvents: Dimethyl Sulfoxide,Tetrahydrofuran; 0 °C; 0 °C; 0 °C -> Rt
标题:Polymer-Supported Thioanisole: A Versatile Platform For Organic Synthesis Reagents
作者:Choi,Matthew Kwok Wai; Et Al
参考文献:Tetrahedron 日期:2004 卷标:60(12) 页码:2875-2879]
119-61-9 + 6814-64-8 = 882-59-7 [标题:Reaction Conditions
标题:Synthesis And Preliminary Pharmacological Activity Of Aminoalkoxy Isosteres Of Glycolate Ester Anticholinergics
作者:Fries,David S.; Et Al
参考文献:Journal Of Medicinal Chemistry 日期:1977 卷标:20(10) 页码:1250-4]
119-61-9 + 1030268-24-6 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydride; 1.5 H,50 °C
标题:Synthesis Of 4-Arylpiperidin-4-Ol Derivatives Of Loperamide As Agents With Potent Antiproliferative Effects Against Hct-116 And Hl-60 Cells
作者:Hatae,Noriyuki; Et Al
参考文献:Heterocycles 日期:2014 卷标:88(1) 页码:663-673]
119-61-9 + 1774-47-6 = 882-59-7
反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Dimethyl Sulfoxide; 0.67 H,50 - 60 °C
标题:"Instant Methylide" Modification Of The Corey-Chaykovsky Epoxide Synthesis
作者:Ciaccio,James A.; Et Al
参考文献:Synthetic Communications 日期:2003 卷标:33(12) 页码:2135-2143]
119-61-9 + 74-95-3 = 882-59-7
反应条件:1.1 Reagents: Lithium,Methyl-,Compd. With Lithium Bromide (Libr) (1:1) Solvents: Diethyl Ether,Tetrahydrofuran; 30 S,-80 °C; -80 °C -> 20 °C; 1 Min,20 °C1.2 Solvents: Water; 20 °C
标题:Continuous Flow Synthesis Of Terminal Epoxides From Ketones Using In Situ Generated Bromomethyl Lithium
作者:Von Keutz,Timo; Et Al
参考文献:Organic Letters 日期:2019 卷标:21(24) 页码:10094-10098]
119-61-9 + 676-84-6 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydride Solvents: Dimethyl Sulfide
标题:Reaction Of Sulfonium Ylides With Polar Double Bonds
作者:Franzen,Volker; Et Al
参考文献:Chemische Berichte 日期:1963 卷标:96(7) 页码:1881-90]
119-61-9 + 93938-04-6 = 882-59-7
反应条件:1.1 Reagents: Methane,Sulfinylbis-,Ion(1-),Sodium Solvents: Dimethyl Sulfoxide1.2 Solvents: Dimethyl Sulfoxide
标题:Reaction Of Sulfonimidamide Anions With Electrophiles
作者:Okuma,Kentaro; Et Al
参考文献:Journal Of Organic Chemistry 日期:1988 卷标:53(18) 页码:4190-3]
119-61-9 + 4358-26-3 + 68944-15-0 = 882-59-7 [标题:Reaction Conditions
标题:Product Class 20: Aryl Tellurium Compounds
作者:Kataoka,T.; Et Al
参考文献:Science Of Synthesis 日期:2007 卷标:31 页码:1159-1181]
119-61-9 + 37181-39-8 = 882-59-7
反应条件:1.1 Solvents: Dimethyl Sulfoxide
标题:Reaction Of Diphenylsulfonium Methylide With Carbonyl Compounds In Non-Basic Media
作者:Hioki,Kazuhito; Et Al
参考文献:Synthesis 日期:1995 卷标:(6) 页码:649-50]
103-30-0 = 882-59-7
反应条件:1.1 Reagents: Iodosylbenzene Catalysts: Manganese (Immobilized,Reaction Products With Functional Group-Modified Hexagona...),Silica (Formyl Group-Modified,Surface-Grafted),S,S-Jacobsen Catalyst (Immobilized,Reaction Products With Formyl Group-Modified Hexagonal Me...) Solvents: Dichloromethane; 2 H,298 K
标题:Immobilization Of Salen-Manganese Complex Over Hexagonal Mesoporous Silica With Different Surface Groups And Modifications
作者:Wu,Meizhi; Et Al
参考文献:Jingxi Huagong Zhongjianti 日期:2005 卷标:35(3) 页码:13-16]
119-61-9 + 3086-29-1 = 882-59-7
反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Dichloromethane,Water
标题:Anion-Catalyzed Phase-Transfer Catalysis. Ii. Effects Of Anionic Tetrakis[3,5-Bis(Trifluoromethyl)Phenyl]Borate Catalyst In Phase-Transfer-Catalyzed Sulfonium Ylide Formation
作者:Shiraki,Yasuichiro; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:1985 卷标:58(10) 页码:3041-2]
119-61-9 + 47025-43-4 = 882-59-7 [标题:Reaction Conditions
标题:Synthesis Of Epoxides By Carbonyl Epoxidation
作者:Aggarwal,V. K.; Et Al
参考文献:Science Of Synthesis 日期:2008 卷标:37 页码:321-406
📜1,1-二苯乙烯置于间氯过氧苯甲酸体系中,用 二氯甲烷 作为反应溶剂,化学反应 2.0H,反应生成 1,1-二苯基环氧乙烷
参考文献:区域选择性和立体定向铜催化的环氧脱氧制烯烃
标题:区域选择性和立体定向铜催化的环氧脱氧制烯烃
摘要:两种铜盐(cu(cf 3 Co 2)2和imescucl)被鉴定为是地球上丰富的,廉价的但有效的金属催化剂,与重氮丙二酸酯一起用于各种环氧化物的化学/区域选择性和立体定向脱氧反应,并具有常见的官能团耐受性(烯烃,酮,酯,对甲氧基苄基,苄基,叔丁基二甲基甲硅烷基和三异丙基甲硅烷基).特别是,空前的区域选择性使二环氧化物首次单脱氧为烯基环氧化物.密度泛函理论的机理研究表明,脱氧是通过折叠游离的叶立德而发生的,不利于通过可能的氧杂环丁烷的环还原而产生的直观途径.
DOI:10.1021/acs.Orglett.6B02405
海关参考信息
- 2902600000-乙苯
2906210000-苄醇
2910100000-环氧乙烷
2909199090-其他醚及其衍生物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2016088138-A1
优先权日:2014-12-01
标题 :Diphenyloxiranes, process for preparation thereof, and its use in an enantioselective synthesis of (+)-sertraline
发明人：SURYAVANSHI GURUNATH MALLAPPA; SUDALAI ARUMUGAM; KAMBLE ROHIT BALKRISHNA
权利人:COUNCIL SCIENT IND RES
摘要:The present invention discloses substituted diphenyloxiranes and process for synthesis thereof. The present invention also provides a process for production of enantiomerically pure anti-3,3' -diphenylmethyloxirane and anti-3,3'- diphenylpropan- 1,2-diol from racemic anti-3,3' -diphenylmethyloxirane using hydrolytic kinetic resolution. Further it provides a process for preparation of enantioselective (+)- Sertraline from anti-3,3' -diphenylpropan-1,2-diol.
专利号:US-3979460-A
优先权日:1974-07-01
标 题 :Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the oganomercaptophenols are also useful as antioxidants.
专利号:US-4064158-A
优先权日:1974-07-01
标题:Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the organomercaptophenols are also useful as antioxidants.
专利号:US-4082808-A
优先权日:1974-07-01
标 题 :Thiobis-2,6-disubstituted phenol
发明人：HAY ALLAN S
权利人:GEN ELECTRIC
摘要:Novel thiobis-2,6-disubstituted phenols are described which are useful as monomers in the synthesis of polycarbonates, polyesters, epoxy resins, among many others chemicals synthesized from polyhydric phenols. In addition, the thiobisphenols are also useful as antioxidants.
专利号:US-10717812-B2
优先权日:2017-03-16
标 题:Lactone-epoxide statistical copolymers
发明人：LYND NATHANIEL A; CHWATKO MALGORZATA
权利人:UNIV TEXAS
摘要:The present disclosure relates to copolymers and methods for copolymer preparation. Disclosed herein are high molecular weight copolymers of lactones and epoxides and methods for their synthesis.
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品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Vashchenko, B. V.; Grygorenko, O. O., Science of Synthesis Knowledge Updates, (2021) 3, 276.
摘要:Croft, R. A.; Bull, J. A., Science of Synthesis Knowledge Updates, (2018) 4, 386.
📝 需求与反馈
尽可能描述清楚需求与问题信息
