CAS: 836-41-9; N-(4-Methoxybenzylidene)Aniline
该化合物是Schiff基地化合物,其特征是其含汞功能组(-C=N-),将4-甲基苯和苯胺联系起来.这一结构具有显著的稳定性和反应性,在有机合成中具有价值,特别是作为制药,农用化学和协运化学的中间体. 电饱和甲基氧组增强了其在核循环反应和金属复合组中的效用. 其晶体形式确保了处理和净化的便利性,而其定义的分子重量(209.25 g/ 摩尔) 允许精确地使用异子测量. 化合物与一系列溶剂的兼容性进一步扩大了其在研究和工业工艺中的应用范围.
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
CAS号98-95-3 硝基苯 | CAS号105-13-5 对甲氧基苄醇 | CAS号3585-93-1 (4-甲氧基亚苄基)苯胺硝酮 | CAS号3526-43-0 N-苯基-4-甲氧基苄胺 | CAS号123-11-5 4-甲氧基苯甲醛; 对甲氧基苯... | CAS号622-37-7 叠氮苯 | CAS号2393-23-9 对甲氧基苄胺 | CAS号103-71-9 异氰酸苯酯 | CAS号56644-00-9 N-cyclohexyl-1-... | CAS号3526-43-0 N-苯基-4-甲氧基苄胺 | CAS号83871-65-2 1,2-bis(4-metho... | CAS号107909-65-9 N-(α-Tetrahydro... | CAS号105-13-5 对甲氧基苄醇 | CAS号104-93-8 4-甲基苯甲醚(MSO) | CAS号15190-69-9 Benzeneacetonit... | CAS号119-61-9 二苯甲酮合成工艺路线路线简述
- 合成目标产物 N-(4-Methoxybenzylidene)Aniline 主要起始原料 Aniline And 4-Ethynylanisole
- 105-13-5 = 836-41-9
反应条件:1.1 Catalysts: Manganese Zirconium Oxide Solvents: Toluene; 3 H,1 Atm,80 °C
标题:Efficient Imine Synthesis Via Oxidative Coupling Of Alcohols With Amines In An Air Atmosphere Using A Mesoporous Manganese-Zirconium Solid Solution Catalyst
作者:Wu,Shipeng; Et Al
参考文献:Catalysis Science & Technology 日期:2021 卷标:11(3) 页码:810-822]
123-11-5 = 836-41-9
反应条件:1.1 Reagents: Hydrogen Catalysts: Copper,Silica Solvents: Toluene; 0.5 H,1 Atm,100 °C
标题:Reductive Amination Of Ketones Or Amination Of Alcohols Over Heterogeneous Cu Catalysts: Matching The Catalyst Support With The N-Alkylating Agent
作者:Santoro,Federica; Et Al
参考文献:Chemcatchem 日期:2012 卷标:4(9) 页码:1249-1254]
123-11-5 = 836-41-9
反应条件:1.1 2 - 2.1 Kpa,80 °C
标题:Alkoxy Substituted (E,E)-3,6-Bis(Styryl)Pyridazine-A Photosensitive Mesogen For Liquid Crystals
作者:Lifka,Thorsten; Et Al
参考文献:Tetrahedron 日期:2008 卷标:64(27) 页码:6551-6560]
857402-61-0 + 123-11-5 = 836-41-9
反应条件:1.1 Solvents: Benzene-D6; 1 H,25 °C
标题:Readily Available Primary Aminoboranes As Powerful Reagents For Aldimine Synthesis
作者:Junor,Glen P.; Et Al
参考文献:Angewandte Chemie 日期:2019 卷标:58(9) 页码:2875-2878]
857402-61-0 + 123-11-5 = 836-41-9
反应条件:1.1 Solvents: Benzene-D6; 0.5 H,Rt
标题:Cobalt-Catalyzed Deoxygenative Hydroboration Of Nitro Compounds And Applications To One-Pot Synthesis Of Aldimines And Amides
作者:Gudun,Kristina A.; Et Al
参考文献:Advanced Synthesis & Catalysis 日期:2022 卷标:364(3) 页码:601-611]
123-11-5 = 836-41-9
反应条件:1.1 Catalysts: Cobalt,Carbon Nitride (C3N4) Solvents: Ethanol,Formic Acid; 12 H,70 °C
标题:Cobalt-Doped G-C3N4 Nanosheets For One-Pot Synthesis Of Imines Under Mild Conditions
作者:Zhu,Jiukang; Et Al
参考文献:Acs Applied Nano Materials 日期:2023 卷标:6(7) 页码:5127-5135]
2393-23-9 = 836-41-9
反应条件:1.1 Reagents: Oxygen Catalysts: Ferrous Bromide; 6 H,110 °C
标题:A Solvent-Free Process For Synthesis Of Imines By Iron-Catalyzed Oxidative Self- Or Cross-Condensation Of Primary Amines Using Molecular Oxygen As Sole Oxidant
作者:Gopalaiah,Kovuru; Et Al
参考文献:Catalysis Letters 日期:2016 卷标:146(9) 页码:1648-1654]
2393-23-9 = 836-41-9
反应条件:1.1 Catalysts: (Sp-5-52)-Carbonylhydro[[n,N′-(2,6-Pyridinediyl-Kn)Bis[p,P-Bis(1,1-Dimethylethyl...; 160 °C
标题:Enhanced Reactivities Toward Amines By Introducing An Imine Arm To The Pincer Ligand: Direct Coupling Of Two Amines To Form An Imine Without Oxidant
作者:He,Li-Peng; Et Al
参考文献:Organometallics 日期:2012 卷标:31(14) 页码:5208-5211]
3585-93-1 = 836-41-9
反应条件:1.1 Reagents: Indium Trichloride Solvents: Acetonitrile
标题:An Indium Mediated Efficient Chemoselective Deoxygenation Of N-Oxides And Nitrones
作者:Ilias,Md.; Et Al
参考文献:Tetrahedron Letters 日期:2002 卷标:43(10) 页码:1877-1879]
103-33-3 + 105-13-5 = 836-41-9
反应条件:1.1 Reagents: Cesium Hydroxide Catalysts: 1,10-Phenanthroline,Cobalt (Reaction Product With 1,10-Phenanthroline/hmta/melamine,Carbon-Suppor...) Solvents: Toluene; 24 H,130 °C
标题:Heterogeneous Cobalt-Catalyzed Degradation Of Azo Compounds Using Alcohols As The Stoichiometric Hydrogen Source
作者:Panja,Dibyajyoti; Et Al
参考文献:Journal Of Environmental Chemical Engineering 日期:2023 卷标:11(2)]
104-87-0 = 836-41-9
反应条件:1.1 Solvents: Ethanol; 3 H,Reflux
标题:Synthesis Of Structurally Diverse 2-Azetidinones Via Staudinger Reaction On A Solid Support
作者:Jarrahpour,Aliasghar; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:2011 卷标:84(3) 页码:320-327]
105-13-5 + 622-37-7 = 836-41-9
反应条件:1.1 Reagents: Triphenylphosphine,Potassium Hydroxide Catalysts: (Oc-6-12)-Dichloro[4-[[(S)-Ethylthio-Ks]Methyl]Acridine-Kn](Triphenylphosphine)R... Solvents: Toluene; Rt -> 135 °C; 18 H,135 °C
标题:Acceptorless Dehydrogenative Construction Of C=n And C=c Bonds Through Catalytic Aza-Wittig And Wittig Reactions In The Presence Of An Air-Stable Ruthenium Pincer Complex
作者:Biswas,Nandita; Et Al
参考文献:Dalton Transactions 日期:2019 卷标:48(19) 页码:6501-6512]
105-13-5 + 622-37-7 = 836-41-9
反应条件:1.1 Reagents: Potassium Tert-Butoxide Catalysts: 2633072-21-4 Solvents: Toluene; 18 H,130 °C
标题:Redox-Neutral Imination Of Alcohol With Azide: A Sustainable Alternative To The Staudinger/aza-Wittig Reaction
作者:Li,Huaifeng; Et Al
参考文献:Acs Catalysis 日期:2021 卷标:11(7) 页码:4071-4076]
123-11-5 = 836-41-9
反应条件:1.1 Catalysts: Titanium Tetrabutoxide Solvents: Tetrahydrofuran; Rt; 54 H,Rt1.2 Reagents: Water; Rt; 1 H,Rt
标题:Room Temperature Metathesis Of Aryl Isocyanates And Aromatic Aldehydes Catalyzed By Group(Iv) Metal Alkoxides: An Experimental And Computational Study
作者:Kumar,Akshai; Et Al
参考文献:Journal Of Organometallic Chemistry 日期:2010 卷标:695(3) 页码:338-345]
123-11-5 + 100-52-7 = 836-41-9
反应条件:1.1 Solvents: Ethanol; 20 Min,50 °C
标题:(R)-Oxynitrilases As Biocatalysts For The Addition Of Cyanide To Phenylimines
作者:Solis O.,Aida; Et Al
参考文献:Revista Mexicana De Ciencias Farmaceuticas 日期:2002 卷标:33(4) 页码:27-31]
105-13-5 = 836-41-9
反应条件:1.1 Reagents: Oxygen Catalysts: Gold Alloy,Base,Au 65,Pd 35 (Nanoparticles,Zirconia-Supported) Solvents: Ethanol; 9 H,40 °C1.2 1 H,40 °C
标题:Au-Pd Alloy Nanoparticle Catalyzed Selective Oxidation Of Benzyl Alcohol And Tandem Synthesis Of Imines At Ambient Conditions
作者:Cui,Wenjing; Et Al
参考文献:Catalysis Today 日期:2014 卷标:235 页码:152-159]
105-13-5 = 836-41-9
反应条件:1.1 Catalysts: Cobalt (Composite With Carbon And Nitrogen; Carbon Nanotube Encapsulated); 20 H,160 °C
标题:Direct Reductive Coupling Of Nitroarenes And Alcohols Catalysed By Co-N-C/cnt@ac
作者:Liu,Di; Et Al
参考文献:Green Chemistry 日期:2019 卷标:21(8) 页码:2129-2137]
105-13-5 = 836-41-9
反应条件:1.1 Catalysts: Cobalt Solvents: Octane; 12 H,0.6 Mpa,140 °C
标题:Preparation Of Co-N-C Catalysts And "One-Pot Method" For Synthesis Of N-Benzyl Aniline
作者:Leng,Jie; Et Al
参考文献:Huagong Xuebao (Chinese Edition) 日期:2020 卷标:71(11) 页码:5016-5024]
105-13-5 = 836-41-9
反应条件:1.1 Catalysts: 1-Butanaminium,N,N,N-Tributyl-,Stereoisomer Of Diaqua[μ10-[orthosilicato(4-)-K... Solvents: Acetonitrile,Toluene; 4 H,60 °C; 2 H,100 °C
标题:Visible-Light-Responsive Multielectron Redox Catalysis Of Lacunary Polyoxometalates Induced By Substrate Coordination To Their Lacuna
作者:Suzuki,Kosuke; Et Al
参考文献:Chemistry - An Asian Journal 日期:2015 卷标:10(1) 页码:144-148]
123-11-5 = 836-41-9
反应条件:1.1 Solvents: Benzene; 4 H,Reflux
标题:Applications Of Dynamic Combinatorial Chemistry For The Determination Of Effective Molarity
作者:Ciaccia,Maria; Et Al
参考文献:Chemical Science 日期:2015 卷标:6(1) 页码:144-151]
123-11-5 = 836-41-9
反应条件:1.1 Reagents: Pinacolborane Catalysts: Cobalt(Ii) Acetylacetonate,Bis[2-(Diphenylphosphino)Phenyl] Ether Solvents: Benzene-D6; 1 H,Rt1.2 Solvents: Benzene-D6; 0.5 H,Rt
标题:Cobalt-Catalyzed Deoxygenative Hydroboration Of Nitro Compounds And Applications To One-Pot Synthesis Of Aldimines And Amides
作者:Gudun,Kristina A.; Et Al
参考文献:Advanced Synthesis & Catalysis 日期:2022 卷标:364(3) 页码:601-611]
123-11-5 = 836-41-9
反应条件:1.1 Reagents: Carbon Monoxide,Water Catalysts: Gold,Titania Solvents: Triethylamine; 1 H,5 Atm,25 °C
标题:Direct One-Pot Reductive Imination Of Nitroarenes Using Aldehydes And Carbon Monoxide By Titania Supported Gold Nanoparticles At Room Temperature
作者:Huang,Jun; Et Al
参考文献:Green Chemistry 日期:2011 卷标:13(10) 页码:2672-2677]
2393-23-9 = 836-41-9
反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Chitosan (Cu/chitosan Bead Complex) Solvents: Acetonitrile; 24 H,80 °C
标题:Uniform Cu/chitosan Beads As A Green And Reusable Catalyst For Facile Synthesis Of Imines Via Oxidative Coupling Reaction
作者:Chutimasakul,Threeraphat; Et Al
参考文献:Rsc Advances 日期:2020 卷标:10(35) 页码:21009-21018]
3526-43-0 = 836-41-9
反应条件:1.1 Reagents: 1,5-Diazabicyclo[4.3.0]Non-5-Ene Catalysts: Carbon Dioxide,Eosin Solvents: Dimethyl Sulfoxide; 48 H,1 Atm,25 - 30 °C
标题:Co2-Catalyzed Efficient Dehydrogenation Of Amines With Detailed Mechanistic And Kinetic Studies
作者:Riemer,Daniel; Et Al
参考文献:Acs Catalysis 日期:2018 卷标:8(12) 页码:11679-11687]
3526-43-0 = 836-41-9
反应条件:1.1 Reagents: Sodium Borohydride Catalysts: Chloro(Triphenylphosphine)Gold,3,6,9,12-Tetraoxatridecan-1-Ol,13-(4-Ethenylphenyl)-,Polymer With Ethenylbenze... Solvents: Tetrahydrofuran,Diglyme; Rt; 3 H,Rt1.2 Solvents: Mesitylene; 5 H,150 °C1.3 Reagents: Oxygen Solvents: Toluene; 20 H,100 °C
标题:Aerobic Oxidation Of Amines Catalyzed By Polymer-Incarcerated Au Nanoclusters: Effect Of Cluster Size And Cooperative Functional Groups In The Polymer
作者:Miyamura,Hiroyuki; Et Al
参考文献:Bulletin Of The Chemical Society Of Japan 日期:2011 卷标:84(6) 页码:588-599]
3526-43-0 = 836-41-9
反应条件:1.1 Reagents: Oxygen Catalysts: Gold,Graphite Solvents: Toluene; 24 H,110 °C
标题:Graphite-Supported Gold Nanoparticles As Efficient Catalyst For Aerobic Oxidation Of Benzylic Amines To Imines And N-Substituted 1,2,3,4-Tetrahydroisoquinolines To Amides: Synthetic Applications And Mechanistic Study
作者:So,Man-Ho; Et Al
参考文献:Chemistry - An Asian Journal 日期:2009 卷标:4(10) 页码:1551-1561]
64-10-8 + 105-13-5 = 836-41-9
反应条件:1.1 Reagents: Potassium Hydroxide,Oxygen; 24 H,135 °C
标题:Base-Mediated Synthesis Of Imines And Amines From N-Phenylureas And Alcohols
作者:Yadav,Dilip Kumar T.; Et Al
参考文献:Synlett 日期:2014 卷标:25(11) 页码:1611-1615]
3585-93-1 = 836-41-9
反应条件:1.1 Reagents: Indium,Ammonium Chloride Solvents: Methanol
标题:Indium-Mediated Deoxygenation Of Nitrones,N-Oxides And Deoxygenative Reductive Coupling Of Nitrones To Vicinal Diamines
作者:Jeevanandam,Arumugasamy; Et Al
参考文献:Synthetic Communications 日期:2000 卷标:30(17) 页码:3153-3160]
3585-93-1 = 836-41-9
反应条件:1.1 Reagents: Triphenylphosphine,Iodine Solvents: Benzene
标题:Deoxygenation Of α-Aryl-N-Phenylnitrones With Diiodotriphenylphosphorane
作者:Furukawa,Isao; Et Al
参考文献:Nippon Kagaku Kaishi 日期:1989 卷标:(10) 页码:1748-52]
103-33-3 + 105-13-5 = 836-41-9
反应条件:1.1 Reagents: Potassium Carbonate Catalysts: 2923249-07-2 Solvents: Toluene; 20 H,130 °C
标题:Chemodivergent Coupling Of Azoarenes With Benzyl Alcohols Via A Borrowing Hydrogen Strategy Using A Well-Defined Nickel Catalyst
作者:Bansal,Sadhna; Et Al
参考文献:Catalysis Science & Technology 日期:2023 卷标:13(9) 页码:2705-2713]
123-11-5 + 622-37-7 = 836-41-9
反应条件:1.1 Reagents: Triphenylphosphine Catalysts: Methyltrioxorhenium Solvents: Benzene; 10 Min,Rt1.2 2 H,Rt
标题:Organic Reactions Catalyzed By Methylrhenium Trioxide: Reactions Of Ethyl Diazoacetate And Organic Azides
作者:Zhu,Zuolin; Et Al
参考文献:Journal Of The American Chemical Society 日期:1996 卷标:118(41) 页码:9901-9907]
64-10-8 + 959-33-1 = 836-41-9
反应条件:1.1 Catalysts: Potassium Hydroxide; 24 H,135 °C
标题:Base-Catalyzed Synthesis Of Amides And Imines Via C-C And C=c Bond Cleavage
作者:Yadav,Dilip Kumar T.; Et Al
参考文献:Rsc Advances 日期:2015 卷标:5(16) 页码:12387-12391]
32979-94-5 = 836-41-9
反应条件:1.1 Reagents: Boron Trifluoride Etherate,Oxygen Solvents: Acetonitrile-D3
标题:Oxidative Carbon-Carbon Bond Cleavage Reaction Of 1,2-Diamines And 1,2-Amino Alcohols Under An Oxygen Atmosphere
作者:Shimizu,Makoto; Et Al
参考文献:Tetrahedron Letters 日期:2001 卷标:42(50) 页码:8865-8868]
38968-72-8 = 836-41-9
反应条件:1.1 Catalysts: Acetic Acid
标题:A Simple High Yield Conversion Of Imidoyl Chlorides To Imines And Amines
作者:Alper,Howard; Et Al
参考文献:Synthesis 日期:1978 卷标:(10) 页码:781-2]
45821-44-1 = 836-41-9
反应条件:1.1 Solvents: Ethanol; Overnight,Rt
标题:N-Heterocyclic Carbene (Nhc)-Catalyzed Oxidation Of Unactivated Aldimines To Amides Via Imine Umpolung Under Aerobic Conditions
作者:Ramarao,Jakkula; Et Al
参考文献:Rsc Advances 日期:2022 卷标:12(13) 页码:7621-7625
📜P-Methoxydiphenylnitrone置于三苯基膦体系中,化学反应 2.5H,以80%的收率获得产物n-(4-甲氧亚苄基)苯胺
参考文献:Sivasubramanian,S.; Ramamoorthy,V.; Balasubramanian,G.,Organic Preparations And Procedures International,1995,Vol. 27,# 2,P. 221-224
标题:Sivasubramanian,S.; Ramamoorthy,V.; Balasubramanian,G.,Organic Preparations And Procedures International,1995,Vol. 27,# 2,P. 221-224
海关参考信息
- 2902300000-甲苯
2905110000-甲醇
2908199090-其他酚的卤化衍生物
2908999090-其他酚的硝化衍生物 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-5001294-A
优先权日:1988-10-31
标 题 :Synthesis of diaryl alkenes
发明人：HAY ALLAN S
权利人:HAY ALLAN S
摘要:Aromatic alkenes, especially diarylbutadienes are produced in a simple economic process by reaction of an anil with an organic compound having a non-aromatic unsaturated system conjugated with an aromatic system, and a terminal methyl group pendent from the non-aromatic unsaturated system; in particular the organic compound is a propenyl-substituted aromatic compound.
专利号:CN-119303575-A
优先权日:2024-09-19
标题:Novel Cu+Zr (OH)4Application of physical mixed catalyst in catalytic synthesis of N-benzylidene aniline or derivative thereof
专利号:US-6506701-B1
优先权日:1996-05-03
标题:Rapid purification by polymer supported quench
发明人：BOLTON GARY L; BOOTH RICHARD J; CRESWELL MARK W; HODGES JOHN C; WARMUS JOSEPH S; WILSON MICHAEL W
权利人:WARNER LAMBERT CO
摘要:Novel polymer-supported quenching reagents of Formula I,whereinP is a polymer of low chemical reactivity which is soluble or insoluble;Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; andL is one or more chemically robust linkers that join P and Q;are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.
专利号:WO-0039055-A1
优先权日:1998-12-23
标 题:Rapid purification by polyaromatic quench reagents
发明人：DA SILVA MARIANNE; DOWNING DENNIS MICHAEL; WARMUS JOSEPH SCOTT; ZHANG LU-YAN
权利人:WARNER LAMBERT CO; DA SILVA MARIANNE; DOWNING DENNIS MICHAEL; WARMUS JOSEPH SCOTT; ZHANG LU YAN
摘要:Novel polyaromatic hydrocarbon quenching reagents of Formula (I), wherein: P is a polyaromatic hydrocarbon of low chemical reactivity which is soluble; Q is one or more quenching reagents, or an acid or base addition salts thereof, that are capable of selective covalent reaction with unwanted byproducts, or excess reagents; and L is one or more chemically robust linkers or dendritic linkers that join P and Q; are described, as well as methods for their preparation and methods for their use in the rapid purification of synthetic intermediates and products in organic synthesis, combinatorial chemistry and automated organic synthesis.
专利号:CN-103342674-B
优先权日:2013-07-05
标 题 :A class of optically active pyrrole derivatives and its synthesis method
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Aguilar, E.; López, L. A., Science of Synthesis Knowledge Updates, (2014) 2, 77.
摘要:Yanagisawa, A., Science of Synthesis Knowledge Updates, (2010) 4, 196.
摘要:Glushkov, V. A.; Shklyaev, Yu. V., Science of Synthesis Knowledge Updates, (2018) 3, 280.
摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 302.
摘要:Dekeukeleire, S.; D'hooghe, M.; De Kimpe, N., Science of Synthesis Knowledge Updates, (2011) 3, 114.
📝 需求与反馈
尽可能描述清楚需求与问题信息
