CAS: 79319-85-0; 5,5'-(Methylenebis(Azanediyl))Bis(1,3,4-Thiadiazole-2(3H)-Thione)
该化合物是五人环,含有硫和氮原子;该化合物具有广泛的抗微生物活动,使其能有效防治各种植物病原体;Bismerthiazol通常用于制剂,以保护作物免受疾病,从而提高农业生产力;其行动方式涉及干扰目标生物的细胞过程,导致其抑制或死亡;就物理特性而言,Bismerthiazol一般在正常条件下保持稳定,但与许多化学物质一样,应谨慎处理,遵守安全准则,以尽量减少接触风险;环境因素也很重要,因为此类化合物的持久性和潜在生态影响需要在农业环境中负责任地使用和管理.
- 英文名称5,5'-(Methylenebis(Azanediyl))Bis(1,3,4-Thiadiazole-2(3H)-Thione)
- 中文名称5,5'-(亚甲基双(氮杂二烷基))双(1,3,4-噻二唑-2(3H)-硫酮)
- IUPAC名称5,5'-(methylenebis(azanediyl))bis(1,3,4-thiadiazole-2(3H)-thione)
- 其它别名噻枯唑; Bismerthiazol
- CAS编号79319-85-0
- MFCD编号:MFCD01681864
- 分子式:C5H6N6S4分子量:278.4
- 产品CID: 1787718
- 产品分类有机原料→分子砌块→芳杂环类化合物→噻二唑类化合物
物理性质
- 熔点194-198 °C
- 沸点415.4±55.0 °C at 760 mmHg
- 闪点205.0±31.5 °C
- 密度2.1±0.1 g/cm3
- pKa:7.20±0.20(预测)
- PSA:81.42
- LogP:2.19628
- 折射率2.088
- 蒸汽压0.0±1.0 mmHg at 25°C
- 敏感性生产过程中使用二硫化碳等有毒或腐蚀性物品，同时环合反应产生硫化氢气体，因此，设备必须密闭，车间应保持良好的通风状态，硫化氢气体须经吸收处理才能排空。
- 外观形态淡黄色loose粉末
- 储存条件2-8°C
- 产品应用高效,安全内吸性杀菌剂,具有良好的预防和治疗作用.主要用于防治植物细菌性病害,持效期长,药效稳定,对水稻白叶枯病,细菌性条斑病,柑橘溃疡病的防治效果良好,残效期10～14d,对作物无药害.如防治水稻白叶枯病,每百平方米用25%可湿性粉剂15～22.5g(病情严重时适当加量),加水6～7.5kg喷雾.秧田在4～5叶期施药1～2次,间隔7～10d,兼治细菌性条斑病.
- 性质描述纯品为白色长方形柱状或浅黄色疏松细粉,m.p.189～191°C (工业品m.p.172～174°C),分解温度200°C,易溶于二甲基甲酰胺,吡啶,二甲基亚砜等,能溶于甲醇,乙醇,丙酮,难溶于苯,氯仿和水.化学性质稳定.
MSDS等安全信息
合成工艺路线路线简述
- 2349-67-9 = 79319-85-0
反应条件:1.1 Reagents: Formaldehyde
标题:A Nitrogen-15 Nuclear Magnetic Resonance Study Of Some Aminothiazoles
作者:Yu,Jun; Ye,Tinggao
参考文献:Huaxue Xuebao 日期:1987 卷标:45(10) 页码:1020-3]
2349-67-9 = 79319-85-0
反应条件:1.1 50 °C
标题:Synthesis And Antibacterial Activity Of Bisthioether Derivatives Containing A 1,3,4-Thiadiazole Moiety
作者:Chen,Xuehai; Yin,Juan; Li,Pei; He,Ming; Jin,Linhong; Et Al
参考文献:Phosphorus 日期:2014 卷标:189(1) 页码:134-142
海关参考信息
- 2921199090-其他无环单胺
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-10906880-B2
优先权日:2016-01-26
标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application
发明人：FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI
权利人:UNIV NANKAI
摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.
专利号:CN-115057881-A
优先权日:2022-06-15
标题:A kind of organocatalytic synthesis of chiral tetra-substituted silanal compounds and method for derivatization thereof
专利号:CN-102924403-B
优先权日:2012-11-20
标 题:Synthesis method of bismerthiazol
专利号:CN-104447617-A
优先权日:2014-12-17
标题 :Synthesis and application of a class of nitroaminoguanidine compounds containing 1,2,3-thiadiazole
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
[参考文献]: Jin-Tao Wang, Et Al. [参考文献]: Sichuan Da Xue Xue Bao Yi Xue Ban. 2004 Nov;35(6):770-3.[参考文献]: Yong-Jie Qiu, Et Al. [参考文献]: Sichuan Da Xue Xue Bao Yi Xue Ban. 2010 Jan;41(1):73-6.
[参考文献]: Z D Fu, Et Al. [参考文献]: Zhonghua Yu Fang Yi Xue Za Zhi. 1984 May;18(3):146-50.
合成参考文献
摘要:Zhejiang Yike Daxue Xuebao. Journal of Zhejiang Medical University., 14(267), 1985
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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