合成目标产物 Aurintricarboxylic Acid 主要起始原料 Formaldehyde And Salicylic Acid
(文献来源)合成步骤主要原料 Formaldehyde 和 Salicylic Acid
📜水杨酸置于聚合甲醛,亚硝酸体系中,化学反应生成 金精三羧酸 参考文献:Structural And Magnetic Properties Of Co-C Composite Films And Co/c Multilayer Films 标题:Structural And Magnetic Properties Of Co-C Composite Films And Co/c Multilayer Films 摘要:Co-C Composite Films And Co/c Multilayer Films Have Been Prepared By A Method Incorporating Ion Beam Sputtering And Plasma Chemical Vapor Deposition. It Has Been Found That The Structure And Magnetic Properties Of Both The Co-C Composite And The Co/c Multilayer Films Depend Strongly On The Substrate Temperature During Deposition. The Co-C Composite Film Deposited At Roorn Temperature Is Amorphous,With Relatively Low Saturation Magnetization And Coercivity. On The Other Hand,The Film Deposited At 250 Degreesc Is Composed Of Fine Co Crystallites Separated By Amorphous C Or Co-C Phase. As A Result,Both The Saturation Magnetization And Coercivity Are Increased Compared With The Film Deposited At Room Temperature. When Deposited At Room Temperature,The Co/c Multilayer Film Exhibits Good Periodicity,With A Period Of 70 Mn (Co: 40 Nm,C: 30 Nm) And Sharp And Flat Co-C Interfaces. High Magnetization (602 Emu/cm(3)) And Low Coercivity (1.6 Oe) Are Obtained For Such A Film. However,Increasing The Substrate Temperature To 250 Degreesc Was Found To Be Detrimental To The Magnetic Properties Due To The Formation Of Cobalt Carbide At The Co-C Interface. DOI:10.1007/s003390000682
专利号:US-6818633-B2 优先权日:2001-06-29 标题:Antiviral compounds and methods for synthesis and therapy 发明人:BALZARINI JAN M R; DE CLERCQ ERIK D A; HOLY ANTONIN 权利人:ACAD OF SCIENCE CZECH REPUBLIC; REGA STICHTING 摘要:Novel compounds are provided having formula (I)whereR1, R2, R3, R4, Z, X and * are defined herein. Also provided are antiviral methods for use and processes for synthesis of the compounds of formula (I).
专利号:US-5874269-A 优先权日:1995-06-07 标 题 :Purified proteins, recombinant DNA sequences and processes for controlling the ripening of coffee plant 发明人:STILES JOHN I; MOISYADI ISTEFO; NEUPANE KABI RAJ 权利人:UNIV HAWAII 摘要:The invention provides purified proteins, DNA sequences that code on expression therefore and recombinant DNA molecules, including hosts transformed therewith for transforming coffee plants to suppress the expression of enzymes necessary for ethylene synthesis. The DNA sequences and recombinant DNA molecules are characerized in that they code on expression for the enzymes ACC synthase or ACC oxidase that are elements of the pathway for ethylene biosynthesis in coffee plants. Coffee plants are transformed with vectors containing ACC synthase and/or with ACC oxidase DNA sequences that code on expression for the respective mRNA that is antisense to the mRNA for ACC synthase and/or ACC oxidase. The resulting antisense mRNA binds to the respective ACC synthase and/or ACC oxidase mRNA, thereby inactivating the mRNA encoding one or more enzymes in the pathway for ethylene synthesis. The described DNA sequences can also be used to block synthesis of ACC synthase or ACC oxidase using co-suppression. The result in either event is that the transformed plants are incapable of synthesizing ethylne, though other aspects of their metabolism is not affected.
专利号:US-2022089618-A1 优先权日:2019-01-29 标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks 发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M 权利人:EXXONMOBIL RES & ENG CO 摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.
专利号:US-10737239-B2 优先权日:2015-11-27 标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks 发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich 权利人:BASF SE 摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.
专利号:US-9951095-B2 优先权日:2014-05-16 标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks 发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI 权利人:TEXAS A & M UNIV SYS 摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.
专利号:US-7115592-B2 优先权日:2003-06-16 标题:Phosphonate substituted pyrimidine compounds and methods for therapy 发明人:BALZARINI JAN M R; DE CLERCQ ERIK D A; HOLY ANTONIN; HOCKOVA DANA 权利人:BIOCHEMISTRY OF THE ACADEMY OF 摘要:Novel compounds are provided having formula (I) n nwheren n R 1 , R 2 , R 3 , R 4 , Z, X and * are defined herein. Also provided are antiviral methods for use and processes for synthesis of the compounds of formula (I).
1: Yoo J, Kim JH, Robertson KD, Medina-Franco JL. Molecular modeling of inhibitors of human DNA methyltransferase with a crystal structure: discovery of a novel DNMT1 inhibitor. Adv Protein Chem Struct Biol. 2012;87:219-47. doi: 10.1016/B978-0-12-398312-1.00008-1. Review. 2: Zhan P, Li Z, Liu X. Cosalane and its analogues: a unique class of anti-HIV agents. Mini Rev Med Chem. 2010 Sep;10(10):966-76. Review. doi: 10.1002/med.20179. Review. doi: 10.1160/TH07-12-0718. Review. Review. Review. Japanese. Review. Review. Review. French. Review. Review. Review.
合成参考文献
参考文献:10.1093/intimm/dxr058 摘要:Lim DG, Park YH, Kim SE, Kim YH, Park CS, Kim SC, Park CG, Han DJ. Aurintricarboxylic acid promotes the conversion of naive CD4+CD25- T cells into Foxp3-expressing regulatory T cells. Int Immunol. 2011 Sep;23(9):583–92. doi: 10.1093/intimm/dxr058.