CAS: 2636-26-2; Cyanophos

上下游产品

potassium p-cyanophenoxide dimethyl chlorothiophosphate MEP 4-cyanophenolNatriumsalz des Thiophosphorsaeure-O,O-dimethylesters p-cyanophenyl dimethyl phosphate O-(4-carbamoylphenyl) O,O-dimethyl thiophosphate

📜硫代膦酸二甲酯,4-羟基苯甲腈置于叔丁基过氧化氢,Lithium Iodide体系中,用 水,乙腈 用作溶剂,化学反应 0.25H,以43%的收率获得杀螟腈
参考文献:Lii / Tbhp介导的p(o)-h化合物与酚和各种亲核试剂的氧化交叉偶联:直接获得有机磷酸酯的合成
标题:Lii / Tbhp介导的p(o)-h化合物与酚和各种亲核试剂的氧化交叉偶联:直接获得有机磷酸酯的合成
摘要:使用氧化交叉偶联策略描述了p(o)-h化合物与各种亲核试剂(例如苯酚,醇,胺和烯醇)的直接磷酸化作用.已经实现了羟基化的萘基和杂芳基的磷酸化.该转化的主要特征是反应时间短,官能团耐受性强和底物范围广.
Doi:10.1002/ejoc.201901362

专利信息

专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人：NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

专利号:WO-2021074309-A1
优先权日:2019-10-16
标 题:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人：WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; SEN INDIRA; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-3,4-dihydroisoquinoline derivative of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale) when spayed on plants), as well as comparative data against three prior art compounds (e.g. pages 52 to 85; formulation examples; examples A1 to A3; table E; compounds E.01 to E.187; biological examples). Exemplary compounds are e.g.: 5-bromo-1-(8-fluoro-3-quinolyl)spiro[4H-isoquinoline-3,1'- cyclopropane] (example A1) 5-bromo-1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline (example A2) 1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline-5-carbonitrile (example A3)

专利号:WO-2021074311-A1
优先权日:2019-10-16
标题:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人：WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola, Monographella nivalis, Fusarium culmorum and/or Gibberella zeae when spayed on plants) (e.g. pages 47 to 55; examples A1 and A2; compounds E.01 to E.17; table E). An exemplary compounds is e.g.: 3-(5-bromo-3,3-dimethyl-2,4-dihydro-1 H-isoquinolin-1-yl)-8-fluoro- quinoline (example A1)

专利号:WO-9832790-A1
优先权日:1997-01-27
标 题:Porous articles with surface functionality and uses thereof
发明人：KOONTZ STEVEN L; DEVIVAR RODRIGO V; FABRICANT JILL D; GOLDKNOPF IRA L
权利人:FLOWGENIX CORP; KOONTZ STEVEN L; DEVIVAR RODRIGO V; FABRICANT JILL D; GOLDKNOPF IRA L
摘要:Porous organic articles having no surface functionality may be treated by remote plasma discharge to introduce oxygen or nitrogen atoms directly bonded to the surface of the article, including the interstitial surface. These oxygen and nitrogen atoms provide chemical handles through which a variety of useful moieties can be bonded to the article. Modified porous organic articles are useful in the solid phase synthesis of biomolecules when nucleosides, amino acids, or their derivatives are bonded directly or indirectly to the nitrogen or oxygen atoms. Alternatively, porous solid supports can be treated to introduce chromatographically active groups, such as an anion exchanger, a cation exchanger, an hydrophobic group, a hydrazide group, a reactive group of covalent bond formation through protein amino groups, a substituent group for reversed phase chromatography, and a substituent group for chiral chromatography. Moreover, surface-functionalized porous articles comprising an immobilized diagnostic agent can be used for diagnosing or monitoring patient conditions and diseases.

专利号:US-11213031-B2
优先权日:2017-11-13
标 题:Tetrazolylpropyl derivatives and their use as fungicides
发明人：SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
权利人:BAYER AG; BAYER CROPSCIENCE AG
摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.

专利号:US-4772677-A
优先权日:1986-12-06
标 题:Highly stretchable elasthane fibres with improved properties
发明人：KAUSCH MICHAEL; SUELING CARLHANS; SCHROEER HANS; WOLF KARLHEINZ; DAUSCHER RUDI
权利人:BAYER AG
摘要:This invention relates to highly stretchable elasthane fibres (Spandex fibres) based on segmented polyurethane(urea)s with improved elastic properties and high resistance to microbial degradation, characterized in that the polyurethane(urea)s used for the synthesis of the elasthanes are prepared from mixtures of relatively high molecular weight copolyester diols in the molecular weight range of from 2,500 to 4,000 and relatively high molecular polytetrahydrofurandiols in the molecular weight range of from 1,500 to 3,000.