CAS: 484-89-9; 3-Hydroxy-2-Methoxy-5-Methyl-1,4-Benzoquinone

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    2,3-二甲氧基-5-甲基-1,4-苯醌 2,3-Dimethoxy-5-Methyl-1,4-Benzoquinone 605-94-7

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      📜3,4,5-三甲氧基甲苯置于vanadia Sodium Chlorate,Sodium Hydroxide,三氯化铝,硫酸,双氧水体系中,用 甲醇,乙醚,水 作为反应溶剂,化学反应 9.83H,反应生成 烟曲霉醌
      参考文献:Synthesis And Spectroscopic Characterization Of [1'-14C]Ubiquinone-2,[1'-14C]-5-Demethoxy-5-Hydroxyubiquinone-2,And [1'-14C]-5-Demethoxyubiquinone-2
      标题:Synthesis And Spectroscopic Characterization Of [1'-14C]Ubiquinone-2,[1'-14C]-5-Demethoxy-5-Hydroxyubiquinone-2,And [1'-14C]-5-Demethoxyubiquinone-2
      摘要:
      DOI:10.1002/1099-0690(200209)2002:17<3015::Aid-Ejoc3015>3.0.Co;2-G

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      专利信息


      专利号:US-6750049-B1
      优先权日:1999-03-23
      标题 :Synthesis of 1,2,3,4-tetrahydroxybenzenes and 1,2,3-trihydroxybenzenes using myo-inositol-1-phosphate synthase and myo-inositol 2-dehydrogenase
      发明人：FROST JOHN W; HANSEN CHAD A
      权利人:UNIV MICHIGAN STATE
      摘要:A bioengineered synthesis scheme for the production of 1,2,3,4-tetrahydroxybenzene from a carbon source is provided. Methods of producing 1,2,3,4-tetrahydroxybenzene from a carbon source based on the synthesis scheme are also provided. Methods are also provided for converting 1,2,3,4-tetrahydroxybenzene to 1,2,3-trihydroxybenzene by catalytic hydrogenation.

      专利号:WO-0056911-A1
      优先权日:1999-03-23
      标题 :Synthesis of 1,2,3,4-tetrahydroxybenzenes and 1,2,3-trihydroxybenzenes using myo-inositol-1-phosphate synthase and myo-inositol 2-dehydrogenase

      专利号:US-2004209337-A1
      优先权日:1999-03-23
      标 题 :Synthesis of 1,2,3,4-tetrahydroxybenzenes from biomass-derived carbon

      专利号:EP-1169466-A1
      优先权日:1999-03-23
      标 题:Synthesis of 1,2,3,4-tetrahydroxybenzenes and 1,2,3-trihydroxybenzenes using myo-inositol-1-phosphate synthase and myo-inositol 2-dehydrogenase

      专利号:CA-2366222-A1
      优先权日:1999-03-23
      标 题:Synthesis of 1,2,3,4-tetrahydroxybenzenes and 1,2,3-trihydroxybenzenes using myo-inositol-1-phosphate synthase and myo-inositol 2-dehydrogenase

      专利号:EP-1169466-A4
      优先权日:1999-03-23
      标 题 :SYNTHESIS OF 1,2,3,4-TETRAHYDROXYBENZENES AND 1,2,3-TRIHYDROXYBENZENES USING MYO-INOSITOL-1PHOSPHATE SYNTHASE AND MYO-INOSITOL 2-DEHYDROGENASE

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      主要参考文献


      1: Packter NM. Studies on the biosynthesis of quinones in fungi. Incorporation of 6-methylsalicylic acid into fumigatin and related compounds in Aspergillus fumigatus I.M.I. 89353. Biochem J. 1965 Nov;97(2):321-32. doi: 10.1042/bj0970321.
      2: Wang L, Zhang X, Zhang K, Zhang X, Zhu T, Che Q, Zhang G, Li D. Overexpression of Global Regulator PbrlaeA Leads to the Discovery of New Polyketide in Fungus Penicillium Brocae HDN-12-143. Front Chem. 2020 Apr 21;8:270. doi: 10.3389/fchem.2020.00270.
      3: Kang D, Son GH, Park HM, Kim J, Choi JN, Kim HY, Lee S, Hong SB, Lee CH. Culture condition-dependent metabolite profiling of Aspergillus fumigatus with antifungal activity. Fungal Biol. 2013 Mar;117(3):211-9. doi: 10.1016/j.funbio.2013.01.009. Epub 2013 Feb 14. 32(4):687-96. doi: 10.1042/bj0320687.

      合成参考文献


      参考文献:10.3891/acta.chem.scand.17-1771
      摘要:Pettersson G, Hasselquist H, Theander O, Hatanaka A, Munch-Petersen J. Toluquinones from Aspergillus fumigatus. Acta Chem. Scand. 1963;17():1771–6. doi: 10.3891/acta.chem.scand.17-1771.
      参考文献:10.3891/acta.chem.scand.18-0335
      摘要:Pettersson G, Motzfeldt K, Lindberg B, Hoffman RA, Nilsson L. The Biosynthesis of Spinulosin in Aspergillus fumigatus. Acta Chem. Scand. 1964;18():335–43. doi: 10.3891/acta.chem.scand.18-0335.
      参考文献:10.1007/978-3-0348-9389-3_11
      参考文献:10.1007/978-94-010-9132-9_3
      摘要:Herbert RB. Polyketides. 1989. In: The Biosynthesis of Secondary Metabolites.
      参考文献:10.1007/978-3-642-85665-5_11
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