📜1,3,5-三氯苯,1-芘硼酸置于c28H44N2Ppd,Potassium Carbonate体系中,用 乙醇,水 用作溶剂,化学反应 8.0H,以82%的收率获得1,3,5-三(1-芘基)苯
参考文献:极活泼的通用催化剂,用于未反应的芳烃的铃木偶联反应
标题:极活泼的通用催化剂,用于未反应的芳烃的铃木偶联反应
摘要:β-二酮亚氨基膦pd络合物2A用作强力催化剂,可在温和条件下轻松进入反应性较低的芳基氯化物的suzuki偶联反应.可以在0.1 Mol%的低催化剂负载量下有效地偶联各种空间受阻和失活的芳基氯化物.此外,该催化体系在一锅多联中也被证明是非常有效的.
Doi:10.1021/ol102677R
专利信息
专利号:DE-112012006817-B3
优先权日:2011-07-22
标题 :Process for the synthesis of a dibenzo [c, g] carbazole compound.
专利号:US-2025042877-A1
优先权日:2021-11-30
标题:Organic compound, organic device, light-emitting apparatus, and electronic appliance
发明人:HAYASHI YUKI; KAWAKAMI SACHIKO; HASHIMOTO NAOAKI
权利人:SEMICONDUCTOR ENERGY LAB
摘要:A novel compound, a synthesis method thereof, and an organic device including the novel compound are provided. A compound represented by General Formula (G1) is provided. In General Formula (G1), each of R1, R2, and R5 to R7 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms. R3 represents a condensed ring composed of 4 to 10 rings containing nitrogen as an element forming the ring, and R4 represents any of a substituted or unsubstituted condensed ring having 1 to 60 carbon atoms, a substituted or unsubstituted aryl group with a molecular weight of 78 or more, and a substituted or unsubstituted heteroaryl group with a molecular weight of 80 or more. At least one of A1 to A3 represents nitrogen, and each of the others represents substituted carbon. Each of substituents of A1 to A3 independently represents any of hydrogen (including deuterium), an alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 1 to 60 carbon atoms, and a substituted or unsubstituted heteroaryl group having 1 to 60 carbon atoms.