CAS: 23582-02-7; ((Phenylphosphinediyl)Bis(Ethane-2,1-Diyl))Bis(Diphenylphosphine)

该化合物是一种多分辨磷离子,广泛用于协调化学和同质催化,其主要优势在于其灵活,三角结构,能够与过渡金属产生强烈的切合关系,增强催化稳定性和活动.苯基和二苯基磷基乙基组的存在提供了...

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CAS号100968-20-5 bis-(2-ethoxy-e... | CAS号33847-61-9 fac-tricarbonyl... | CAS号3030-47-5 五甲基二乙烯三胺

合成工艺路线路线简述

  • 合成目标产物 Bis(2-Diphenylphosphinoethyl)Phenylphosphine 主要起始原料 Phenyl Phosphine And Diphenylvinylphosphine
  • (文献来源)合成步骤主要原料 Phenyl Phosphine 和 Diphenylvinylphosphine
📜苯基膦,乙烯基二苯基膦置于偶氮二异丁腈体系中,化学反应生成双(2-二苯基膦乙基)苯基磷
参考文献:Issleib,K.; Weichmann,H.,Zeitschrift Fur Chemie,1971,Vol. 11,P. 188-189
标题:Issleib,K.; Weichmann,H.,Zeitschrift Fur Chemie,1971,Vol. 11,P. 188-189

海关参考信息

专利信息


专利号:US-11407993-B2
优先权日:2017-02-14
标 题 :Method for the synthesis of DNA conjugates by micellar catalysis
发明人:BHAT AVINASH SHASHIDHAR; KLIKA SKOPIC MATEJA; BRUNSCHWEIGER ANDREAS; WEBERSKIRCH RALF
权利人:UNIV DORTMUND TECH
摘要:A method for the synthesis of a chimeric conjugate molecule by micellar catalysis that may form part of DNA-encoded compound libraries. A DNA-coupled organic starter molecule may be reacted with another organic compound, using a catalyst located within a micelle, to form a conjugate of an organic candidate compound coupled to a DNA identifier tag.

专利号:WO-0125179-A1
优先权日:1999-10-01
标 题:Preparation of tetracyclic intermediates
发明人:CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
权利人:INST OF DRUG TECHNOLOGY AUSTRA; CHEN QING PING; WOODS ROSS ALEXANDER; ELLIOTT ROBYN LOUISE
摘要:The invention provides a process for preparing deoxytetracyclic compounds of formula (I) useful in the synthesis of anthracyclines by the rearrangement of thiono ester derivatives followed by reduction, as well as intermediates useful therefor. In said formula, R is H or optionally protected OH.

专利号:US-6303717-B1
优先权日:1997-02-05
标 题:Metal catalyzed synthesis of hyperbranched ethylene and/or α-olefin polymers
发明人:SEN AYUSMAN; KIM JANG SUB; PAWLOW JAMES H; MURTUZA SHAHID; KACKER SMITA; WOJCINSKI III LOUIS M
权利人:UNIV PENN STATE RES FOUND
摘要:Oily hyperbranched polymers derived from ethylene, propylene, butene and/or a C 5 -C 24 α-olefin, and a method for their synthesis, are disclosed. The polymers have non-regular microstructures and are characterized by a ratio ()of methyl hydrogens centered around 0.85 ppm on the 1H-NMR spectra of the polymers relative to total aliphatic hydrogens of from about 0.40 to about 0.65 for polymers derived from ethylene or butene, and a ratio ()of from greater than 0.50 to about 0.65 for polymers derived from propylene. A method for grafting hyperbranched polymers derived from ethylene, propylene, butene and/or a C 5 -C 24 α-olefin onto aromatic rings in organic molecules and polymers, and the resulting grafted materials, are also disclosed. The hyperbranched polymers and grafted materials are useful, for example, as lubricants and lubricant additives.

专利号:WO-2013076053-A1
优先权日:2011-11-25
标题:Synthesis of polyalkylene polyamines with low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
发明人:STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
权利人:BASF SE; STRAUTMANN JULIA; SCHAUB THOMAS; HUEFFER STEPHAN; MAAS STEFFEN; PACIELLO ROCCO
摘要:The invention relates to a method for the production of polyalkylene polyamines by homogeneously catalyzed alcohol amination, wherein aliphatic alkanolamines are reacted with each other or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols in the presence of a homogeneous catalyst while eliminating water and in the presence of hydrogen gas. The invention further relates to polyalkylene polyamines, which can be obtained by said methods, and to polyalkylene polyamines which contain hydroxyl groups, secondary amines or tertiary amines. The invention finally relates to uses of said polyalkylene polyamines as adhesion promoters in inks, adhesion promoters in composite films, cohesion promoters in adhesives, cross-linkers/hardeners for resins, primers for paints, wet adhesion promoters for dispersion paints, complexing agents and flocculants, penetration auxiliaries for use in wood preservation, corrosion inhibitors, and immobilization agents of proteins and enzymes.

专利号:US-11518726-B2
优先权日:2017-10-11
标题 :Synthesis of bicyclo[2.2.2]octane derivatives
发明人:HU YUE RACHEL; HEMBRE ROBERT THOMAS; TUSTIN GERALD CHARLES; LIU ZHUFANG; ADAMS STEVEN J
权利人:EASTMAN CHEM CO
摘要:Provided is a process for the preparation of certain 1,4-bicyclo[2.2.2]octane derivatives. The new synthetic procedure involves treating 1,4-dimethylene cyclohexane with an oxidizing agent in the presence of a transition metal catalyst to afford an oxo-substituted bicyclo[2.2.2]octane species. This intermediate structure can then be further derivatized. The processes of this disclosure thus affords a novel and simplified means for the commercial production of a wide variety of bicyclo[2.2.2]octane derivatives.

专利号:US-4594463-A
优先权日:1985-01-28
标 题:Synthesis of aldehydes from alcohols
发明人:WEGMAN RICHARD W; MILLER DEBORAH S
权利人:UNION CARBIDE CORP
摘要:A catalyst has been found for the low pressure hydroformylation of alcohols to produce aldehydes. This catalyst consists of a rhodium containing compound, an iodide containing compound, and a chelating Group V compound, which is used alone or in combination with a monodentate, Group V compound. n It is the first rhodium-based catalyst that generates acetaldehyde via hydroformylation of the methanol. The reaction is typically carried out at 160°-180° C. and 1000-2000 psi. The acetaldehyde rate and selectivity are 1-5 Mhr -1 and 50-75%. Conventional cobalt catalysts require operating pressures of at least 3000-6000 psi in order to obtain reasonable productivities.

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主要参考文献

参考标题: Methods, Processes And Intermediates For Preparing Chroman Compounds Procédés, Processus Et Intermédiaires Pour La Préparation De Composés Chromane
摘要:This Disclosure Describes An Economical And Scalable Method And Process To Synthesize The Calcium Sensing Receptor (Casr) Modulating Agent 2-Methyl-5-((2R,4S)-2-((((R)-1-(Naphthalen-1-Yl)Ethyl)Amino)Methyl)Chroman-4-Yl)Benzoic Acid, Its Intermediates And Pharmaceutically Acceptable Salts Therefor. Uses Of Said Intermediates For Synthesis Of Compounds Which May Be Intermediates To The Synthesis Of 2-Methyl-5-((2R,4S)-2-((((R)-1-(Naphthalen-1-Yl)Ethyl)Amino)Methyl)Chroman-4-Yl)Benzoic Acid Are Also Described Herein.

合成参考文献


摘要:O'Connor, J. M., Science of Synthesis, (2001) 1, 696.
摘要:Ito, T.; Minato, M., Science of Synthesis, (2003) 2, 358.
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