CAS: 1883-78-9; 2-((Isopropylthio)Methyl)Furan

相似化合物

1438-91-1 58066-86-7 13678-68-7

Furan-2-Ylmethyl 2-Isopropyl Sulfoxide置于四羟基二硼体系中,用 甲苯 用作溶剂,以95%的收率获得硫酸异丙基糠酯
参考文献:使用 B2(Oh)4 作为脱氧剂,在无催化剂和添加剂的情况下将亚砜化学选择性还原为硫化物
标题:使用 B2(Oh)4 作为脱氧剂,在无催化剂和添加剂的情况下将亚砜化学选择性还原为硫化物
摘要:描述了一种在没有催化剂和添加剂的情况下使用四羟基二硼 [b 2 (Oh) 4 ] 作为脱氧剂将亚砜还原为硫化物的操作简单实用的方法.多种二芳基亚砜,二烷基亚砜和芳基/烷基亚砜成功转化为相应的硫化物,收率为 92-99%.通过36个实例和克级合成证明了其适用性和实用性.该工作拓展了b 2 (Oh) 4从芳环,羰基,烯烃,炔烃,亚胺,硝基化合物,卤化物到亚砜的还原反应的应用领域.
Doi:10.1016/j.Tet.2023.133411

专利信息

专利号:US-6797819-B1
优先权日:1998-06-11
标 题 :Alkaloids
发明人：SHAIR MATTHEW; WESTWOOD NICHOLAS; PELISH HENRY EFREM; KIRCHHAUSEN THOMAS; FENG YAN
权利人:HARVARD COLLEGE; CBR INST FOR BIOMED RES INC
摘要:The present invention provides novel alkaloid compounds and collections of these compounds, and provides methods for the synthesis of these compounds using biomimetic synthetic strategies. Additionally, the present invention provides pharmaceutical compositions and methods for treating disorders such as bacterial infections, proliferative diseases, and reproductive disorders, to name a few.

专利号:CN-116178225-A
优先权日:2022-12-11
标题 :A kind of method of sulfoxide reduction synthesis thioether compound