CAS: 17872-92-3; Trimethyl((Phenylsulfonyl)Methyl)Silane

该化合物是一种有机合成的多用途试剂,以其精致稳定性和高纯度而著称,它促进各种变异,包括丝绸和磺化,并且与多种溶剂兼容,其独特的结构特征有助于其在化学反应中的效率和可靠性.

结构式图片

欧盟法规

ECHA物质C&L通报

上下游产品

CAS号17873-08-4 三甲基(苯硫甲基)硅烷 | CAS号3112-85-4 甲基苯基砜 | CAS号75-77-4 三甲基氯硅烷 | CAS号930-69-8 苯硫酚钠 | CAS号100-68-5 茴香硫醚 | CAS号5535-48-8 苯基乙烯基砜 | CAS号16212-06-9 反式苯基-β-肉桂砜 | CAS号100289-55-2 1-acetoxy-1-phe... | CAS号28975-80-6 Benzene,(1-prop... | CAS号76380-14-8 prop-1-en-2-yls... | CAS号85969-76-2 trimethyl(3-phe... | CAS号90020-44-3 cyclohexylidene... | CAS号61242-29-3 4-(benzenesulfo... | CAS号5418-11-1 苯基trans-苯乙烯基砜 | CAS号54897-35-7 2-methylprop-1-...

合成工艺路线路线简述

    📜苯甲砜置于正丁基锂,三甲基氯硅烷体系中,用 四氢呋喃,正己烷,水 用作溶剂,化学反应生成苯基三甲基硅基甲砜
    参考文献:Azetidine Derivatives,Their Preparation And Pharmaceutical Compositions Containing Them
    标题:Azetidine Derivatives,Their Preparation And Pharmaceutical Compositions Containing Them
    摘要:式1中r代表cr1R2,C═c(R5)So2R6或c═c(R7)So2烷基基团,它们的制备以及含有它们的药物组合物.

    海关参考信息

    专利信息


    专利号:US-5637719-A
    优先权日:1989-06-09
    标 题 :Reagents for rapid peptide synthesis
    发明人:CARPINO LOUIS A; PHILBIN MICHAEL
    权利人:RES CORP TECHNOLOGIES INC
    摘要:The compounds of the present invention are adaptable as blocking or protecting groups for an amine composition useful in peptide synthesis. The present invention is directed to a method of protecting an amino group of an organic molecule during a reaction which modifies a portion of the molecule other than the protected amino group.

    专利号:EP-0401817-B1
    优先权日:1989-06-09
    标题 :Reagents for rapid peptide synthesis
    发明人:CARPINO LOUIS A; PHILBIN MICHAEL
    权利人:RES CORP TECHNOLOGIES INC
    摘要:This invention relates to compounds of the formula: wherein R is an electron withdrawing group; R1 is H or COZ; X1 and X2 are independently H, lower alkyl, aryl, aryl lower-alkyl or polystyrene or R and X1 taken together with the carbon atoms to which they are attached form a ring containing from 4 to 15 ring carbon atoms and may contain up to 2 heteroatoms, wherein the heteroatoms are O, S, or N; and Z is an amino acid residue, a peptide residue or a leaving group. The compounds of the present invention are adaptable as blocking or protecting groups for an amine composition useful in peptide synthesis. The present invention is also directed to a method of protecting an amino group of an organic molecule during a reaction which modifies a portion of the molecule other than the protected amino group.

    专利号:JP-2832643-B2
    优先权日:1989-10-23
    标题:Synthesis of amino acid fluorides as peptide coupling agents and their use

    专利号:WO-9105564-A1
    优先权日:1989-10-23
    标题:Synthesis and use of amino acid fluorides as peptide coupling reagents

    专利号:EP-0496836-A4
    优先权日:1989-10-23
    标题 :Synthesis and use of amino acid fluorides as peptide coupling reagents

    专利号:EP-0496836-A1
    优先权日:1989-10-23
    标题 :SYNTHESIS AND USE OF AMINO ACID FLUORIDES AS PEPTIDE COUPLING REAGENTS.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 276.
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