CAS: 1159-86-0; 1,2-Phenylenebis(Phenylmethanone)

该化合物是一种有机化合物,其结构特征是两个苯并基组,附于一个中苯环,其化学特性包括能够承受典型的芳香化合物的各种反应,例如电极替代;此外,该化合物显示出荧光,在某些分析应用中有用;安全考虑包括谨慎处理,因为它在接触皮肤或眼睛时可能引起刺激;建议与该化合物合作时进行适当的通风,以避免吸入粉尘或蒸气.

结构式图片

相似化合物

16780-82-8 84-65-1 131-58-8

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上下游产品

N-phenylphthalimide bromobenzene phthalic anhydride ethyl bromide 1,2-bis-(α-phenylhydrazono-benzyl)-benzene 9-phenylanthracene 1,3-diphenylisobenzofuran

合成工艺路线路线简述

    📜邻苯二甲酸二甲酯 反应生成1,2-二苯基苯
    参考文献:Guyot; Catel,Bulletin De La Societe Chimique De France,1906,Vol. <3> 35,P. 554
    标题:Guyot; Catel,Bulletin De La Societe Chimique De France,1906,Vol. <3> 35,P. 554

    海关参考信息

    专利信息


    专利号:US-4405523-A
    优先权日:1982-03-24
    标题:Process for preparation of benzophenone, anthraquinone and O-dibenzoylbenzene
    发明人:FIELDS ELLIS K
    权利人:STANDARD OIL CO INDIANA
    摘要:Process for the concurrent synthesis of benzophenone, anthraquinone, and o-dibenzoylbenzene by pyrolysis of benzoic acid salts of yttrium, erbium, and dysprosium and mixtures thereof at temperatures of from about 200 DEG C. to 500 DEG C. and a pressure of about 0.1 to about 100 atmospheres. In an alternative method, a benzoic acid compound is passed through an oxide of yttrium, erbium, dysprosium and mixtures thereof in the presence of steam.

    专利号:US-5194562-A
    优先权日:1989-02-22
    标题:Nucleophilic displacement method for synthesis of non-rigid PBZ polymers
    发明人:INBASEKARAN MUTHIAH N; MULLINS MICHAEL J
    权利人:DOW CHEMICAL CO
    摘要:Azole rings, such as oxazole and thiazole rings, can activate an aromatic ring bonded to a leaving group such as a halogen atom so that the aromatic ring will undergo aromatic nucleophilic substitution. The reaction is useful for making ethers, thioethers and amines containing azole rings. In particular, monomers having azole rings, activated aromatic rings with leaving groups and nucleophilic moieties can react under conditions of aromatic nucleophilic displacement to form non-rigid rob PBZ polymers. The non-rigid rod PBZ polymers can be used to form molecular composites with rigid rod PBZ polymers which molecular composites are not substantially phase separated.

    专利号:US-5216110-A
    优先权日:1989-02-22
    标题 :Monomers useful in nucleophilic displacement synthesis of polybenzazole polymers
    发明人:INBASEKARAN MUTHIAH N; MULLINS MICHAEL J
    权利人:DOW CHEMICAL CO
    摘要:Azole rings, such as oxazole and thiazole rings, can activate an aromatic ring bonded to a leaving group such as a halogen atom so that the aromatic ring will undergo aromatic nucleophilic substitution. The reaction is useful for making ethers, thioethers and amines containing azole rings. In particular, monomers having azole rings, activated aromatic rings with leaving groups and nucleophilic moieties can react under conditions of aromatic nucleophilic displacement to form non-rigid rod PBZ polymers. The non-rigid rod PBZ polymers can be used to form molecular composites with rigid rod PBZ polymers which molecular composites are not substantially phase separated.

    专利号:US-5104960-A
    优先权日:1989-02-22
    标 题:Nucleophilic displacement method for synthesis of non-rigid PBZ polymers
    发明人:INBASEKARAN MUTHIAH N; MULLINS MICHAEL J
    权利人:DOW CHEMICAL CO
    摘要:Azole rings, such as oxazole and thiazole rings, can activate an aromatic ring bonded to a leaving group such as a halogen atom so that the aromatic ring will undergo aromatic nucleophilic substitution. The reaction is useful for making ethers, thioethers and amines containing azole rings. In particular, monomers having azole rings, activated aromatic rings with leaving groups and nucleophilic moieties can react under conditions of aromatic nucleophilic displacement to form non-rigid rod PBZ polymers. The non-rigid rod PBZ polymers can be used to form molecular composites with rigid rod PBZ polymers which molecular composites are not substantially phase separated.

    专利号:US-3872218-A
    优先权日:1972-03-06
    标题 :Synthesis of alkali metal tetracarbonylferrates
    发明人:COLLMAN JAMES P; WINTER STANLEY R
    权利人:UNIV LELAND STANFORD JUNIOR
    摘要:Production of alkali metal tetracarbonylferrate by reaction of alkali metal with an iron carbonyl, preferably iron pentacarbonyl (Fe(CO)5), in a suitable solvent and in the presence of an electron carrier. Alkali metal may be in solid phase or liquid phase.

    专利号:WO-2018115033-A1
    优先权日:2016-12-21
    标题:Poly(ether ketone ketone) polymers, corresponding synthesis methods and polymer compositions and articles made therefrom
    发明人:LOUIS CHANTAL
    权利人:SOLVAY SPECIALTY POLYMERS USA
    摘要:Described herein are PEKK polymers having improved processability and improved crystallinity. It was surprisingly found that PEKK polymers formed using a specifically adapted nucleophilic synthesis route, in which different monomers are added to the polymerization reaction at different points during the synthesis, had lower glass transition temperatures ('Tg') and increased crystallinities, relative to PEKK polymers formed using traditional nucleophilic synthesis routes ('traditional PEKK polymers'). Furthermore, compared with PEKK polymers synthesized using an electrophilic synthesis routes, the PEKK polymers described herein and significantly lower halogen content. The synthesis routes includes a first heating of a first monomer blend in a reaction mixture, a subsequent first addition of a second monomer blend to the reaction mixture, and a second heating of the reaction mixture subsequent to the first addition.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 40.
    摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 35.
    摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 1.
    摘要:Kwiecień, H., Science of Synthesis Knowledge Updates, (2018) 3, 73.
    参考文献:10.1007/s10895-021-02872-4
    摘要:Wang Z, Song Q, Zhu L, Zhao C, Ma H. Synthesis, Characterization of NR@SiO2/PNIPAm-co-Ppa Composite Nanogel and Study On Its Application in Photodynamic Therapy. Journal of Fluorescence. 2022 Jan 29;32(2):771–82. doi: 10.1007/s10895-021-02872-4.
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