CAS: 144-19-4; 2,2,4-Trimethyl-1,3-Pentanediol

该化合物是一种高纯度二醇化合物,其特点是其分支分子结构,有助于极好的溶解性和低挥发性.它是聚酯,增塑剂和涂层合成的多用途中间体,其独特结构可增强水解稳定性和与疏水系统兼容性.TMD还因其耐受紫外线照射下的黄黄和降解,使其适合需要长期耐久的用途而受到重视.其双功能氢氧基组可控制聚合物配方的交叉连接,改善机械特性.该化合物的低湿度吸收能进一步保证湿润环境中的性能稳定性. TMPD通常用于粘合剂,油墨和特殊树脂中.

结构式图片

相似化合物

25265-77-4 35763-45-2 109387-36-2

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

2,2,4,4-四甲基-1,3-环丁二醇 2,2,4,4-Tetramethyl-1,3-Cyclobutanediol 3010-96-6
3-羟基-2,2,4-三甲基-戊酸 2,2,4-Trimethyl-3-Hydroxyvaleric Acid 35763-45-2

合成工艺路线路线简述

    7-Isopropyl-8,8-Dimethyl-8,9-Dihydro-7H-6,10-Dioxabenzocyclononene-5,11-Dione 以48%的收率获得2,2,4-三甲基-1,3-戊二醇
    参考文献:Monoesters And Macrocyclic Diester Of Phthalic Acid And Synthesis Thereof
    标题:Monoesters And Macrocyclic Diester Of Phthalic Acid And Synthesis Thereof
    摘要:本文介绍了2,2,4-三甲基-1,3-戊二醇和邻苯二甲酸或其衍生物的单酯和大环二酯.同时还介绍了制备这些单酯和二酯的方法.本发明的单酯和二酯在制备清晰,硬度高的热塑性聚合物方面具有应用价值.这些热塑性聚合物在涂料,油墨,增强塑料和包装材料中有用.

    海关参考信息

    专利信息


    专利号:US-2024368099-A1
    优先权日:2022-01-18
    标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
    发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
    权利人:HENKEL AG & CO KGAA
    摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

    专利号:US-9611352-B2
    优先权日:2014-09-17
    标 题:Synthesis and molecular weight control of aliphatic polyester diols
    发明人:NARINE SURESH; LI SHAOJUN; JOSE JESMY; SHETRANJIWALLA SHEGUFTA; BOUZIDI LAZIZ
    权利人:UNIV TRENT
    摘要:The synthesis of certain polyester diols (PEDs) is disclosed. This application also discloses the purification and polymerization kinetics of lipid based PEDs. Molecular weight and distribution controls were achieved by initial and induced stoichiometric imbalance and optimization of the purification protocol. Thermal degradation and thermal transition behavior of the PEDs were also investigated by TGA and DSC.

    专利号:US-11292873-B2
    优先权日:2013-11-05
    标 题 :Etheramines prepared from a mixture of two or more multifunctional alcohol initiators, and their use as curatives or intermediates for polymer synthesis
    发明人:ZHOU HUI; LEWIS DAVID C; KLEIN HOWARD P; RENKEN TERRY L; PATTERSON LEAH
    权利人:HUNTSMAN PETROCHEMICAL LLC
    摘要:Implementations described herein generally relate to etheramine mixtures formed from a mixture of two or more multifunctional alcohol initiators, processes for the etheramine mixtures production, and its use as a curing agent or as a raw material in the synthesis of polymers. In one implementation, the process comprises mixing a polyol initiator having a melting point greater than a processing temperature and a polyol initiator having a melting point less than the processing temperature to form a polyol initiator mixture having a melting point less than the processing temperature, charging the polyol initiator mixture to an alkoxylation reaction zone, contacting the polyol initiator mixture with an alkylene oxide in the alkoxylation reaction zone to provide a mixture of alkoxylated precursor polyols and charging the mixture of alkoxylated precursor polyols to a reductive amination zone and reductively aminating the mixture of alkoxylated precursor polyols to form the etheramine mixture.

    专利号:US-2024254395-A1
    优先权日:2021-06-02
    标题 :Pyrolysis of polyurethane compound-containing material in order to recover raw materials
    发明人:EIDEN STEFANIE; BELLINGHAUSEN RAINER; WOLF AUREL; HAHN CHRISTIAN; LODDENKEMPER TIM; JENDRZOK CAROLA
    权利人:COVESTRO DEUTSCHLAND AG
    摘要:The invention relates to a process according to claim 1 and pyrolysis devices used therein for the pyrolysis of pyrolysis stock comprising polyurethane-containing material, allowing carrying out pyrolysis on an industrial scale. According to the invention, even with higher amounts of pyrolysis stock an amount of pyrolysis product is obtained that contains cleavage products which can be reused for the synthesis of polyurethane-containing material.

    专利号:US-2024352216-A1
    优先权日:2021-08-20
    标 题:Pyrolysis of a polymeric polyurethane compound in order to recover raw materials
    发明人:EIDEN STEFANIE; BELLINGHAUSEN RAINER; WOLF AUREL; ALBACH ROLF
    权利人:COVESTRO DEUTSCHLAND AG
    摘要:The invention relates to a method according to claim 1 for the commercial implementation of a pyrolysis, and to pyrolysis devices for the pyrolysis of pyrolysis stock used in this method. The pyrolysis stock contains a polymeric compound having at least one structural polyurethane unit of the formula (I), wherein Q is a hydrocarbon group with 2 to 8 carbon atoms, preferably 3 to 8 carbon atoms, and n represents a number from 2 to 4, most preferably 2, and -* represents a covalent bond to the polymer backbone. The method and the pyrolysis device according to the invention allow, even with higher compounds of pyrolysis stock an amount of pyrolysis product to be obtained that contains cleavage products which can be reused for the synthesis of polyurethane-containing material.

    专利号:US-5510516-A
    优先权日:1990-07-06
    标 题 :Process for selective epoxidation of unsaturated (meth)acrylates, new functional (meth)acrylates obtained and their application to the synthesis of new polymers
    发明人:CAUBERE PAUL; FORT YVES; ORTAR AGNES
    权利人:ATOCHEM
    摘要:An unsaturated (meth) acrylic compound of formula: (I) (X=O, S, NH, NR3 (R3=C1-12-alkyl) or O-(CH2)n (where n=1-16 approximately); R2=C2-20 straight-chain or branched alkyl, monocyclic or polycyclic cycloalkyl or heterocycloalkyl, or alkylaryl hydrocarbon chain, comprising an olefinic double bond in the chain, or at the end of the chain in the case of alkyl or alkylaryl, or an exocyclic or endocyclic olefinic double bond in the case of monocyclic or polycyclic cycloalkyl or heterocycloalkyl; and R1=H or C1-5-alkyl), is reacted at 10 DEG -60 DEG C. with at least one oxidising compound (hydrogen peroxide) in the presence of at least one catalyst (alkali metal molybdates and tungstates) and in the presence of at least one phase transfer agent and when R2=polycyclic cycloalkyl or hetercycloalkyl, an organic peracid or hydrogen peroxide in the presence of at least one heteropolyacid. To open the epoxide function, the epoxide obtained is reacted with a compound chosen from strong inorganic acids, boron trifluoride etherate complexes, acid salts in the presence of the corresponding acid, halides of trialkylsilanes or trialkoxysilanes, and ketones in the presence of cationic resins.
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    合成参考文献


    摘要:Sasano, Y.; Iwabuchi, Y., Science of Synthesis: Special Topics, (2022) 1, 329.
    摘要:Kodak Company Reports., 21MAY1971
    摘要:Shah JJ, Heyerdahl; National Ambient Volatile Organic Compounds (VOCs) Database Update. USEPA/600/3-88-010(a). Research Triangle Park, NC: USEPA p. 60 (1988)
    摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
    摘要:Kirk-Othmer Encyclopedia of Chemical Technology. 3rd ed., Volumes 1-26. New York, NY: John Wiley and Sons, 1978-1984., p. V11 963 (1990)
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