CAS: 13183-70-5; 1,4-Bis(Trimethylsilyl)Benzene

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1,4-Bis(Trimethylstannyl)Benzene置于正丁基锂体系中,用 乙醚,正己烷,正戊烷 用作溶剂,化学反应 48.0H,反应生成1,4-二(三甲基硅烷基)苯
参考文献:新型有机硼烷路易斯酸通过选择性硼-锡交换过程对卤化硼亲电引发的空间约束
标题:新型有机硼烷路易斯酸通过选择性硼-锡交换过程对卤化硼亲电引发的空间约束
摘要:为了制备新的单齿和双齿有机硼路易斯酸,通过卤化硼和合适的有机锡烷之间的硼-锡交换来合成所需有机硼烷的范围和局限性已被详细研究.以下有机锡衍生物已从相应的 Rmgbr 或 Rli 试剂和 Mensncl4-n 或从使用有机卤化物,Me3Sncl 和镁金属的 Barbier 程序中获得:1,2-双(三甲基锡基)乙炔,O-,M-,和对-双(三甲基-甲锡烷基)苯,α,O-双(三甲基甲锡烷基)甲苯,α,α-双(三甲基锡烷基)-邻二甲苯和2,2-二甲基-2-锡丹.1,2-双(三甲基甲锡烷基)乙炔和异构双(三甲基甲锡烷基)苯与 Et2Bbr 的单独相互作用产生相应的双(二乙基硼基)衍生物.相比之下,使用 Et2Bcl 时,α,O-双(三甲基甲锡烷基)甲苯仅生成邻二乙基硼基-α-三甲基甲锡基甲苯,而使用 Bcl3 时仅反应生成α,α'-双(三甲基甲锡烷基)-邻二甲苯,-双-(氯二甲基甲锡烷基)-O-二甲苯.此外,在邻双(三甲基锡基)苯和
Doi:10.1002/(Sici)1099-0682(199806)1998:6<761::Aid-Ejic761>3.0.Co;2-1

专利信息

专利号:US-9388345-B2
优先权日:2012-07-03
标题:Hydrocarbon synthesis methods, apparatus, and systems
发明人：MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G
权利人:SARTEC CORP
摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.