CAS: 814-68-6; Acrylyl Chloride

• 英文名称Acrylyl Chloride
• 中文名称丙烯酰氯
• IUPAC名称prop-2-enoyl chloride
• 其它别名2-Propenoyl chloride
• CAS编号814-68-6
• MFCD编号:MFCD00000731
• EINECS号:212-399-0
• FDA UNII编号:8K23O56TG5
• 分子式:C3H3ClO
• 分子量:90.51
• 产品CID: 1808056
• 产品分类有机原料 → 烃类化合物及其衍生物 → 烃类卤化物

• 相似结构搜索
• 产品信息参考
• InChIKey: HFBMWMNUJJDEQZ-UHFFFAOYSA-N
• InChI=1S/C3H3ClO/c1-2-3(4)5/h2H,1H2…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数1.0

物理性质

• 熔点72-76 °C
• 沸点75.5±0.0 °C at 760 mmHg
• 闪点16.1±0.0 °C
• 密度1.1±0.1 g/cm3
• PSA:17.07
• LogP:1.06
• 折射率1.417
• 蒸汽压104.8±0.1 mmHg at 25°C
• 溶解性可溶于氯仿,甲醇(微量)
• 敏感性1.常温常压下稳定，避免水分、光、碱、活性金属、热、紫外线辐射、自由基引发剂接触。2.高度易燃，有腐蚀性，能引起烧伤，对眼睛及呼吸系统有刺激性，大量使用应穿适当的防护服，戴手套和防护镜。
• 外观形态透明液体
• 储存条件储存在干爽的惰性气体下，保持容器密封保存、阴凉、干燥环境的地方。
• 产品应用用作有机合成中间体.
• 性质描述无色液体.沸点75-76°C,相对密度1.1136(20/4°C),折光率1.4343.能与氯仿混溶,在水及乙醇中分解.易挥发.

MSDS等安全信息

• GHS象形图
• GHS符号GHS02 & GHS06 & GHS05;
  注释: Flame & Skull and crossbones & Corrosion
• 危险类别易燃液体 类别2
  急性毒性 类别1(吸入)
  急性毒性 类别4(经口)
  皮肤腐蚀 类别1B
  急性毒性 类别4(经皮)
  水生急性毒性 类别1
  金属腐蚀物 类别1
  皮肤腐蚀 类别1A
  严重眼损伤 类别1
• 警示词Danger(危险)
• 危险描述H225 |高度易燃液体和蒸气.
  H330 |吸入致命.
  H302 |吞咽有害.
  H314 |造成严重皮肤灼伤和眼损伤.
  H312 |皮肤接触有害.
  H400 |对水生生物毒性极大.
  H290 |可能对金属造成腐蚀.
  H318 |造成严重眼损伤.
• 防范说明P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338
• UN编号2924.0
• 危险品标志C:Corrosive
• 安全声明S16-S26-S28-S36/37/39-S45-S7/9
• 危险类别码R34,R11
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 26189-59-3 = 814-68-6 [标题:Reaction Conditions
  标题:Synthesis Of Acyl Halides Under Very Mild Conditions
  作者:Devos,Alain; Et Al
  参考文献:Journal Of The Chemical Society 日期:1979 卷标:(24) 页码:1180-1]
  
  625-36-5 = 814-68-6 [标题:Reaction Conditions
  标题:β-Propiolactone. Viii. Reactions With Organic And Inorganic Acids,Acid Chlorides,And Anhydrides
  作者:Gresham,T. L.; Et Al
  参考文献:Journal Of The American Chemical Society 日期:1950 卷标:72 页码:72-4]
  
  1520-21-4 + 10544-50-0 + 814-68-6 = 814-68-6
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Tetrahydrofuran,Water; Rt -> 0 °C; 2 H,0 °C
  标题:Functionalized Chalcogenide Hybrid Inorganic/organic Polymers (Chips) Via Inverse Vulcanization Of Elemental Sulfur And Vinylanilines
  作者:Zhang,Yueyan; Et Al
  参考文献:Polymer Chemistry 日期:2018 卷标:9(17) 页码:2290-2294]
  
  814-68-6 + 2680-03-7 = 814-68-6
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Diethyl Ether,Water; 1 H,4 °C; 2 H,Rt
  标题:Thermosensitive Phase-Separation Behavior Of Poly(Acrylic Acid)-Graft-Poly(N,N-Dimethylacrylamide) Aqueous Solution
  作者:Shibanuma,Tetsuo; Et Al
  参考文献:Macromolecules 日期:2000 卷标:33(2) 页码:444-450]
  
  = 814-68-6 [标题:Reaction Conditions
  标题:On The Hydrozirconation Of 4,4-Dimethyl-2-Oxazolines Of Some α,β-,β,γ- And γ,δ-Unsaturated Fatty Acids
  作者:Alvhaell,J.; Et Al
  参考文献:Chemica Scripta 日期:1984 卷标:24(4-5) 页码:170-7]
  
  107-94-8 = 814-68-6 [标题:Reaction Conditions
  标题:Anionotropic Rearrangement In The Reaction Of β-Chloropropionic Acid With Phosphoric Anhydride
  作者:Kostyanovskii,R. G.
  参考文献:Zhurnal Obshchei Khimii 日期:1961 卷标:31]
  
  814-68-6 + 13822-56-5 = 814-68-6
  反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; 1 H,5 °C; 4 H,0 °C
  标题:Phosphinite-Functionalized Silica And Hexagonal Mesoporous Silica Containing Palladium Nanoparticles In Heck Coupling Reaction: Synthesis,Characterization,And Catalytic Activity
  作者:Farjadian,Fatemeh; Et Al
  参考文献:Rsc Advances 日期:2015 卷标:5(97) 页码:79976-79987]
  
  60180-60-1 = 814-68-6 [标题:Reaction Conditions
  标题:Synthesis Of Acyl Halides Under Very Mild Conditions
  作者:Devos,Alain; Et Al
  参考文献:Journal Of The Chemical Society 日期:1979 卷标:(24) 页码:1180-1]
  
  = 814-68-6
  反应条件:1.1 Reagents: Benzoyl Chloride,Triethylamine,Hydroquinone
  标题:Facile Hydrophobic Modification Of Hybrid Poly(Urethane-Urea)Methacrylate Aqueous Dispersions And Films Through Blending With Novel Waterborne Fluorinated Acrylic Copolymers
  作者:Yang,Chengcheng; Et Al
  参考文献:Colloid And Polymer Science 日期:2012 卷标:290(6) 页码:491-506]
  
  814-68-6 + 108-30-5 = 814-68-6
  反应条件:1.1 Solvents: Tetrahydrofuran; 6 H,60 °C; 60 °C -> 0 °C1.2 Reagents: Triethylamine; 0 °C; 2 H,> 0 °C; 0 °C -> Rt; 48 H,Rt
  标题:Preparation And Properties Of Photopolymerized Hybrid Composites With Covalently Attached Magnetite Nanoparticles
  作者:Melinte,Violeta; Et Al
  参考文献:Chemical Engineering Journal (Amsterdam 日期:2015 卷标:259 页码:542-551]
  
  352426-89-2 = 814-68-6
  反应条件:1.1 Reagents: Sodium Methoxide Solvents: Methanol; Rt1.2 Reagents: Dowex; Neutralized,Rt
  标题:Novel Multivalent Mannose Compounds And Their Inhibition Of The Adhesion Of Type 1 Fimbriated Uropathogenic E. Coli
  作者:Appeldoorn,Chantal C. M.; Et Al
  参考文献:Tetrahedron: Asymmetry 日期:2005 卷标:16(2) 页码:361-372]
  
  = 814-68-6
  反应条件:1.1 Reagents: Zirconium Chloride (Zrcl4)
  标题:Preparation Of Acryloyl Chloride From Acrylic Acid
  参考文献:European Patent Organization]
  
  98-88-4 = 814-68-6
  反应条件:1.1 Catalysts: Hydroquinone
  标题:Reactivity Ratios Of Monomers Cholesteryl Acrylate And 1-Hexene In Liquid Crystalline Copolymers: Their Synthesis And Characterization
  作者:Hoque,Samiul; Et Al
  参考文献:Journal Of Polymer Materials 日期:2011 卷标:28(1) 页码:49-58]
  
  98-88-4 = 814-68-6 [标题:Reaction Conditions
  标题:Synthesis And Structure Of 4-Benzoyl-3-Hydroxyphenyl Acrylate
  作者:Sosnina,V. V.; Et Al
  参考文献:Izvestiya Vysshikh Uchebnykh Zavedenii 日期:1994 卷标:37(2) 页码:67-72]
  
  98-88-4 = 814-68-6
  反应条件:1.1 70 - 72 °C
  标题:Total Synthesis Of (+)-Trans-Trikentrin A
  作者:Tebeka,Iris R. M.; Et Al
  参考文献:Chemistry - A European Journal 日期:2012 卷标:18(52) 页码:16890-16901]
  
  = 814-68-6
  反应条件:1.1 Reagents: Tert-Butyl Hypochlorite
  标题:Positive Halogen Compounds. Xiii. Tert-Butyl Hypochlorite Chlorination Of Ethers,Aldehydes,And Other Molecules With Polar Substituents
  作者:Walling,Cheves; Et Al
  参考文献:Journal Of The American Chemical Society 日期:1967 卷标:89(6) 页码:1515-19]
  
  = 814-68-6
  反应条件:1.1 Catalysts: Tert-Butyl Hypochlorite
  标题:T-Butyl Hypochlorite
  作者:Simpkins,Nigel S.; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  = 814-68-6
  反应条件:1.1 Reagents: Triphenylphosphine Solvents: Tetrahydrofuran,Water; 45 °C
  标题:Asymmetric Synthesis Of (-)-9-Epi-Metazocine
  作者:Chen,Qiang; Et Al
  参考文献:Synlett 日期:2012 卷标:23(9) 页码:1349-1352]
  
  24938-60-1 + 72092-61-6 = 814-68-6
  反应条件:1.1 Catalysts: Irgacure 369,Bis(2,4,6-Trimethylbenzoyl)Phenylphosphine Oxide Solvents: Dimethylacetamide; 24 H,Rt; 5 - 20 Min
  标题:Robust Thermostable Polymer Composition Based On Poly[n,N'-(1,3-Phenylene)Isophthalamide] And 3,3-Bis(4-Acrylamidophenyl)Phthalide For Laser 3D Printing
  作者:Kholkhoev,Bato Ch.; Et Al
  参考文献:Mendeleev Communications 日期:2019 卷标:29(2) 页码:223-225]
  
  58160-99-9 + 814-68-6 = 814-68-6
  反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; 1 H,5 °C; 4 H,0 °C
  标题:Phosphinite-Functionalized Silica And Hexagonal Mesoporous Silica Containing Palladium Nanoparticles In Heck Coupling Reaction: Synthesis,Characterization,And Catalytic Activity
  作者:Farjadian,Fatemeh; Et Al
  参考文献:Rsc Advances 日期:2015 卷标:5(97) 页码:79976-79987

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2912110000-甲醛
  2912120000-乙醛
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

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• ➥ 防范代码详解
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