CAS: 2155-96-6; Diphenyl(Vinyl)Phosphine

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CAS号52773-69-0 (2-diphenylphos...

乙烯基氯化镁,二苯基氯化膦 反应生成乙烯基二苯基膦
参考文献:含有间胍基苯基部分的水溶性阳离子膦配体.Heck型反应的合成及应用.
标题:含有间胍基苯基部分的水溶性阳离子膦配体.Heck型反应的合成及应用.
摘要:包含间胍基苯基取代基的阳离子膦配体{ph(3-N)p [c(6)h(4)-M-Nhc(nh(2))(nme(2))](n)}(n +) Ncl(-)(n = 1-3)(17A-C)是通过在酸性介质中将二甲基氰胺加到叔(间氨基苯基)膦的氨基上而获得的.叔(间氨基苯基)膦ph(3-N)p(c(6)h(4)-M-Nh(2))(n)(4A-C)通过(3-[n,N-双(三甲基甲硅烷基)氨基]苯基)氯化镁与氯膦ph(3-N)pcl(n),然后用甲醇对双(三甲基甲硅烷基)氨基进行脱保护.使用与上述类似的保护基合成方法,也可以制备仲(间氨基苯基)膦ph(h)pc(6)h(4)-M-Nh(2)(7).它可以用作合成带有间氨基苯基取代基的手性二齿膦配体(11,14和15)的基础.胍鎓膦17B和17C易溶于水.钯催化水相中17B和17C,芳基烷基胍鎓膦18和19和tppts(p(c(6)h(4)-M-So(
Doi:10.1021/jo961140N

专利信息

专利号:US-4895922-A
优先权日:1988-05-05
标 题 :Low temperature synthesis of polyesteramides
发明人：OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention disclosed a process for the synthesis of polyesteramides. By utilizing the phosphorus containing catalyst systems of the present invention, such polyesteramides can be synthesized at relatively low temperatures. The present invention specifically discloses a process for the synthesis of a polyesteramide which comprises polymerizing at least one diamine, at least one diol, and at least one dicarboxylic acid in the presence of (1) at least one acid acceptor; (2) at least one halogenated organic compound; and (3) at least one phosphorus containing compound selected from the group consisting of (a) triphenylphosphine, (b) triphenylphosphine oxide, (c) triphenylphosphine sulfide, (d) polymeric agents having pendant diphenylphosphine groups, (e) silicon-phosphorus compositions which contain at least one divalent oxygen atom which is bonded directly to a tetravalent silicon atom and a trivalent or pentavalent phosphorus atom; (f) compounds with the structural formula (C 6 H 5 ) 3 P=N-R, wherein R is a hydrogen atom or an alkyl group containing from 1 to 10 carbon atoms; and (g) compounds with the structural formula (C 6 H 5 )PR 1 R 2 wherein R 1 and R 2 can be the same or different, wherein R 1 is selected from the group consisting of alkyl groups containing from 1 to 10 carbon atoms and phenyl groups, and wherein R 2 is an alkyl group containing from 1 to 10 carbon atoms.

专利号:US-4794199-A
优先权日:1984-07-05
标题:Process for synthesis of primary amines from olefins, syngas and ammonia
发明人：LIN JIANG-JEN; KNIFTON JOHN F
权利人:TEXACO INC
摘要:This invention concerns the synthesis of primary amines from olefins, synthesis gas and ammonia via an amination process in the presence of a cobalt catalyst, an ether solvent and a tertiary group VB donor ligand.

专利号:US-4923839-A
优先权日:1987-02-05
标题:Low temperature synthesis of condensation polymers
发明人：OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-11370736-B2
优先权日:2019-04-01
标 题:Synthesis of fluoro hemiacetals via transition metal-catalyzed fluoro ester and carboxamide hydrogenation
发明人：DUB PAVEL A; BATRICE RAMI J; GORDON JOHN C
权利人:TRIAD NAT SECURITY LLC
摘要:This application is directed to use of transition metal-ligand complexes to hydrogenate fluorinated esters and carboxamides into fluorinated hemiacetals. Methods for synthesis of certain ligands are also provided.

专利号:US-4843053-A
优先权日:1987-02-05
标 题 :Low temperature synthesis of condensation polymers
发明人：OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4996178-A
优先权日:1987-02-05
标题 :Low temperature synthesis of condensation polymers
发明人：OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.