CAS: 191-26-4; Naphtho[7,8,1,2,3-Nopqr]Tetraphene

该化合物是一种多环芳烃(PAH),由6个装有引信的苯环组成,形成独特的角形结构,因其高热稳定性,光物理特性和有机电子学的潜在应用,如有机发光二极管(OLEDs)和半导体,受到重视.其扩展的共聚系统能够高效电荷运输,使之适合光电子装置.还研究过苯衍生物的发光特性和染料或感应器的使用.该化合物的硬平板结构有助于其在高温环境中的坚固性.由于其合成的多功能,它成为研究和工业应用中先进材料的建筑块.

结构式图片

物理性质

MSDS等安全信息

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CAS号641-13-4 蒽缔蒽酮 | CAS号72391-96-9 1,1'-binaphthyl... | CAS号10034-85-2 氢碘酸 | CAS号872294-43-4 3,9-dihydroxy-d... | CAS号31927-64-7 6-Methylnaphtho... | CAS号63040-55-1 Dibenzo[def,mno... | CAS号63040-58-4 6-Methyldibenzo... | CAS号641-13-4 蒽缔蒽酮 | CAS号41217-05-4 6,12-Dimethylan...

合成工艺路线路线简述

    📜蒽缔蒽酮置于锌体系中,用39%的收率获得蒽嵌蒽
    参考文献:不含海湾区的六环芳烃二苯并[def]亚甲基(蒽)的微粒体诱变代谢物.
    标题:不含海湾区的六环芳烃二苯并[def]亚甲基(蒽)的微粒体诱变代谢物.
    摘要:人们认为,在多环芳烃海湾区域内代谢形成的二氢二醇环氧化物是造成这些环境污染物遗传毒性的原因.六环芳烃二苯并[def,Mnochrysene](蒽)虽然缺乏此结构特征,但在鼠伤寒沙门氏菌的组氨酸依赖性菌株ta97,Ta98,Ta100和ta104中表现出相当大的致突变性.经aroclor 1254处理的sprague-Dawley大鼠肝线粒体代谢活化后,代谢激活后的-40 His(+)回复菌落/ Nmol.诱变作用占苯并[a] Re在以下条件下测定的值的44-84%.相同的条件.用未经处理的动物的细胞部分获得的ta100菌株中蒽蒽的比致突变性为6 His(+)回复菌落/ Nmol,苯巴比妥处理后增加2.7倍,3-甲基胆碱处理后增加4.5倍.为了阐明导致遗传毒性代谢物的代谢途径,研究了蒽蒽的微粒体生物转化.结合色谱,光谱和生化方法,可以鉴定反式-4,5-二氢二醇,4,5-氧化物,4,5-,1,6-,3
    Doi:10.1021/tx010131T

    海关参考信息

    专利信息


    专利号:US-8288497-B2
    优先权日:2008-02-27
    标 题 :Synthesis of poly-(P-aryleneethynylene)s in neat water under aerobic conditions
    发明人：KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J
    权利人:KANG YOUN K; DERIA PRAVAS; THERIEN MICHAEL J; UNIV PENNSYLVANIA
    摘要:Provided are ethyne synthons comprising boron and related methods. Also provided are related water-soluble arylethynylene polymers capable of being synthesized in neat water under aerobic conditions.

    专利号:US-3965049-A
    优先权日:1972-10-24
    标 题 :One-step synthesis of aromatic organic diselenides
    发明人：GRUSHKIN BERNARD; SALZMAN MICHAEL N
    权利人:XEROX CORP
    摘要:Disclosed is a novel method for the preparation of aromatic organic diselenide compounds. The method involves reacting an alkali metal diselenide with certain halogenated aromatic compounds in dimethylformamide to form the corresponding aromatic diselenide. The use of dimethylformamide enables one to prepare certain aromatic diselenide compounds containing two replaceable halogen atoms in a one-step process.

    专利号:US-2009326150-A1
    优先权日:2008-02-27
    标题:Synthesis of poly-(p-aryleneethynylene)s in neat water under aerobic condit

    专利号:US-2011257356-A1
    优先权日:2008-02-27
    标题:Synthesis of Poly-(P-Aryleneethynylene)s in Neat Water Under Aerobic Conditions

    专利号:CN-105473224-A
    优先权日:2013-07-31
    标 题:Catalysts and methods for the production of olefins from synthesis gas

    专利号:CN-103509032-B
    优先权日:2013-08-06
    标 题:Batch Green Synthesis Method of Dioxaanthanthrene Oxygen-Containing Condensed Ring Compounds

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    合成参考文献


    摘要:T. Handa and M. Kobayashi. Yoki Gosei Kagaku Kyokai Shi 13, 580 (1955); 14, 337, 550 (1956); CA 51, 8439d.
    摘要:A10: Santodonato J, Howard P, Basu D: Health and ecological assessment of polynuclear aromatic hydrocarbons. J Environ Pathol Toxicol. 1981 Sep;5(1):1-364.
    参考文献:10.1007/s10653-011-9392-4
    摘要:Kuo CY, Chen HC, Cheng FC, Huang LR, Chien PS, Wang JY. Polycyclic aromatic hydrocarbons in household dust near diesel transport routes. Environ Geochem Health. 2012 Feb;34(1):77–87. doi: 10.1007/s10653-011-9392-4.
    参考文献:10.1007/bf00184672
    摘要:Scherer G, Conze C, Tricker AR, Adlkofer F. Uptake of tobacco smoke constituents on exposure to environmental tobacco smoke (ETS). Journal of Molecular Medicine. 1992 Mar 01;70(3-4):352–67. doi: 10.1007/bf00184672.
    参考文献:10.1021/ac9025994
    摘要:Benhabib M, Chiesl TN, Stockton AM, Scherer JR, Mathies RA. Multichannel capillary electrophoresis microdevice and instrumentation for in situ planetary analysis of organic molecules and biomarkers. Anal Chem. 2010 Mar 15;82(6):2372–9. doi: 10.1021/ac9025994.
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