CAS: 16644-98-7; (E)-1-Iodohex-1-Ene

该化合物是一种有机化合物,其结构特征是线性烷,在第一和第二碳原子之间有双环,与第一个碳原子有双环,碘原子与第一个碳相连.该化合物属于卤代醇类,由于存在卤代物,已知其具有反应性.1E)的指定表明双重结合的配置,具体而言,双重结合物的两侧的较高优先替代物位于对面,使其成为反向异构体.1-Hexene,1-i-io-通常在室内温度下无色,在浅黄色液体中无色,在有机溶剂中可溶解.它可以参与各种化学反应,包括核分裂替代和添加反应,使其在有机合成和工业应用中有用.在处理这一化合物时,应当采取安全防范措施,因为其因具有再活动性和碘的存在而可能对健康造成危害.

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(Z)-hex-1-enyl(trimethyl)silane (E)-1-bromohex-1-ene (E)-1-hexenyldihydroxyborane 2-Iodothiophene (E)-°Ct-3-en-1-yne (E)-4-nonen-1-yl bromide (E)-5-Decenylbromid ((E)-N-°Ct-3-enyl)-benzamide

合成工艺路线路线简述

    📜1-己炔置于碘体系中,化学反应生成反-1-碘己烯
    参考文献:Stereoselective Synthesis Of Some Isomers Of Dodecadien-1-Ol: Compounds Related To The Pine Moth Sex Pheromone.
    标题:Stereoselective Synthesis Of Some Isomers Of Dodecadien-1-Ol: Compounds Related To The Pine Moth Sex Pheromone.
    摘要:过去曾提出5,7-十二碳二烯-1-醇的4种异构体为松树蚕的性信息素.这些异构体是通过对1-己炔和5-己炔-1-醇的四氢吡喃醚进行立体选择性合成得到的.(5Z,7Z)异构体是通过chodkiewic Cadiot反应和随后的硼氢化反应合成的,而其他三种异构体则是通过包括使用二茂锆氢化物[schwarz试剂(C5H5)2Zn(H)Cl]调控区域选择性偶联反应的新颖合成方法获得的.5,8-和5,9-十二碳二烯-1-醇也通过类似方法合成,以便与内源性性信息素的特性进行比较.
    Doi:10.1271/bbb1961.46.717

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    专利信息


    专利号:US-2021237040-A1
    优先权日:2018-06-26
    标题:Metal-iodide catalytic system for direct etherification from aldehydes and/or ketones
    发明人：WU DAN; ORDOMSKY VITALY; HERNANDEZ ENCISO WILLINTON YESID; STREIFF STÉPHANE
    权利人:RHODIA OPERATIONS; CENTRE NAT RECH SCIENT; UNIV DE LILE; CENTRALE LILLE INST
    摘要:A process for etherification of aldehydes and/or ketones in the presence of a catalyst and an iodine source. In particular, a process for the synthesis of an ether compound, comprising reacting an aldehyde and/or a ketone with an alcohol, in the presence of (i) a metal/support heterogeneous catalyst and an iodine source, or (ii) a metal-iodine catalyst, in a reactor, whereby the ether compound is obtained. A catalytic system comprising a metal/support heterogeneous catalyst and an iodine source, and a process for its preparation.

    专利号:PL-238522-B1
    优先权日:2017-04-07
    标 题:Method for synthesis of (Z5,E7)-dodecadien-1-ol, as a sex pheromone of the pine tree pine lappet moth (Dendrolimus pini) pest

    专利号:CN-1423629-A
    优先权日:1999-11-18
    标题:Metathesis synthesis of pheromones or components thereof

    专利号:WO-2016176560-A1
    优先权日:2015-04-30
    标 题:Chromium-mediated coupling and application to the synthesis of halichondrins

    专利号:CN-100528829-C
    优先权日:1999-11-18
    标 题:Metathesis synthesis of pheromones or their components

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    合成参考文献


    摘要:Ito, S.; Morita, N., Science of Synthesis, (2010) 45, 454.
    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 271.
    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 256.
    摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 287.
    摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 47, 472.
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