CAS: 94-60-0; Dimethyl Cyclohexane-1,4-Dicarboxylate

该化合物其结构特征为结构结构,由两种箱状甲状腺组组成,在环乙烷环上与甲基组一起受精;该化合物一般没有颜色,可粉色,可粉色,可口味;可溶于乙醇和乙醚等有机溶剂,但因其对水的恐惧性六氯环己烷框架,在水中溶解性有限;二甲基甲型六氯环己烷箱主要用作有机合成的建筑块,特别是在生产各种聚合物和合成药物和农用化学物时,其再活性受可进行水分解,转化和其他化学转化的酯组的存在影响;安全数据表明,应谨慎处理,因为这可能会对皮肤和眼睛产生刺激;建议采取适当安全措施,包括使用个人防护设备,在与该化合物合作时采用.

英文名称Dimethyl Cyclohexane-1,4-Dicarboxylate
中文名称1,4-环己二甲酸二甲酯
IUPAC名称dimethyl cyclohexane-1,4-dicarboxylate
其它别名Dimethyl Cis-1,4-Cyclohexanedicarboxylate; Dimethylcyclohexane-1,4-Dicarboxylate; Trans-1,4-Cyclohexanedicarboxylic Acid, Dimethyl Ester; Rel-(1R,4R)-Dimethyl Cyclo
CAS编号94-60-0
MFCD编号:MFCD00001460
EINECS号:202-347-5
分子式:C10H16O4
分子量:200.23
产品CID: 1997672
产品分类有机原料→分子砌块→脂肪链类化合物

相似结构搜索
InChIKey: LNGAGQAGYITKCW-UHFFFAOYSA-N
InChI=1S/C10H16O4/c1-13-9(11)7-3-5-8(6-4-7)10(12)14-2/h7-8H,3-6H2,1-2H3…
计算化学: 氢键受体数4.0氢键供体数0.0可旋转键数4.0

相似化合物

3399-21-1 3399-22-2 105-08-8

MSDS等安全信息

GHS象形图
GHS符号GHS07;
注释: Exclamation mark
危险类别严重眼刺激类别2
水生慢性毒性类别3
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2A
警示词Warning(警告)
危险描述H319 |造成严重眼刺激.
H412 |对水生生物有害并具有长期持续影响.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
UN编号NONH for all modes of transport
危险品标志Xi
安全声明26-36-61-37
危险类别码36-52/53-38
WGK Germany1

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

合成目标产物 Dimethyl 1,4-Cyclohexanedicarboxylate 主要起始原料 Dimethyl Terephthalate
120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Ruthenium,Carbon Solvents: Tetrahydrofuran; 6 H,120 °C; 45 Bar
标题:Zinc(Ii) Acetate Catalyzed Depolymerization Of Poly(Ethylene Terephthalate)
作者:Hofmann,Melanie; Sundermeier,Jannis; Alberti,Christoph; Enthaler,Stephan
参考文献:Chemistryselect 日期:2020 卷标:5(32) 页码:10010-10014]

1076-97-7 = 94-60-0
反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; Overnight,Rt
标题:Structure-Activity Relationships Of Cycloalkylamide Derivatives As Inhibitors Of The Soluble Epoxide Hydrolase
作者:Kim,In-Hae; Park,Yong-Kyu; Hammock,Bruce D.; Nishi,Kosuke
参考文献:Journal Of Medicinal Chemistry 日期:2011 卷标:54(6) 页码:1752-1761]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Alumina,Ruthenium Solvents: Methanol; 1 H,5 Mpa,140 °C
标题:Preparation Of Dimethyl 1,4-Cyclohexanedicarboxylate
参考文献:China]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Lanthanum Sesquioxide; 3 Mpa,140 °C
标题:Hydrogenation Catalyst For Hydrogenation Of Benzene-Carboxylic Acid Alkyl Ester And Preparation Method Thereof
参考文献:China]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Ruthenium; 4.5 H,5 Mpa,150 °C
标题:Method Of Manufacturing Batch Hydrogenation Reduction Compounds
参考文献:Japan]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Platinum Solvents: Acetic Acid
标题:Electrolytic Synthesis Of The Dimethyl Ester Of [1,1'-Bicyclohexane]-4,4'-Dicarboxylic Acid From Trans-Hexahydroterephthalic Acid Monomethyl Ester
作者:Fichter,Fr.; Holbro,Theodor
参考文献:Helvetica Chimica Acta 日期:1938 卷标:21 页码:141-51]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Alumina,Ruthenium Solvents: Water; 4 H,300 °C
标题:Selective Hydrogenation Of Dimethyl Terephthalate On Ru-Based Catalysts In The Fixed Bed Reactor
作者:Zhang,Jia; Zhou,Jiande; Shen,Weihua; Zhu,Zhiqing; Fang,Yunjin
参考文献:Shiyou Huagong 日期:2020 卷标:49(6) 页码:521-528]

1076-97-7 = 94-60-0
反应条件:1.1 Catalysts: Sulfuric Acid Solvents: Methanol; 5 H,75 °C
标题:Thermoreversible Gelation Of Poly(Urethane Acyl-Semicarbazides) Carrying Cycloaliphatic Moieties And Studies On Selective Adsorption Of Dyes From Wastewater
作者:Baddi,Sravan; Palanisamy,Aruna
参考文献:European Polymer Journal 日期:2018 卷标:99 页码:90-101]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen; 6 Mpa,140 °C
标题:Preparation Of 1,4-Cyclohexanedicarboxylic Acid Dimethyl Ester
参考文献:China]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Platinum; 10 H,5 Mpa,413 K
标题:Synthesis Of Gasoline And Jet Fuel Range Cycloalkanes And Aromatics From Poly(Ethylene Terephthalate) Waste
作者:Tang,Hao; Li,Ning; Li,Guangyi; Wang,Aiqin; Cong,Yu; Et Al
参考文献:Green Chemistry 日期:2019 卷标:21(10) 页码:2709-2719]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Alumina,Ruthenium Solvents: Ethyl Acetate; 20 H,700 - 800 Psi,120 °C
标题:Hydrogenation Process And Preparation Of A Highly Stable Catalyst For The Manufacture Of Dimethyl 1,4-Cyclohexanedicarboxylate From Dimethyl Terephthalate
参考文献:United States]

1076-97-7 = 94-60-0
反应条件:1.1 Reagents: Hydrochloric Acid,Thionyl Chloride Solvents: Methanol; Cooled; 1 H,Reflux
标题:Preparation Of Hydroxamic Acid Derivatives Useful In The Treatment Of Bacterial Infections
参考文献:World Intellectual Property Organization]

1257982-57-2 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Platinum; 250 °C
标题:Solvent-Driven Isomerization Of Cis,Cis-Muconic Acid For The Production Of Specialty And Performance-Advantaged Cyclic Biobased Monomers
作者:Carraher,Jack M.; Carter,Prerana; Rao,Radhika G.; Forrester,Michael J.; Pfennig,Toni; Et Al
参考文献:Green Chemistry 日期:2020 卷标:22(19) 页码:6444-6454]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Sodium Hydroxide,Sodium Borohydride Catalysts: Alumina,Palladium Alloy,Nonbase,Pd,Ru Solvents: Water; Ph 8,Rt; 20 Min1.2 6 H,8 Mpa,160 °C
标题:Low-Content Supported Ruthenium-Palladium Bimetal Hydrogenation Catalyst And Preparation Method Thereof
参考文献:China]

1076-97-7 = 94-60-0
反应条件:1.1 Reagents: Sulfuryl Chloride Solvents: Methanol; 0 °C; Overnight,Rt
标题:Preparation Of Substituted Diaminocarboxamide And Diaminocarbonitrile Pyrimidines As Jnk Pathway Inhibitors
参考文献:World Intellectual Property Organization]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Palladium,Ruthenium Solvents: Ethyl Acetate; 6 H,8 Mpa,180 °C
标题:Composition Regulation Of Bimetallic Rupd Catalysts Supported On Porous Alumina Spheres For Selective Hydrogenation
作者:Chen,Jiali; Liu,Xin; Zhang,Fazhi
参考文献:Chemical Engineering Journal (Amsterdam 日期:2015 卷标:259 页码:43-52]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen
标题:Dimethyl Cis- And Trans-1,4-Cyclohexanedicarboxylates
作者:Naumann,Hans Joachim; Schmidt,Harald
参考文献:Journal Fuer Praktische Chemie (Leipzig) 日期:1965 卷标:29(3-6) 页码:230-6]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Hydrogen Catalysts: Dibromo[1,2-Di(Methoxy-Ko)Ethane]Nickel; 100 Bar,Rt; 42 H,160 °C
标题:Metal Oxide-Supported Earth-Abundant Metal Catalysts For Highly Efficient Organic Transformations
参考文献:World Intellectual Property Organization]

120-61-6 = 94-60-0
反应条件:1.1 Reagents: Diisopropylethylamine Catalysts: Methylamine Hydrochloride,Iridium(1+),[4,4′-Bis(1,1-Dimethylethyl)-2,2′-Bipyridine-Kn1,Kn1′]Bis[3,5-Diflu... Solvents: Dimethylformamide; 15 - 18 H,25 °C
标题:Birch-Type Photoreduction Of Arenes And Heteroarenes By Sensitized Electron Transfer
作者:Chatterjee,Anamitra; Koenig,Burkhard
参考文献:Angewandte Chemie 日期:2019 卷标:58(40) 页码:14289-14294]

1119-43-3 = 94-60-0 + 22646-79-3 + 120-61-6
反应条件:1.1 Solvents: Diglyme; 24 H,1.79 Mpa,165 °C1.2 Catalysts: Palladium; Rt; Rt -> 169 °C; 8 H,169 °C
标题:Preparation Of Trans,Trans Muconic Acid And Trans,Trans Muconates
参考文献:United States

(E,E)-2,4-己二烯二酸二甲酯置于palladium On Activated Charcoal 氢气体系中,用二氯甲烷,间二甲苯作为反应溶剂,20.0~168.0 °C,1.79 Mpa 条件下,反应 48.0H,反应生成 1,4-环己烷二羧酸二甲酯
参考文献: Continuous Dehydrogenation Of 1,4-Carboxylate Substituted Cyclohexenes[fr] Déshydrogénation En Continu De Cyclohexènes Substitués Par 1,4-Carboxylate
标题: Continuous Dehydrogenation Of 1,4-Carboxylate Substituted Cyclohexenes[fr] Déshydrogénation En Continu De Cyclohexènes Substitués Par 1,4-Carboxylate
摘要:一种方法,包括将含有1和4位置的环己烯环的羧酸酯衍生物,以及可选的2位置,与一个或多个脱氢催化剂接触,可选地在一个或多个氧化剂的存在下,在连续流模式下在条件下,制备含有芳香环和1和4位置的羧酸酯衍生物,以及可选的2位置的化合物.该发明还涉及从可再生资源衍生的起始材料衍生的这种化合物.