CAS: 6423-43-4; Propane-1,2-Diyl Dinitrate
- 英文名称Propane-1,2-Diyl Dinitrate
- 中文名称1,2-丙二醇二硝酸酯
- IUPAC名称propane-1,2-diyl dinitrate
- 其它别名Propyleneglycol1,2-Dinitrate; Propyleneglycoldinitrate; Propylenenitrate; Propane-1,2-Diyl Dinitrate; Dipropyleneglycol1,2-Dinitrate; Dinitric Acid Propane-1,2-Diyl Ester; Propane-1,2-Diol Dinitrate; 1,2-Bis-(Nitryloxy)-Propane
- CAS编号6423-43-4
- MFCD编号:MFCD01698023
- EINECS号:229-180-0
- FDA UNII编号:4BY6T6Y8D1
- 分子式:C3H6N2O6分子量:166.09
- 产品CID: 1626484
- 产品分类有机原料 → 无机酸酯
物理性质
- 熔点18 °F (NIOSH, 2016)
- 沸点206.7 °C at 760 mmHg
- 闪点98.5 °C
- 密度1.423g/cm3
- PSA:110.1
- LogP:0.8379
- 折射率1.451
- 蒸汽压0.38 mm Hg @ 25 °C /Estimated/
- 溶解性In water, 3,262 mg/L @ 25 °C /Estimated/
- 敏感性PROPYLENE GLYCOL DINITRATE is explosive. Acts as a strong oxidizing agent. Heating may cause a violent combustion or explosion producing toxic fumes (nitrogen oxides). May also decompose explosively from shock, friction or from a build-up of electrostatic charge that sparks suddenly to ground. Can begin a vigorous reaction that culminates in an explosion if mixed with reducing agents including hydrides, sulfides, and nitrides and numerous ordinary combustible materials. Reacts violently with Al, BP, cyanides, esters, PN2H, P, NaCN, SnCl2, sodium hypophosphite, and thiocyanates. Reacts with acids and with alkalis, including ammonia and amines. Must be stored in a cool, ventilated place, away from acute fire hazards and easily oxidized materials.
- 外观形态红橙色或无色液体,具有刺激性气味
MSDS等安全信息
- 危险类别Excerpt from NIOSH Pocket Guide for Propylene glycol dinitrate: | Exposure Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact | Symptoms: Irritation eyes; conjunctivitis; methemoglobinemia; headache, impaired balance, visual disturbance; In Animals: liver, kidney damage | Target Organs: Eyes, central nervous system, blood, liver, kidneys (NIOSH, 2024)
- 警示词Danger
- 危险描述H302: Harmful if swallowed [Warning Acute toxicity, oral]
H370: Causes damage to organs [Danger Specific target organ toxicity, single exposure]
H371: May cause damage to organs [Warning Specific target organ toxicity, single exposure]
H372: Causes damage to organs through prolonged or repeated exposure [Danger Specific target organ toxicity, repeated exposure]
H373: May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure] - 防范说明P260, P264, P270, P301+P317, P308+P316, P319, P321, P330, P405, and P501
- 危险等级1.1A
- UN编号0473
- 危险类别码Listed in the ACGIH table: Examples of Industrial Chemicals for Which Methemoglobin Formation is NOT the Principal Cause of Toxicity; Headache is a common symptom in new employees, but tolerance develops after repeated exposures. Volunteers exposed at 0.5 ppm for 6 to 8 hours showed impaired performance (ataxia) similar to the effects in these same subjects at high blood alcohol concentrations. Male volunteers exposed to levels from 0.03-1.5 ppm over a range of time showed no significant hematological effects. No evidence of chronic neurological effects was found in a group of 87 workers at a torpedo manufacturing plant where PGDN peak air concentrations measured from not detectable to 0.22 ppm (90% below 0.1 ppm). [ACGIH] An eye irritant; Can induce methemoglobinemia; [ICSC]
上下游产品
CAS号75-56-9 环氧丙烷 | CAS号137514-23-9 N-nitropropylenimine | CAS号57-55-6 丙二醇 | CAS号187737-37-7 propene | CAS号75-55-8 2-甲基氮丙啶 | CAS号7697-37-2 硝酸 | CAS号601-75-2 乙基丙二酸 | CAS号110-94-1 戊二酸 | CAS号498-21-5 甲基丁二酸 | CAS号57-55-6 丙二醇合成工艺路线路线简述
📜2-甲基氮丙啶置于五氧化二氮体系中,用 二氯甲烷 作为反应溶剂,以18.5%的收率获得产物1,2-丙二醇二硝酸酯
参考文献:氮氧化物硝化,第4部分:某些氮丙啶和氮杂环丁烷与五氧化二氮反应后的意外行为
标题:氮氧化物硝化,第4部分:某些氮丙啶和氮杂环丁烷与五氧化二氮反应后的意外行为
摘要:在环氮上未取代的或带有n-酰基(n,N-二甲基氨基甲酰基或丙酰基)的七个氮丙啶和氮杂环丁烷在卤化溶剂中与n 2 O 5反应,结果如下:-氮丙啶的行为高度依赖在n-取代基上,分别得到二硝酸酯,硝酸硝胺或主要不具有特征的产物,而氮杂环丁烷在所有情况下均给出n-硝基氮杂环丁烷.据信,不同的行为是由环应变效应引起的.
DOI:10.1016/s0040-4039(00)93514-7
海关参考信息
- 2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2012108838-A1
优先权日:2009-09-24
标 题 :Synthesis of an energetic nitrate ester
专利号:US-8324421-B2
优先权日:2009-09-24
标题:Synthesis of an energetic nitrate ester
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Spravochnik po Toksikologii i Gigienicheskim Normativam, -(94), 1999
摘要:Toxicology and Applied Pharmacology., 15(175), 1969 []
摘要:Bronstein, A.C., P.L. Currance; Emergency Care for Hazardous Materials Exposure. 2nd ed. St. Louis, MO. Mosby Lifeline. 1994., p. 252
摘要:Atkinson R; J Phys Ref Data. Monograph 2 (1994)
摘要:American Conference of Governmental Industrial Hygienists. Documentation of Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices for 2001. Cincinnati, OH. 2001., p. 1
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